A5060050294- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Supramolecular Chemistry and Complexes
- Molecular Sensors and Ion Detection
- Magnetism in coordination complexes
- Metal-Organic Frameworks: Synthesis and Applications
- Supramolecular Self-Assembly in Materials
- Radiopharmaceutical Chemistry and Applications
- Advanced biosensing and bioanalysis techniques
- Luminescence and Fluorescent Materials
- Chemical Reactions and Isotopes
- Silicone and Siloxane Chemistry
- Crystallography and molecular interactions
- Covalent Organic Framework Applications
- Innovations in Concrete and Construction Materials
- Surface Modification and Superhydrophobicity
- Nanocluster Synthesis and Applications
- Polyoxometalates: Synthesis and Applications
- Building materials and conservation
- Inhalation and Respiratory Drug Delivery
- Aerogels and thermal insulation
The University of Tokyo
2022-2023
Beijing University of Technology
2018
State Key Laboratory of Analytical Chemistry for Life Science
2012
Nanjing University
2012
Entangled (M3 L2 )n polyhedral complexes represent a unique class of supramolecular architectures that are stabilized by relatively weak metal-acetylene interactions in cooperation with conventional metal-pyridyl coordination. Counter-anion exchange these nitrate (NO3- ) ion triggered formal metal insertion between the centers, and heteroleptic ternary coordination mode acetylenic, pyridyl, donors was generated on centers. As result, main frameworks M18 L12 M12 L8 were formally extended into...
Superb control over the helical chirality of highly-entangled (M 3 L 2 ) n polyhedra = Cu( i ), Ag( ); 2,4,8) was achieved via multiplication weak chiral inductions by side chains accumulated on huge polyhedral surfaces.
Square-like metallamacrocyclic palladium(II) complexes [M8L4]8+ (1-7) were synthesized by reacting aromatic dipyrazole ligands (H2L1-H2L3 with pyromellitic arylimide-, 1,4,5,8-naphthalenetetracarboxylic and anthracene-based groups, respectively) dipalladium corners ([(bpy)2Pd2(NO3)2](NO3)2, [(dmbpy)2Pd2(NO3)2](NO3)2, or [(phen)2Pd2(NO3)2](NO3)2, where bpy = 2,2'-bipyridine, dmbpy 4,4'-dimethyl-2,2'-bipyridine, phen 1,10-phenanthroline) in aqueous solutions via metal-directed self-assembly....
By employing dipalladium corners [(bpy)(2)Pd(2)(NO(3))(2)](NO(3))(2) or [(phen)(2)Pd(2)(NO(3))(2)](NO(3))(2) (where bpy = 2,2'-bipyridine and phen 1,10-phenanthroline) to bridge ferrocene-based dipyrazole ligand (L(1)) m-phenylene-based ligands (L(2-3)) in aqueous solution, a series of positively-charged [M(4)L(2)](4+) metallomacrocycles were obtained. Their structures characterized by (1)H NMR, electrospray ionization mass spectrometry (ESI-MS), elemental analysis, single crystal X-ray...
Abstract The aqueous self‐assembly of the flexible ligand L bis(1H‐benz[d]imidazole‐1‐yl)methane and cis ‐coordinated Pt II precursors [(en)Pt 2+ , (tmeda)Pt en=ethylenediamine, tmeda=N,N, N ′, ′‐tetramethylethylenediamine)] led to formation metallacalixarenes with full alternative conformations (e.g., two novel water‐soluble [M 2 ] 4+ 3 6+ D symmetry, respectively). Their molecular structures were determined by single crystal X‐ray analyses in solid state. present different cavity sizes...
Abstract Entangled (M 3 L 2 ) n polyhedral complexes represent a unique class of supramolecular architectures that are stabilized by relatively weak metal–acetylene interactions in cooperation with conventional metal–pyridyl coordination. Counter‐anion exchange these nitrate (NO − ion triggered formal metal insertion between the centers, and heteroleptic ternary coordination mode acetylenic, pyridyl, donors was generated on centers. As result, main frameworks M 18 12 8 were formally extended...
Metal-directed self-assembly approaches led to the formation of two novel boat-shaped palladium(II)-based metallacalixarenes 1 (1 a, b and c) 2 (2 c), by using new ligands 2,6-bis(1H-naphtho[2,3]imidazol-1-yl)pyridine (L1 ) 1,3-bis(1H-naphtho[2,3]imidazol-1-yl)benzene (L2 with cis-coordinated PdII precursor (tmeda)Pd(ONO2 )2 (tmeda=N, N, N', N'-tetra-methylethylenediamine), repectively. All complexes different counterions were systematically characterized in solution, their structures...
Silver–acetylene interactions adopting a heteroleptic ternary coordination mode enabled the synthesis of concave polyhedral cages upon anion-exchange-triggered interconversion highly entangled polyhedra. In their Communication (e202303714), Yuya Domoto and co-workers describe skeletally edited 3D architectures having partially disconnected knot or link motifs at faces.