A5070467491- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Nanocluster Synthesis and Applications
- Gold and Silver Nanoparticles Synthesis and Applications
- Nanomaterials for catalytic reactions
- Advanced Nanomaterials in Catalysis
- Fuel Cells and Related Materials
- Membrane-based Ion Separation Techniques
- Advanced Battery Technologies Research
- Asymmetric Hydrogenation and Catalysis
- Organometallic Complex Synthesis and Catalysis
- Polyoxometalates: Synthesis and Applications
- Inorganic Chemistry and Materials
- Infrastructure Maintenance and Monitoring
- Transport Systems and Technology
- Pharmacological Effects and Toxicity Studies
- Crystallography and molecular interactions
- Asphalt Pavement Performance Evaluation
University of Jyväskylä
2020-2024
Centre de Nanosciences et de Nanotechnologies
2020
University of Tehran
2018
Abstract Deciphering the molecular pictures of multi‐component and non‐periodic organic‐inorganic interlayer is a grand technical challenge. Here we show that atomic arrangement hybrid surface ligands on metal nanoparticles can be precisely quantified through comprehensive characterization novel gold cluster, Au 44 ( i Pr 2 ‐bimy) 9 (PA) 6 Br 8 1 ), which features three types ligands, namely, carbene (1,3‐diisopropylbenzimidazolin‐2‐ylidene, ‐bimy), alkynyl (phenylacetylide, PA), halide...
Herein, we describe the synthesis of a toroidal Au
The preparation of a novel Au6 cluster bearing bidentate mixed carbene-thiolate ligand is presented. length linker between the central benzimidazole and thiolate has strong effect on formation products, with C2 chain giving an cluster, while C3 results in no evidence formation. Density functional theory analysis predicts non-metallic large HOMO-LUMO (3.2-3.6 eV) optical gap.
Abstract Deciphering the molecular pictures of multi‐component and non‐periodic organic‐inorganic interlayer is a grand technical challenge. Here we show that atomic arrangement hybrid surface ligands on metal nanoparticles can be precisely quantified through comprehensive characterization novel gold cluster, Au 44 ( i Pr 2 ‐bimy) 9 (PA) 6 Br 8 1 ), which features three types ligands, namely, carbene (1,3‐diisopropylbenzimidazolin‐2‐ylidene, ‐bimy), alkynyl (phenylacetylide, PA), halide...
The use of metal nanoclusters is strongly reliant on their size and configuration; hence, studying the potential isomers a cluster extremely beneficial in understanding performance. In general, prediction identification isomer structures properties can be challenging computationally expensive. Our work describes an investigation to find local for previously experimentally characterized small gold [Au6(NHC-S)4]2+ protected by bidentate mixed carbene-thiolate ligands. We employ molecular...
Density functional theory is used to study geometric, energetic, and electronic properties of metal–ligand bonds in a series group-11 metal complexes ligand-protected clusters.