A5043688665- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Organometallic Complex Synthesis and Catalysis
- Carbon dioxide utilization in catalysis
- Synthetic Organic Chemistry Methods
- Crystallography and molecular interactions
- Asymmetric Hydrogenation and Catalysis
- Metal complexes synthesis and properties
- N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
- Metal-Organic Frameworks: Synthesis and Applications
- Crystal structures of chemical compounds
- Catalytic Alkyne Reactions
- Magnetism in coordination complexes
- Luminescence and Fluorescent Materials
- Synthesis and characterization of novel inorganic/organometallic compounds
- Catalytic Cross-Coupling Reactions
- Synthesis and biological activity
- biodegradable polymer synthesis and properties
- Perovskite Materials and Applications
- Organic Electronics and Photovoltaics
- Conducting polymers and applications
- Catalytic C–H Functionalization Methods
- Molecular Sensors and Ion Detection
- Supramolecular Chemistry and Complexes
- Synthesis and Characterization of Heterocyclic Compounds
Beijing National Laboratory for Molecular Sciences
2016-2025
Chinese Academy of Sciences
2016-2025
Institute of Chemistry
2016-2025
University of Chinese Academy of Sciences
2018-2025
Molecular Sciences Institute
2025
Czech Academy of Sciences, Institute of Analytical Chemistry
2025
Qilu University of Technology
2015
Lanzhou Institute of Chemical Physics
2008
Qingdao University of Science and Technology
2006
Developing active-layer systems with both high performance and mechanical robustness is a crucial step towards achieving future commercialization of flexible stretchable organic solar cells (OSCs). Herein, we design synthesize series acceptors BTA-C6, BTA-E3, BTA-E6, BTA-E9, featuring the side chains hexyl, 3, 6, 9 carbon-chain ethyl ester end groups respectively. Benefiting from suitable phase separation vertical distribution, PM6:BTA-E3-based OSCs processed by o-xylene exhibit lower energy...
Abstract Circularly polarized luminescence (CPL) is attractive in understanding the excited‐state chirality and developing advanced materials. Herein, we propose a chiral reticular self‐assembly strategy to unite achiral AIEgens, donors, metal ions fabricate optically pure AIEgen metal–organic frameworks (MOFs) as efficient CPL We have found that activity of single‐crystal MOF was generated by framework‐enabled strong emission from AIEgens through‐space transfer donors via metal‐ion bridges....
Highly active <italic>para-t</italic>-Bu-containing 1,2-bis(imino)acenaphthene-Ni(<sc>ii</sc>) catalysts are disclosed which afford hyper-branched PEs with <italic>M</italic><sub>w</sub>'s up to 3.1 × 10<sup>6</sup> g mol<sup>−1</sup>; high tensile strength, excellent shape fixity as well elongation at break a feature.
The series of acenaphthylene-1-[2,6-bis(bis(4-fluorophenyl)methyl)-4-methylphenylimino]-2-arylimine derivatives and their dichloronickel complexes were synthesized fully characterized as well the single-crystal X-ray diffraction representative nickel complexes, revealing a distorted tetrahedral geometry. Upon activation with either MAO or Et2AlCl, all showed high activities in ethylene polymerization; moreover, catalytic systems better thermal stabilities on being manipulated at 80 °C...
The charge transfer from the donor to acceptor units results in a CT complex with excellent near-infrared photothermal conversion efficiency, which acted as an material seawater desalination application.
The unprecedented development of perovskite solar cells (PSCs) makes them one the most promising candidates for terawatt-scale green energy production with low cost. However, high boiling point solvents during solution-processed film deposition cause anisotropic crystal growth and toxic solvent vapor high-throughput manufacturing. Here, a dual-component consisting isopropyl acetate acetonitrile is proposed to form volatile precursor, which can realize high-quality thin by intermediate phase...
We systematically investigated the effects of top substituents on physicochemical properties SMAs and achieved highest PCE for OSCs processed using a non-halogenated solvent without any extra treatment.
In this study, hybrid steric hindrance was introduced into the α-diimine structure to prepare a set of nickel complexes, aiming enhance catalytic performance and polyethylene properties simultaneously for ethylene polymerization.
Abstract Minimizing the energy loss, particularly non-radiative loss (Δ E nr ), without sacrificing charge collection efficiency, is key to further improve photovoltaic performance of organic solar cells (OSCs). Herein, we proposed an asymmetric molecular design strategy, via developing alkyl/thienyl hybrid side chain based small molecule acceptors (SMAs) BTP-C11-TBO and BTP-BO-TBO, manipulate intermolecular interactions realize enhanced luminescence efficiency reduced loss. Theoretical...
A series of 2-[1-(4,6-dimethyl-2-benzhydrylphenylimino)ethyl]-6-[1-(arylimino)ethyl]pyridines was synthesized and used to prepare the iron(II) cobalt(II) chloride complexes thereof. All organic compounds were fully characterized by elemental analysis, IR NMR ((1)H/(13)C) spectroscopy, whilst metal analysis spectroscopy as well single-crystal X-ray diffraction studies (for two representative cobalt complexes), which revealed that geometry at either pseudo-square-pyramidal or trigonal...
A series of cobalt(II) dichloride complexes ligated by 2-[1-(2,4-dibenzhydryl-6-methylphenylimino) ethyl]-6-[1-(arylimino)ethyl]pyridines was synthesized and characterized FT-IR spectroscopy elemental analysis. The molecular structure the representative complex Co4 (R1 = Me, R2 Me) confirmed as pseudo square-pyramidal geometry at cobalt single-crystal X-ray diffraction. Upon treatment with co-catalysts MAO or MMAO, all pre-catalysts exhibited high activities up to 1.81 × 107 g PE mol−1(Co)...
