A5102925704- Radical Photochemical Reactions
- Catalytic C–H Functionalization Methods
- Sulfur-Based Synthesis Techniques
- Synthesis of Indole Derivatives
- Synthesis and Catalytic Reactions
- Chemical Reactions and Isotopes
- Quantum Dots Synthesis And Properties
- Advanced Materials and Mechanics
- Fluorine in Organic Chemistry
- High-Voltage Power Transmission Systems
- Inorganic Fluorides and Related Compounds
- Perovskite Materials and Applications
- Conducting polymers and applications
- Carbon dioxide utilization in catalysis
- Ionic liquids properties and applications
- Advanced Sensor and Energy Harvesting Materials
- Innovative Microfluidic and Catalytic Techniques Innovation
- Advanced Photocatalysis Techniques
China West Normal University
2021-2024
China Electric Power Research Institute
2024
Tiangong University
2023
South China Agricultural University
2015
Abstract Developing multifunctional triboelectric nanogenerators (TENGs) with special intelligence is of great significance for next‐generation self‐powered electronic devices. However, the relevant work on intelligent TENGs, especially those spontaneously responsive to external stimuli, rarely reported. Herein, an TENG thermal‐triggered switchable functionality and high outputs developed by designing a movable layer, which driven two‐way shape memory polyurethane. The resultant device can...
A novel photocatalytic method for the preparation of diarylmethyl silanes was reported through silyl radicals addition strategy to p-QMs (p-quinone methides). This protocol could tolerate a variety functional groups affording corresponding silylation products with moderate excellent yields. The resulting be easily converted into series bioactive GPR40 agonists and useful precursors synthesis compounds possessing both quaternary carbon centers silicon substituents simple operation. plausible...
Abstract A novel electrocatalyzed method for the preparation of dibenzosiloles was developed through intramolecular C−H/Si−H dehydrogenative coupling strategy starting from biarylhydrosilanes. Both electro‐donating and electro‐withdrawing substitution groups were tolerated this transformation, desired dibenzosilole products could be obtained in moderate to excellent yields. sila‐Friedel‐Crafts reaction mechanism proposed on basis previous literature our controlled experiments. magnified image
Abstract Herein, electrochemical reductive carboxylation of para ‐quinone methides with CO 2 was developed. A variety value‐added carboxylic acids can be accessed in moderate to excellent yields. Preliminary studies showed that were reduced benzyl carbanion during the reaction. This protocol features high atom economy, operational simplicity, and environmental friendliness, enabling synthesis various compounds.
It is significant to develop novel difluoromethylation methods because of the important roles difluoromethyl groups in medicinal chemistry and material industries. Here, we developed a difluoromethylation–carboxylation difluoromethylation–deuteration method triggered by radical generated electroreduction stable easily available difluoromethyltriphenylphosphonium bromide. Various molecules containing carboxyl or deuterium can be synthesized through this method. The establishment will provide...
The dihydroisoquinolones skeleton is ubiquitous in natural products and biological molecules. Reported strategies for constructing usually require noble metal catalysts or stoichiometric oxidants, which limit their wide applications. Herein, we developed a photoredox catalyzed tandem denitrogenative [4 + 2] annulation reaction of 1,2,3-benzotriazin-4(3H)-ones with terminal olefins. A variety can be accessed moderate to excellent yield. This protocol features high atom-economy, mild...
An electrochemical Appel reaction was developed for the synthesis of nitriles.This protocol features operationally simplicity, mild conditions and environmental friendliness, enabling various aromatic aliphatic nitriles.Based on controlled experiments cyclic voltammetry (CV) experimental results, an mechanism proposed to explain process.