Shangru Li

ORCID: 0009-0001-6574-4233
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About
Contact & Profiles
Research Areas
  • Advanced Sensor and Energy Harvesting Materials
  • Click Chemistry and Applications
  • Tactile and Sensory Interactions
  • Nanomaterials and Printing Technologies
  • Sulfur-Based Synthesis Techniques
  • Chemical Synthesis and Analysis
  • Synthesis and Catalytic Reactions
  • Fluorine in Organic Chemistry
  • Conducting polymers and applications

Tianjin University
2023

Sun Yat-sen University
2019

Here we report the first asymmetric synthesis of large chiral macrocycles with sulfur atoms. Building on stereospecific SuFEx and SuPhenEx click chemistries, this approach utilizes disulfonimidoyl fluorides p-nitrophenolates─which are efficient building blocks two centers, diphenols to efficiently form novel S–O bonds. Characteristic results include enantiospecific one-step rings consisting 21–58 members characterization both enantiomers (R,R S,S) by e.g. X-ray crystallography.

10.1021/acs.joc.3c01656 article EN cc-by The Journal of Organic Chemistry 2023-10-30
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