A series of 1,2-bis(arylimino)acenaphthylidenes (L1–L5) and their corresponding 4,4′-methylenebis(1-(2,6-diisopropylphenylimino)-2-(arylimino)acenaphthylene) derivatives (L6–L10) were synthesized used to form mono-nuclear nickel bromides LnnNiBr2 (n = 1–5, Ni1–Ni5) bi-nuclear halides LnnNi2X4 6–10: X Br, Ni2-1–Ni2-5; n 4, Cl, Ni2-6). All the organic compounds fully characterized by FT-IR spectra, NMR measurements elemental analysis. The complexes spectra analysis molecular structures...
A series of 2-(1-arylimino)ethyl-9-arylimino-5,6,7,8-tetrahydrocycloheptapyridine derivatives was synthesized and fully characterized, thereafter reacted with iron dichloride to form their corresponding iron(II) complexes. The single crystals representative organic complex compounds were obtained analyzed by the X-ray diffraction analysis, indicating distorted bipyramidal geometry around core. Moreover, DFT calculations performed on selected species determine structural features. On...
The 9-aryliminocycloheptapyridyl nickel chlorides, activated by Et<sub>3</sub>Al<sub>2</sub>Cl<sub>3</sub> or MAO, exhibited high activities toward ethylene polymerization and produced highly branched PE in narrow polydispersity.
A series of 2-(1-aryliminoethyl)-9-arylimino-5,6,7,8-tetrahydrocycloheptapyridylcobalt chlorides were synthesized and characterized using FT-IR elemental analysis, the molecular structures complexes , confirmed to present a pseudo-square-pyramidal or trigonal-bipyramidal geometry around cobalt center single-crystal X-ray diffraction. Upon activation with either methylaluminoxane (MAO) modified (MMAO), all precatalysts gave high activities up level 10(7) gPE mol(-1) (Co) h(-1) toward ethylene...
The five unsymmetrical ligands 2-[1-(2,6-dibenzhydryl-4-tert-butylphenylimino)ethyl]-6-[1-(arylimino)ethyl]pyridine (aryl = 2,6-Me2C6H3 (L1), 2,6-Et2C6H3 (L2), 2,6-iPr2C6H3 (L3), 2,4,6-Me3C6H2 (L4), 2,6-Et2-4-MeC6H2 (L5)) and the symmetrical ligand 2,6-bis(1-(2,6-dibenzhydryl-4-tert-butylphenylimino)ethyl)pyridine (L6) have been prepared characterized by FT IR 1H/13C NMR spectroscopy elemental analysis. treatment of L1–L6 with FeCl2·4H2O afforded corresponding ferrous chloride complexes...
Solid state emissive materials with high quantum yields and tunable emissions are desirable for various applications. A new TPE derivative (1) two carbazole moieties cyano groups is reported, which shows typical aggregation induced emission behavior. Four crystals 1a, 1b, 1c, 1d obtained after crystallization from N,N-dimethylformamid (DMF), trichloromethane (CHCl3 ), tetrahydrofuran (THF), dichloromethane (CH2 Cl2 respectively. Crystal structural analyses reveal that (i) molecules of 1...
A straightforward two-step synthesis of a new family electronically distinct para-biphenylene-linked 1,2-bis(imino)acenaphthene/pyridyl-2-imine (BIAN-PI) ligands, 2′-CMeN{1-[2,6-(Ph2CH)2-4-R-C6H2N]-2-[3,3′,5,5′-iPr4-1,1′-(C6H2)2-4-N]C2C10H6}C5H4N (R = Me L1′, iPr L2′, tBu L3′, OMe L4′, OCF3 L5′, Cl L6′, F L7′, NO2 L8′), is disclosed. Their reaction with two equivalents NiBr2(DME) results in occupation the inequivalent N,N′ pockets within BIAN-PI framework to afford binuclear nickel(II)...
2-(2-Benzoxazolyl)-6-(1-(arylimino)-ethyl)pyridines (L) were designed as ligands, and their nickel complexes LNiX2 (X = Cl, 1a−7a; X Br, 1b−7b) formed. All ligands fully characterized by NMR, FT-IR spectra, elemental analyses, while the examined spectra analyses. The molecular structures of established single-crystal X-ray diffraction. Complex 6a possesses coordination number 6 one ligand, two moles methanol, chloride anion, whereas 1b 5b possess 5 with distinct distortions, for toward...
Chromophore reactions with changes to conjugation degree, especially those between the conjugated and unconjugated state, will bring a large spectral variation. To realize such process, meso-naked BODIPY (MNBOD) two electron-withdrawing groups around core is designed synthesized. The resulting system extremely sensitive bases. red, highly fluorescent solution readily becomes colorless non-fluorescent after base addition; however, color fluorescence can be totally instantly restored by...
Abstract A series of α,α′‐bis(arylimino)‐2,3:5,6‐bis(pentamethylene)pyridylcobalt chlorides was synthesized by the one‐pot template reaction α,α′‐dioxo‐2,3:5,6‐bis(pentamethylene)pyridine, anilines, and cobalt chloride in refluxing acetic acid. The molecular structure complex Co1 determined single‐crystal X‐ray crystallography, which revealed a distorted square‐pyramidal geometry around center. On activation with methylaluminoxane or modified methylaluminoxane, all complexes exhibited high...