- Porphyrin and Phthalocyanine Chemistry
- Synthesis and Biological Evaluation
- Phenothiazines and Benzothiazines Synthesis and Activities
- Synthesis and Characterization of Heterocyclic Compounds
- Photochemistry and Electron Transfer Studies
- Molecular Sensors and Ion Detection
- Luminescence and Fluorescent Materials
- Photosynthetic Processes and Mechanisms
- Quinazolinone synthesis and applications
- Metal-Catalyzed Oxygenation Mechanisms
- Metal complexes synthesis and properties
- Synthesis and Reactions of Organic Compounds
- Genetics and Plant Breeding
- Rice Cultivation and Yield Improvement
- Solid-state spectroscopy and crystallography
- Synthesis and Reactivity of Heterocycles
- Analytical Chemistry and Sensors
- Inorganic and Organometallic Chemistry
- Crop Yield and Soil Fertility
- Electrochemical sensors and biosensors
- Synthesis and biological activity
- RNA Interference and Gene Delivery
- Agricultural Practices and Plant Genetics
- Magnetism in coordination complexes
- RNA Research and Splicing
University of Michigan
2011-2024
Analysis Group (United States)
2013
Indian Institute of Science Bangalore
1996-2011
Michigan United
2011
Krishna Institute of Medical Sciences
2002
Natco Pharma (India)
1999-2001
Jawaharlal Nehru Technological University, Hyderabad
2001
Jawaharlal Nehru Centre for Advanced Scientific Research
1992-1998
Indian Drugs and Pharmaceuticals Limited
1982-1991
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOctabromotetraphenylporphyrin and its metal derivatives: Electronic structure electrochemical propertiesP. Bhyrappa V. KrishnanCite this: Inorg. Chem. 1991, 30, 2, 239–245Publication Date (Print):January 1, 1991Publication History Published online1 May 2002Published inissue 1 January 1991https://pubs.acs.org/doi/10.1021/ic00002a018https://doi.org/10.1021/ic00002a018research-articleACS PublicationsRequest reuse permissionsArticle...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPorphyrins with multiple crown ether voids: novel systems for cation complexation studiesV. Thanabal and V. KrishnanCite this: J. Am. Chem. Soc. 1982, 104, 13, 3643–3650Publication Date (Print):June 1, 1982Publication History Published online1 May 2002Published inissue 1 June 1982https://pubs.acs.org/doi/10.1021/ja00377a016https://doi.org/10.1021/ja00377a016research-articleACS PublicationsRequest reuse permissionsArticle...
Cancer stem cells exhibit close resemblance to normal in phenotype as well function. Hence, studying cell behavior is important understanding cancer pathogenesis. It has recently been shown that human breast can be enriched suspension cultures mammospheres. However, little known about the of these long-term cultures. Since extensive self-renewal potential hallmark cells, we undertook a detailed phenotypic and functional characterization mammospheres over passages.Single suspensions derived...
RNA interference (RNAi) is a set of intracellular pathways in eukaryotes that controls both exogenous and endogenous gene expression. The power RNAi to knock down (silence) any interest by the introduction synthetic small-interfering (si)RNAs has afforded powerful insight into biological function through reverse genetic approaches borne new field therapeutics. A number questions are outstanding concerning potency siRNAs, necessitating an understanding how short double-stranded RNAs processed...
Complex generics are generic versions of drug products that generally have complex active ingredients, formulations, routes delivery, dosage forms, drug-device combination products, or other characteristics can make it to demonstrate bioequivalence develop as generics. These (i.e. generics) an important element the United States (U.S.) Food and Drug Administration's (FDA's) Generic User Fee Amendments (GDUFA) II Commitment Letter. The Center for Research on Generics (CRCG) was formed by a...
Abstract A series of mono ferrocene Schiff-base porphyrins in which the unit is disposed different orientations to porphyrin core have been synthesized from meso-5(o or p)aminophenyl-10, 15, 20-triphenyl-21,23-H-porphyrin and ferrocenealdehyde. The optical magnetic resonance spectral features these derivatives reveal weak interactions between units. kinetics metal incorporation into free-base ferrocenyl indicate steric induced by unit. Electrochemical redox behaviour compounds shows that...
Studies on combining ability and heterosis were carried out at Agricultural Research Farm, PAJANCOA & RI, Karaikal, during kharif 2013 for thirteen agronomic yield traits viz., 100 grain weight, 30 single cross hybrids developed using 6 x full diallel method. The analysis revealed the presence of higher magnitude SCA than GCA variance all characters under study. ratio additive to dominance was lower unity traits, indicating non variance. Among parents, inbred line namely UMI 213 found be...
Abstract Diazo coupling reactions of nickel (II) complexes 4, 9-dimethyl-5, 8-diazadodeca-4, 8-diene-2, 11-dione and 6, 9-trimethy1-5, 8-diene-2,11-dione in aqueous methanol have been studied. It is shown that the diazo reaction proceeds selectively leading to asymmetric mono(glyoxalarylhydra-zoneimino) symmetric bie (glyoxalaryl-hydrazoneimino) complexes. Synthesis these types has achieved by direct synthesis from coupled Schiff bases derived β-diketones 1,2 diamines acetate. The products...
A total of 64 medium duration rice accessions were evaluated for their genetic variability and divergence during Rabi season 2020 at Pandit Jawaharlal Nehru College Agriculture Research Institute, Karaikal. Analysis variance revealed significant differences all the traits considered study. The spikelets per panicle filled grains recorded high GCV as well PCV thereby indicating that these would be improved effectively through selection. Other yield component viz., plant height, productive...
Abstract— Intramolecular donor‐acceptor systems bearing porphyrins covalently linked to phenol‐phthalein at various distances and different orientations have been synthesized. Optical absorption emission spectra magnetic resonance studies reveal interaction between the porphyrin unit lactone/semiquinone forms of phenolphthalein. The charge‐transfer quenching fluoresence in these is found be more pronounced compared intermolecular systems. lifetime are interpreted terms intramolecular...