A. Hierro

ORCID: 0000-0002-0414-4920
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About
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Research Areas
  • Semiconductor Quantum Structures and Devices
  • GaN-based semiconductor devices and materials
  • ZnO doping and properties
  • Advanced Semiconductor Detectors and Materials
  • Quantum Dots Synthesis And Properties
  • Semiconductor materials and devices
  • Ga2O3 and related materials
  • Semiconductor Lasers and Optical Devices
  • Chalcogenide Semiconductor Thin Films
  • Spectroscopy and Laser Applications
  • Gas Sensing Nanomaterials and Sensors
  • Plasmonic and Surface Plasmon Research
  • solar cell performance optimization
  • Copper-based nanomaterials and applications
  • Electronic and Structural Properties of Oxides
  • Nanowire Synthesis and Applications
  • Metamaterials and Metasurfaces Applications
  • Photonic Crystals and Applications
  • Thermal Radiation and Cooling Technologies
  • Atmospheric Ozone and Climate
  • Optical Coatings and Gratings
  • Perovskite Materials and Applications
  • Semiconductor materials and interfaces
  • Advanced Chemical Physics Studies
  • Acoustic Wave Resonator Technologies

Universidad Politécnica de Madrid
2016-2025

Institut für Sozialforschung und Sozialwirtschaft
2018

Universidad Complutense de Madrid
2017

Institute of Microelectronics
2016

Binghamton University
2015

Centre National de la Recherche Scientifique
2011

Université Côte d'Azur
2011

Universitat de València
2007

The Ohio State University
1998-2002

Universidad Autónoma de Madrid
1996-1997

Abstract Tackling the interfacial loss in emerged perovskite‐based solar cells (PSCs) to address synchronously carrier dynamics and environmental stability, has been of fundamental viable importance, while technological hurdles remain not only creating such mediator, but subsequent embedding active layer. This article reports a strategy hydrophobic fluorinated‐gold‐clusters (FGCs) for highly efficient stable PSCs. The p‐type semiconducting feature enables FGC mediator improve by reducing...

10.1002/adma.202101590 article EN Advanced Materials 2021-07-24

N-Schottky and p+–n GaN junctions are currently used for different technologies. A comparison of the deep levels found throughout entire band gap n-GaN grown by metal-organic chemical vapor deposition under both configurations is presented. Both level optical spectroscopy transient measurements allowing observation majority minority carrier traps. Deep at Ec−Et=0.58–0.62, 1.35, 2.57–2.64, 3.22 eV observed diode configurations, with concentrations in ∼1014–1016 cm−3 range. The 0.58–0.62...

10.1063/1.126580 article EN Applied Physics Letters 2000-05-22

The Sb-induced changes in the optical properties of GaAsSb-capped InAs/GaAs quantum dots (QDs) are shown to be strongly correlated with structural changes. observed redshift photoluminescence emission is follow two different regimes. In first regime, Sb concentrations up $\ensuremath{\sim}12\mathrm{%}$, wavelength shifts $\ensuremath{\sim}1280\text{ }\text{nm}$ a large enhancement luminescence characteristics. A analysis at atomic scale by cross-sectional scanning tunneling microscopy shows...

10.1103/physrevb.81.165305 article EN Physical Review B 2010-04-06

Differential postgrowth hydrogen passivation of deep levels in n–GaN grown by metal-organic chemical vapor deposition has been directly observed means both level transient spectroscopy and optical spectroscopy. Two found at Ec−Et=0.62 1.35 eV show strong H effects, with their concentrations decreasing a factor ⩾30 ∼14, respectively. The decrease the 0.62 trap concentration together its correlation presence Mg is consistent Mg–H complex formation. A band closely spaced Ec−Et=2.64–2.80 narrows...

10.1063/1.1290042 article EN Applied Physics Letters 2000-09-04

Schottky photodiodes based on Au-ZnMgO/sapphire are demonstrated covering the spectral region from 3.35 to 3.48 eV, with UV/VIS rejection ratios up ∼105 and responsivities as high 185 A/W. Both ratio responsivity shown be largely enhanced by presence of an internal gain mechanism, which compensated films become highly conductive a result illumination. This causes large increase in tunnel current through barrier, yielding gains that function incident photon flux.

