A5042722414- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Crystallography and molecular interactions
- Metal complexes synthesis and properties
- Crystal structures of chemical compounds
- DNA and Nucleic Acid Chemistry
- Metal-Organic Frameworks: Synthesis and Applications
- Analytical Chemistry and Chromatography
- Magnetism in coordination complexes
- Synthesis and Characterization of Heterocyclic Compounds
- Molecular Sensors and Ion Detection
- Asymmetric Synthesis and Catalysis
- Inorganic and Organometallic Chemistry
- Synthetic Organic Chemistry Methods
- Coordination Chemistry and Organometallics
- Chemical Thermodynamics and Molecular Structure
- Chemical Synthesis and Reactions
- Chemical Synthesis and Analysis
- Fluorine in Organic Chemistry
- Advanced Chemical Sensor Technologies
- Catalytic Cross-Coupling Reactions
- Synthesis and biological activity
- Organic Chemistry Cycloaddition Reactions
- Biochemical Analysis and Sensing Techniques
- Synthesis and Reactions of Organic Compounds
Universitat de les Illes Balears
2013-2022
Fundació Universitat-Empresa de les Illes Balears
2014-2020
Clinica Rotger
2017
Research Institute of Health Sciences
2007-2010
Institut de Ciència de Materials de Barcelona
2007-2009
Universitat de València
1987-1989
In this manuscript we report a high-level ab initio study of anion-pi interactions involving N9-methyl-adenine, N6-methyl-adenine, N9-methyl-hypoxanthine, dimer and N9,N9'-trimethylene-bisadenine. DNA bases like adenine are electron-deficient arenes that well suited for interacting favorably with anions. We demonstrate these compounds able to interact N9-Methyl-adenine, the N9-methyl-adenine anion via six-membered ring more strongly than due cooperativity effects between noncovalent pi-pi...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDeoxygenation of highly hindered phenolsJose M. Saa, Mercedes Dopico, Gabriel Martorell, and Angel Garcia-RasoCite this: J. Org. Chem. 1990, 55, 3, 991–995Publication Date (Print):February 1, 1990Publication History Published online1 May 2002Published inissue 1 February 1990https://pubs.acs.org/doi/10.1021/jo00290a033https://doi.org/10.1021/jo00290a033research-articleACS PublicationsRequest reuse permissionsArticle...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPalladium-catalyzed cross-coupling reactions of highly hindered, electron-rich phenol triflates and organostannanesJose M. Saa, Gabriel Martorell, Angel Garcia-RasoCite this: J. Org. Chem. 1992, 57, 2, 678–685Publication Date (Print):January 1, 1992Publication History Published online1 May 2002Published inissue 1 January 1992https://pubs.acs.org/doi/10.1021/jo00028a051https://doi.org/10.1021/jo00028a051research-articleACS PublicationsRequest reuse...
Preparation de phenyl-1 alcene-1ones-3 et diphenyl-1,5 pentadiene-1,4 one-3 dibenzylidene cyclanones
We have recently communicated the important role of lone pair–π, π–π and hydrophobic interactions in solid architecture 5-fluoro-1-hexyluracil 1-hexyluracil (CrystEngComm, 2010, 12, 362–365). As a matter fact, simple substitution hydrogen atom by fluorine has an enormous consequence state structure. It been demonstrated that this is due to increase π-acidity ring. In article we extend study other uracil derivatives, where changed hydrophobicity hexyl chain introducing hydrophilic groups...
The synthesis of a metalled double-helix containing exclusively silver-mediated C*-C* base pairs is reported herein (C*=N1 hexylcytosine). Remarkably, it the first crystal structure infinite and consecutive C*-AgI -C* that form double helix. AgI ion occupies center between two C* residues with N(3)-Ag bond lengths 2.1 Å short -AgI distances (3.1 Å) suggesting an interesting argentophilic attraction as stabilization source helical disposition. solid-state further stabilized by metal-mediated...
Herein we report the synthesis and X-ray characterization of a gold(iii) complex 1-hexylcytosine via N(3). The AuCl3N complexes stack on top each other by reciprocal [AuCl] regium bonding interactions. After first example 35 years ago, this is second available structure cytosine nucleobase model complexed to gold(iii).
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAb Initio Calculations of the Potential Surface for Thermal Decomposition Phenoxyl RadicalSantiago Olivella, Albert Sole, and Angel Garcia-RasoCite this: J. Phys. Chem. 1995, 99, 26, 10549–10556Publication Date (Print):June 1, 1995Publication History Published online1 May 2002Published inissue 1 June 1995https://pubs.acs.org/doi/10.1021/j100026a018https://doi.org/10.1021/j100026a018research-articleACS PublicationsRequest reuse permissionsArticle...
The simple substitution of a hydrogen atom by fluorine in 1-hexyluracil has an enormous consequence on the solid state structure due to increment π-acidity ring.
In this manuscript, we report the synthesis and solid-state characterization of five new compounds based on 2-aminopyrimidine building block. Some them exhibit interesting anion-π interactions. addition, a high level ab initio study interactions involving 2-methylaminopyrimidine its dimer. We demonstrate that these are able to interact favorably with anions. The dimer interacts anion more strongly than monomer due cooperativity effects between noncovalent hydrogen bonding This pattern, is,...
In this manuscript, we report the synthesis and X-ray characterization of two new Au(III)-cytosine systems: AuCl3(CytC6) (1) (HCytC6)2[AuCl4]Cl (2), where CytC6 is N1-hexylcytosine. Compound 1 an inner sphere...