A5058006357- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Metal complexes synthesis and properties
- Lanthanide and Transition Metal Complexes
- Protein Interaction Studies and Fluorescence Analysis
- Crystal structures of chemical compounds
- Inorganic and Organometallic Chemistry
- Chemical and Physical Properties in Aqueous Solutions
- Radioactive element chemistry and processing
- Electrochemical Analysis and Applications
- Metal-Organic Frameworks: Synthesis and Applications
- Crystallography and molecular interactions
- Chemical Synthesis and Characterization
- Analytical Chemistry and Sensors
- Analytical chemistry methods development
- Polyoxometalates: Synthesis and Applications
- Synthesis and Characterization of Heterocyclic Compounds
- Magnetism in coordination complexes
- Thermal and Kinetic Analysis
- Biochemical Analysis and Sensing Techniques
- Extraction and Separation Processes
- Organometallic Compounds Synthesis and Characterization
- Computational Drug Discovery Methods
- Quinazolinone synthesis and applications
- Various Chemistry Research Topics
Bursa Uludağ Üni̇versi̇tesi̇
2015-2024
University of Arts
2019
Bursa Technical University
2019
Abstract [Cu(5‐ClSal‐Trp)(bpy)]·CH 3 OH ( 1 ) and [Cu(3,5‐ClSal‐Trp)(bpy)]·H 2 O (5‐ClSal‐Trp: Schiff base derived from 5‐chlorosalicylaldehyde tryptophan, 3,5‐ClSal‐Trp: 3, 5 ‐di chlorosalicylaldehyde bpy: 2,2′‐bipyridine) have been synthesized analyzed by CHN analysis, FTIR, electronic absorption spectroscopy, ESI‐MS XRD techniques. Interaction of the complexes with biomolecules {calf thymus DNA (CT‐DNA) bovine serum albumin (BSA)} has researched fluorescence spectroscopy. The results show...
As potential drug candidates N 2 O -type tetradentate Schiff bases and their Ni( ii ) complexes have been synthesized investigated in vitro biomolecular (CT-DNA/BSA) interactions biological activities.
One-dimensional (1-D) coordination polymer and mononuclear copper(II) complexes, ([Cu(nphen)(asn)]ClO4)n (1) [Cu(nphen)(gln)(H2O)]ClO4·H2O (2) (nphen = 5-nitro-110-phenanthroline, asn asparagine, gln glutamine), have been synthesized characterized by IR spectroscopy, ESI-MS, CHN analysis, single-crystal X-ray diffraction. These binary ternary complexes of with nphen, asn, investigated using potentiometric methods in 0.1 M KCl aqueous ionic media at 298.2 K. The protonation constants the...
In this paper, three new copper (II) complexes, [Cu(4‐mphen)(tyr)(H 2 O)]ClO 4 (1) , [Cu(5‐mphen)(tyr)(H ·1.5H O (2) and [Cu (tmphen)(tyr)(NO 3 )]0.5H (3) (4‐mphen: 4‐methyl‐1,10‐phenanthroline, 5‐mphen: 5‐methyl‐1,10‐phenanthroline, tmphen: 3,4,7,8‐tetramethyl‐1,10‐phenanthroline tyr: L‐tyrosine), were synthesized characterized using elemental analyses, FT‐IR, ESI‐MS, cyclic voltammetry single‐crystal X‐ray diffraction. It was found that the complexes adopt a distorted five‐coordinate...
A new copper(II) complex, [Cu(Bphen)(Leu)(NO3)(H2O)] (Bphen = 4,7-diphenyl-1,10-phenanthroline, leu L-leucine), has been synthesized and characterized by IR spectroscopy, CHN analysis, single-crystal X-ray diffraction techniques. The CT-DNA binding properties of the complex have investigated both absorption emission spectroscopy. parameters for fluorescence Scatchard plot were also determined. Further, interaction with bovine serum albumin (BSA) using thermodynamic parameters, free energy...
New binary and ternary copper(II) complexes, [Cu(py‐phen) 2 (NO 3 )]NO ( 1 ), [Cu (py‐phen) (gly) ) (H O) ]⋅3H O (tyr) ](NO ⋅3H (py‐phen: pyrazino[2,3‐f][1,10]phenanthroline; gly: glycine; tyr: tyrosine), have been synthesized characterized using CHN analysis, electrospray ionization mass spectrometry, Fourier transform infrared spectroscopy single‐crystal X‐ray diffraction. Interaction of these complexes with calf thymus DNA has investigated absorption spectral titration, ethidium bromide...
Three novel water‐soluble copper(II) complexes – {[Cu(phen)(trp)]ClO 4 ·3H 2 O} n ( 1 ), {[Cu(4‐mphen)(trp)]ClO ) and [[Cu(dmphen)(trp)(MeOH)][Cu(dmphen)(trp)(NO 3 )]]NO (phen: 1,10‐phenanthroline; 4‐mphen: 4‐methyl‐1,10‐phenanthroline; dmphen: 4,7‐dimethyl‐1,10‐phenanthroline; trp: l ‐tryptophan) have been synthesized characterized using various techniques. Complexes are isostructural, exist as one‐dimensional coordination polymers. Complex consists of two discrete containing...
New binary copper(II) complexes – [Cu(4-mphen)2(NO3)]NO3·H2O (1), [Cu(5-mphen)2 (NO3)]NO3·H2O (2), the known complex [Cu(dmphen)2(NO3)]NO3 (3) and [Cu(tmphen)2 (4) - (4-mphen: 4-methyl-1,10-phenanthroline, 5-mphen: 5-methyl-1,10-phenanthroline, dmphen: 4,7-dimethyl-1,10-phenanthroline, tmphen: 3,4,7,8-tetramethyl-1,10-phenanthroline), have been synthesized characterized by CHN analysis, ESI-MS, FTIR single-crystal X-ray diffraction techniques. Interaction of these with calf thymus DNA...
Novel water soluble palladium(<sc>ii</sc>) complexes have been synthesized and characterized. Moreover, the cytotoxicities of these against different human tumor healthy cell lines were investigated by XTT assay.
Yttrium(III) equilibria in the presence of catecholamines adrenaline (AD), noradrenaline (NAD), and dopamine (DP) have been investigated by potentiometric titration aqueous solution I = 0.20 mol·dm-3 KCl ionic medium at 298.15 K. The complexation model for Y(III)−catecholamine systems has established "BEST" software from data. types complexes yttrium(III)−catecholamine ascertained, protonation constants stability yttrium(III) with obtained. YHL2+- Y(HL)2+-type are reported. Catecholamines...
Potentiometric equilibrium measurements have been performed at 25 °C and in an I = 0.10 M KCl ionic medium for the interaction of nickel(II), copper(II), zinc(II) with adenosine 5′-triphosphate (ATP) dicarboxylic amino acids (aa): aspartic acid (Asp) glutamic (Glu). The formation 1:1 1:2 binary 1:1:1 ternary complexes was inferred from potentiometric titration curves. It deduced that acts as a primary ligand involving acids. complexation model systems established by "BEST" software data....
The interaction of lanthanum(III) with the catecholamines adrenaline (AD), noradrenaline (NAD), and dopamine (DP) has been investigated by potentiometric spectrophotometric methods at 298.15 K in an I = 0.2 M KCl ionic medium. protonation constants for ligands stability La(III) complexes are calculated from data using "BEST" software. LaHL La(HL)2 reported 1:1 1:2 molar ratios data. species distribution diagrams were also calculated. In all catecholamine systems, coordination to occurs via...