10.1063/1.3340945 article EN Applied Physics Letters 2010-03-08

The impact of rapid thermal annealing on the optical emission GaInNAs/GaAs quantum wells (QWs) grown by molecular beam epitaxy with high In and N content is shown to be highly dependent crystal structure QWs, as determined transmission electron microscopy. Due presence higher concentrations nonradiative recombination centers, temperature required obtain maximum photoluminescence for QW strong structural modulation upper interface [at onset three-dimensional (3D) growth], intermediate...

10.1063/1.1591416 article EN Journal of Applied Physics 2003-08-01

The effect of growth regime on the deep level spectrum n-GaN using molecular-beam epitaxy (MBE) was investigated. As Ga/N flux ratio decreased towards Ga-lean conditions, concentration two acceptor-like levels, at Ec−3.04 and 3.28 eV, increased from 1015 to 1016 cm−3 causing carrier compensation in these films. Thus, traps behaved as dominant compensating centers MBE n-GaN. Furthermore, increase trap also strongly correlated with degradation both surface morphology bulk electron mobility...

10.1063/1.1445274 article EN Applied Physics Letters 2002-02-04

The origin of the modified optical properties InAs/GaAs quantum dots (QD) capped with a thin GaAs1−xSbx layer is analyzed in terms band structure. To do so, size, shape, and composition QDs capping are determined through cross-sectional scanning tunnelling microscopy used as input parameters an 8 × k·p model. As Sb content increased, there two competing effects determining carrier confinement oscillator strength: increased QD height reduced strain on one side QD-capping valence offset other....

10.1063/1.4755794 article EN Journal of Applied Physics 2012-10-01

Light polarization-sensitive UV photodetectors (PSPDs) using non-polar a-plane ZnMgO/ZnO multiple quantum wells grown both on sapphire and ZnO substrates have been demonstrated. For the PSPDs with anisotropic biaxial in-plain strain, responsivity absorption edge shifts by ΔE ∼ 21 meV between light polarized perpendicular (⊥) parallel (||) to c-axis, maximum (R) contrast is (R⊥/R||)max 6. ZnO, strain-free wells, 40 5. These polarization sensitivities explained in terms of excitonic...

10.1063/1.3624924 article EN Applied Physics Letters 2011-08-15

We have developed a method to grow and characterize the state of art non-polar ZnO/(Zn,Mg)O multi-quantum wells on m-plane ZnO substrates as prerequisite for applications based intersubband transitions. The epilayer interfaces exhibit low roughness, layer thickness remains constant within one monolayer in these heterostructures. optical properties been studied UV IR domains by means photoluminescence absorption experiments, respectively. In UV, is very well described an excitonic transition,...

10.1063/1.5003146 article EN cc-by Applied Physics Letters 2017-12-04

Abstract Surface-enhanced infrared absorption (SEIRA) spectroscopy holds significant promise for chemical detection as it enables direct identification of distinct vibrational fingerprints molecules. Traditionally, SEIRA has been exploited through the use tailored metallic nanoantennas, which are burdened by high losses in mid and costly nanofabrication techniques. In this work, we introduce an alternative, simpler approach using self-assembled Cd(Zn)O nanoparticles a platform. We...

10.1515/nanoph-2025-0020 article EN cc-by Nanophotonics 2025-05-26

The carrier capture kinetics of the Ec—0.59 eV and Ec—0.91 electron traps found in molecular beam epitaxy (MBE)-grown n-GaN have been determined by means deep level transient spectroscopy (DLTS). 0.59 trap does not show behaviour either ideal point defects or line defects. In contrast, 0.91 displays linearly arranged interacting defects, which generate a time-dependent local Coulombic potential with characteristic time constant ≈ 8.6 μs.

