A5029101220- Electrochemical Analysis and Applications
- Chemical Reaction Mechanisms
- Free Radicals and Antioxidants
- Analytical Chemistry and Sensors
- Chemistry and Chemical Engineering
- Organic and Inorganic Chemical Reactions
- Electrochemical sensors and biosensors
- Radical Photochemical Reactions
- Microfluidic and Capillary Electrophoresis Applications
- Metal complexes synthesis and properties
- Spectroscopy and Quantum Chemical Studies
- Bioactive Compounds and Antitumor Agents
- Paraquat toxicity studies and treatments
- Innovative Microfluidic and Catalytic Techniques Innovation
- Chemical Synthesis and Reactions
- Magnetism in coordination complexes
- Cancer therapeutics and mechanisms
- Cassava research and cyanide
- Metal-Catalyzed Oxygenation Mechanisms
- Various Chemistry Research Topics
- Chemical Synthesis and Analysis
- Molecular Junctions and Nanostructures
- Conducting polymers and applications
- Genomics, phytochemicals, and oxidative stress
- Cancer Treatment and Pharmacology
Yeditepe University
2013-2019
Near East University
2010
Czech Academy of Sciences, J. Heyrovský Institute of Physical Chemistry
2006
Clarkson University
2003-2006
Gazi University
2006
Hydrogen cyanide (HCN) poisoning due to amygdalin (AMY) in apricot seeds is one of the public health issues Turkey. The aim this study was investigate AMY content 13 different including bitter and sweet ones, which are either sulfurized or roasted. determined by a high-performance liquid chromatography. Release HCN predicted total amount can cause calculated. mean 26 ± 14 mg g−1 that 0.16 0.09 g−1. consumption small amounts may poisoning.
The antioxidant, antimalarial, antibacterial, and antitumor activities of thiosemicarbazones have made this class compounds important for medicinal chemists. In addition, are among the most potent well-known ribonucleotide reductase inhibitors. study, 24 new thiosemicarbazone derivatives were synthesized, structures purity determined by IR, 1 H NMR, 13 C mass spectroscopy, elemental analysis. IC50 values these with an assay inhibition. Compounds 19, 20, inhibited enzyme activity at a higher...
In this work, the effects of common cooking practices such as boiling, microwaving, steaming, and oven their influence on amount release glucoraphanin (GCP) sulforaphane (SFP) in broccoli red cabbage were investigated using HPLC.
Eight new mixed ligand complexes of dioxomolybdenum(VI) with 2-hydroxy-3-methoxy/3,5-dibromo benzaldehyde 4-phenyl/ethyl-S-methyl/butyl thiosemicarbazones (L) were synthesized. The general formula [MoO2LD] (D: methanol, pyridine) characterized by elemental analysis, IR, UV, and 1H-NMR spectroscopy. structure 3a was also determined X-ray single-crystal diffraction. thiosemicarbazone ligands are coordinated to center through ONN set the sixth site molybdenum is occupied second (D). in vitro...
Aromatic oximes are reduced in aqueous solution a four-electron process. The reducible species the pH range 5−8 is diprotonated form of oxime. This generated course electrolysis vicinity electrode surface from adsorbed neutral reduction initiated by cleavage N−O bond. diprotonation facilitates process preformation OH2+ as good leaving group and positive charge on azomethine nitrogen. Diprotonation has been proven based shapes i = f(pH) plots, observed shifts half-wave potentials with...
The acid ionization constant (pKa) values of 2-(3H)-benzoxazolinone and its 17 derivatives were determined in buffered solutions by UV–vis spectrophotometry, potentiometry, capillary zone electrophoresis techniques. pKa the studied compounds are found to be range 9.01 7.15. advantages limitations each technique discussed. results suggest that removal a proton from molecule occurred on nitrogen atom ring analgesic/anti-inflammatory activities benzoxazolinone decrease when increase.
Abstract Dienogest is a synthetic oral progestogen with unique pharmacological properties that used orally in the treatment of endometrosis. The first time, detailed electrochemical mechanism dienogest investigated different aqueous mediums. Different progestins were to understand completely oxidation mechanism. was systematically by cyclic voltammetry, differential pulse and square wave voltammetry. A simple adsorptive stripping voltammetry method has been developed for fully validated...
The investigation of electrochemical reduction capecitabine on DME resulted in a scheme that involves two electron the C=O bond six membered heterocyclic ring and comparison with model compounds such as benzophenone, 5-fluorouracil cytosine supported observed behavior. Reporting an inexpensive, simple, rapid validated method for determination was achieved by DPP good precision, accuracy reproducibility. This work emphasizes polarography to be best choice when studying mechanisms presents...
Dienogest (DGN), is an orally administered synthetic progestin that has shown to have selective progesterone receptor (PR) agonistic activity and oral progestational potency on endometrium. In this paper, the investigation of electrochemical reduction dropping mercury electrode (DME) achieved resulted in a scheme involves two electron 3-keto-delta-4-group A-ring molecule. This observation supported by comparison compound with model compounds testosterone norethisterone. study, determination...
Abstract not Available.
Abstract not Available.
Abstract not Available.