A5086622175- Organometallic Complex Synthesis and Catalysis
- Metal and Thin Film Mechanics
- Ionic liquids properties and applications
- Fungal Biology and Applications
- Advanced materials and composites
- Medical Imaging and Analysis
- Asymmetric Hydrogenation and Catalysis
- Copper Interconnects and Reliability
- Spine and Intervertebral Disc Pathology
- Cervical and Thoracic Myelopathy
- Molecular spectroscopy and chirality
- Computational Drug Discovery Methods
- Fullerene Chemistry and Applications
- Phytochemistry and Biological Activities
- Graph theory and applications
- Microbial Natural Products and Biosynthesis
- Synthesis and Properties of Aromatic Compounds
- Metal complexes synthesis and properties
- Catalytic C–H Functionalization Methods
- Radical Photochemical Reactions
- Coordination Chemistry and Organometallics
- Catalytic Cross-Coupling Reactions
- Magnetism in coordination complexes
Beijing National Laboratory for Molecular Sciences
2023-2024
Peking University
2023-2024
State Key Laboratory of Rare Earth Materials Chemistry and Application
2024
Xiamen University
2011-2022
Collaborative Innovation Center of Chemistry for Energy Materials
2022
Jiangxi Chest Hospital
2015
Terminal rare-earth imido complexes containing metal nitrogen double bonds have received more attention in recent years due to their importance group transformation and catalytic reactions. However, the...
还原条件下非对称钳形 PNN 钴配合物的反应性研究 陈元金 黄大江 石向辉 席振峰 魏俊年 * (北京大学化学与分子工程学院 北京分子科学国家研究中心 生物有机与分子工程教育部重点实验室 北京 100871) 摘要 本工作报道了还原条件下, 非对称钳形钴配合物 PNNCoCl (1) (PNN: [6-( t Bu2PN)C5H3N-2-(3-Mes)C3H2N2])和有 机分子的反应性.利用
A new diphenyl ether methyl 2-(2-formyl-3-hydroxy-5-methylphenoxy)-5-hydroxy-3-methoxybenzoate (3), together with four known compounds, asterric acid (1), asterrate (2), 9(Z),12(Z)-nonadecadienoic (4) and orsellinic (5), were isolated from the Phoma sp. strain SHZK-2, which was a polluted environment in southern China. The structures of these compounds determined by spectroscopic methods. Cytotoxicities against HEPG2 cell Raji lines preliminarily evaluated MTT method.
While the concept of metalla-aromaticity has well been extended to transition organometallic compounds in diverse geometries, aromatic rare-earth complexes are rare due special (n – 1)d0 configuration and high-lying 1)d orbitals centers. In particular, nonplanar cases have not reported so far. Here, we disclose aromaticity dinuclear scandium samarium metallacycles characterized by various indices (nucleus-independent chemical shift, isochemical shielding surface, anisotropy induced current...
A series of theoretical methods, including density functional theory, multiconfiguration molecular orbital and ab initio valence bond are devoted to understanding the metal-ligand bonds in M-BP (BP = biphenyl; M Sc, Y, or La) complexes. Different from most transition metal-BP complexes, stable metal-biphenyl conformers not half-sandwich but clamshell. Energy decomposition analysis results reveal that clamshell possess extra-large relaxation. According wave function analysis, 2-fold donations...
Abstract As a monoamine neurotransmitter, serotonin affects wide range of physiological and behavioral procedures humans but its biological function is complex multifaceted. Here we present comprehensive study the weak serotonin‐residue interactions from cluster science point view. Eight pairs binary clusters are representatively studied. Upon most stable structures depict hydrogen bonding interaction patterns, along with natural bond orbital (NBO) analysis, atoms in molecules (AIM)...
Compared with rare and expensive late-transition metals, rare-earth photocatalysts are much less investigated in synthetic chemistry, particularly concerning redox-inactive metals. Herein, we describe a general strategy to realize the photocatalysis by grafting light-absorbing scaffold onto common ligands organometallics. Three guanidinate complexes photocatalytic functions were synthesized found exhibit higher catalytic efficiency than phenothiazine reductive homocoupling of benzyl...