A5070351901- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Metal complexes synthesis and properties
- Molecular Sensors and Ion Detection
- Electrochemical Analysis and Applications
- Chemical synthesis and pharmacological studies
- Synthesis and Characterization of Heterocyclic Compounds
- Protein Interaction Studies and Fluorescence Analysis
- Organoselenium and organotellurium chemistry
- Analytical chemistry methods development
- Free Radicals and Antioxidants
- Organometallic Compounds Synthesis and Characterization
- Porphyrin Metabolism and Disorders
- Mercury impact and mitigation studies
- Nonlinear Optical Materials Research
- Trace Elements in Health
- Synthesis and biological activity
- Organic Chemistry Cycloaddition Reactions
- Synthesis and Characterization of Pyrroles
National Institute of Technology Tiruchirappalli
2018-2023
Karunya University
2023
Abstract Two new thiosemicarbazone ligands of 2‐hydroxynaphthldehyde ( L1 and L2 ) their square planar Cu(II) complexes C1 C2 have been synthesised. The were characterised by various spectroscopic technique (UV‐Visible spectra, FT IR (ATR), 1 H & 13 C NMR, ESI mass EPR spectra). molecular structure complex confirmed single crystal X‐ray crystallography. showed a slightly distorted geometry. in vitro DNA protein (BSA) binding assay these conducted using electronic absorption spectra...
A sequence of aroyl selenourea ligands (L1–L3) substituted by aniline and their Ru(II) (η6-p-cymene) complexes (1-3), [Ru(II) L] (L = monodentate ligand) have been synthesized characterized the composition metal complexes. The molecular structures ligand L1 complex 3 were also confirmed single XRD crystal method. single-crystal study showed that coordinates with Ru via Se novel neutral atom. In vitro DNA interaction studies investigated Fluorescence UV-Visible spectroscopic methods which...
A series of aroyl selenourea dibenzosuberene (1–3) derivatives were synthesized and characterized by different analytical methods single crystal X-ray crystallography. Quantum chemical computations made using DFT to determine the structural molecular properties compounds. The in vitro antibacterial action compounds was evaluated against chosen gram-negative (Pseudomonas aeruginosa, Klebsiella pneumoniae, Escherichia coli), gram-positive (Bacillus subtilis, Staphylococcus aureus, epidermidis)...
This study was aimed to synthesize and characterize a series of novel bis(thiourea) compounds (1–3) featuring ortho phenylenediamine substitutions assess their potential biological properties. A range analytical spectroscopic techniques, including elemental analyses, UV–visible, FT-IR, NMR, mass, were employed confirm successful compound synthesis. Single-crystal X-ray diffraction utilized validate crystal structures. Density functional theory calculations conducted compare optimized...
Abstract We introduce a novel selenium-based compound [N-(Phenylcarbamoselenoyl) furan-2-carboxamide] for the optical and fluorimetric detection of Hg in an aqueous medium. The synthesized was characterized by different spectroscopic methods. designed chemosensor FSU has shown significant fluorescence quenching when 2+ ions were added to sensing Furthermore, provoked 2:1 complex formation with FSU. It is found that offers high selectivity over variety cations such as Co , Cr 3+ Ni Zn Cu Mg...