A5056675636- Corporate Taxation and Avoidance
- American Constitutional Law and Politics
- Catalytic C–H Functionalization Methods
- Local Government Finance and Decentralization
- Radical Photochemical Reactions
- Taxation and Compliance Studies
- Sulfur-Based Synthesis Techniques
- Catalytic Cross-Coupling Reactions
- Cyclopropane Reaction Mechanisms
Merck & Co., Inc., Rahway, NJ, USA (United States)
2024
Princeton University
2023
Under mild blue-light irradiation, α-acylated saturated heterocycles undergo a photomediated one-atom ring contraction that extrudes heteroatom from the cyclic core. However, for nitrogenous heterocycles, this powerful skeletal edit has been limited to substrates bearing electron-withdrawing substituents on nitrogen. Moreover, mechanism and wavelength-dependent efficiency of transformation have remained unclear. In work, we increased electron richness nitrogen in azacycles improve light...
ADVERTISEMENT RETURN TO ARTICLES ASAPPREVFirst ReactionsNEXTSynthesis of Planar Chiral Ferroceneformaldehydes via Rh(I)-Catalyzed C–H ArylationA general synthetic entry into 1,2-disubstituted chiral planar ferrocene derivatives has been developed based on an enantioselective Rh(I)-catalyzed C−H arylation.Hailey HendricksHailey HendricksDepartment Chemistry, Princeton University, Princeton, New Jersey, 08544, United StatesMore by Hailey Hendrickshttps://orcid.org/0009-0009-3648-8769 and Jose....