10.1002/1521-3951(200111)228:1<309::aid-pssb309>3.0.co;2-n article EN physica status solidi (b) 2001-11-01

A systematic analysis of the deep level spectrum in lower half bandgap Au–Zn1−xMgxO (0.056&amp;lt;x&amp;lt;0.18) Schottky diodes is presented. Two levels are observed at Ev+580 and Ev+280 meV regardless energy with trap concentrations linearly increasing Mg content. The concentration becomes as high 1.01×1018 cm−3 18% Mg, partially compensating films causing a decrease from 8.02×1016 to 1.27×1016 net electron an increase by three orders magnitude diode series resistance due trapping.

10.1063/1.3149699 article EN Applied Physics Letters 2009-06-08

High quality 1 μm thick a-plane MgxZn1−xO layers were produced by molecular beam epitaxy with Mg contents higher than 50%. Resonant Rutherford backscattering spectrometry combined ion channeling revealed a uniform growth in both composition and atomic order. The lattice-site location of Mg, Zn O elements was determined independently, proving the substitutional behaviour Zn-sites wurtzite lattice. X-Ray diffraction pole figure analysis also confirms absence phase separation. Optical...

10.1039/c2ce06315h article EN CrystEngComm 2011-12-15

The photoluminescence efficiency of GaAsSb-capped InAs/GaAs type II quantum dots (QDs) can be greatly enhanced by rapid thermal annealing while preserving long radiative lifetimes which are ∼20 times larger than in standard GaAs-capped QDs. Despite the reduced electron-hole wavefunction overlap, type-II samples more efficient type-I counterparts terms luminescence, showing a great potential for device applications. Strain-driven In-Ga intermixing during is found to modify QD shape and...

10.1063/1.4773008 article EN Applied Physics Letters 2012-12-17

This paper reports on the demonstration of quantum cascade detectors (QCDs) based ZnO/ZnMgO wells (QWs) grown by molecular beam epitaxy an m-plane ZnO substrate. The TM-polarized intersubband absorption is peaked at a 3 μm wavelength. sample has been processed in form square mesas with sizes ranging from 10 × μm2 up to 100 μm2. I-V characteristics reveal that 86% 260 devices are operational and surface leakage current negligible room temperature, which not case 77 K. photocurrent...

10.1063/1.5058120 article EN Applied Physics Letters 2018-12-17

The effect of the capping process on morphology InAs/GaAs quantum dots (QDs) by using different GaAs-based layers (CLs), ranging from strain reduction to compensating layers, has been studied transmission microscopic techniques. For this, we have measured simultaneously height and diameter in buried uncapped QDs covering populations hundreds that are statistically reliable. First, QD population evolves all cases a pyramidal shape into more homogenous distribution with spherical-dome shape,...

10.1088/0957-4484/27/12/125703 article EN Nanotechnology 2016-02-18

Multi-junction solar cells made by assembling semiconductor materials with different bandgap energies have hold the record conversion efficiencies for many years and are currently approaching 50%. Theoretical efficiency limits make use of optimum designs right lattice constant-bandgap energy combination, which requires a 1.0-1.15 eV material lattice-matched to GaAs/Ge. Nevertheless, lack suitable is hindering achievement predicted efficiencies, since only candidates were up now complex...

10.1038/s41598-017-04321-4 article EN cc-by Scientific Reports 2017-06-15

Transparent conducting oxides (TCOs) are widely used in applications from solar cells to light emitting diodes. Here, we show that the metal organic chemical vapor deposition (MOCVD)-grown, rock-salt CdZnO ternary, has excellent potential as a TCO. To assess this compound, use combination of infrared reflectance and ultraviolet-visible absorption spectroscopies, together with Hall effect, determine its optical electrical transport characteristics. It is found incorporation Zn produces an...

10.1063/1.5048771 article EN Applied Physics Letters 2018-11-26

Unexpected light propagation effects, such as negative refraction, have been reported in artificial media. Leveraging on the intersubband resonances heterostructured semiconductors, we show that all possible optical regimes, ranging from classical dieletric and metal to hyperbolic metamaterial types 1 2, can be achieved. As a demonstration, prove refraction effect occur at designed frequency by controlling electronic quantum confinement.

10.1103/physrevlett.123.117401 article EN cc-by Physical Review Letters 2019-09-10
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