A5008951337- Carbon dioxide utilization in catalysis
- Carbon Dioxide Capture Technologies
- Molecular spectroscopy and chirality
- Mass Spectrometry Techniques and Applications
- Crystallization and Solubility Studies
- Photochromic and Fluorescence Chemistry
- Covalent Organic Framework Applications
- Molecular Sensors and Ion Detection
- Phase Equilibria and Thermodynamics
- Supramolecular Chemistry and Complexes
- Axial and Atropisomeric Chirality Synthesis
Centrale Marseille
2024
Centre National de la Recherche Scientifique
2023-2024
Institut de Chimie et Biochimie Moléculaires et Supramoléculaires
2024
Université Claude Bernard Lyon 1
2024
Institut des Sciences Moléculaires
2023
Université de Bordeaux
2023
Lyon College
2023
Abstract Carbon capture, utilization and storage is a key yet cost-intensive technology for the fight against climate change. Single-component water-lean solvents have emerged as promising materials post-combustion CO 2 but little known regarding their mechanism of action. Here we present combined experimental modelling study single-component solvents, find that capture accompanied by self-assembly reverse-micelle-like tetrameric clusters in solution. This spontaneous aggregation leads to...
The synthesis, characterization, and chiroptical properties of a new class hemicryptophanes combining phosphine moiety cyclotriveratrylene unit are reported. synthesis was short efficient. racemic mixture the cage resolved by chiral high-performance liquid chromatography (HPLC), giving access to enantiopure molecular cages, whose absolute configurations could be assigned electronic circular dichroism (ECD) spectroscopy. These phosphines were then reacted with gold in order make corresponding...
In switchable molecular recognition, 1 O2 stimulus responsive receptors offer a unique structural change that is rarely exploited. The employed [4+2] reaction between and anthracene derivatives quantitative, reversible easily implemented. To evaluate the full potential of this new stimulus, non-macrocyclic anthracene-based host was designed for modular binding cations. investigation showed controlled atropisomerism in an on/off fashion within pair hosts. studies revealed higher association...
Abstract Carbon capture, utilization, and storage is a key yet cost-intensive technology for the fight against climate change. In combined experimental modeling study of single-component water-lean solvent, we found that CO 2 capture accompanied by self-assembly reverse micelle-like tetrameric clusters in solution. This spontaneous aggregation leads to stepwise cooperative phenomena with highly contrasting kinetic thermodynamic features. The emergence well-defined supramolecular...