- Advanced Battery Materials and Technologies
- Supercapacitor Materials and Fabrication
- Advancements in Battery Materials
- Crystal Structures and Properties
- Gas Sensing Nanomaterials and Sensors
- Analytical Chemistry and Sensors
- Fluorine in Organic Chemistry
- Porphyrin and Phthalocyanine Chemistry
- X-ray Diffraction in Crystallography
- Lanthanide and Transition Metal Complexes
- ZnO doping and properties
- Solid-state spectroscopy and crystallography
Institute of Physics
2024
University of Chinese Academy of Sciences
2017-2022
High-capacity Li-rich Mn-based oxide cathodes show a great potential in next generation Li-ion batteries but suffer from some critical issues, such as, lattice oxygen escape, irreversible transition metal (TM) cation migration, and voltage decay. Herein, comprehensive structural modulation the bulk surface of is proposed through simultaneously introducing vacancies P doping to mitigate these improvement mechanism revealed. First, elongates OO distance, which lowers energy barrier enhances...
LiCoO2 (LCO) is ideal for 3C electronics due to its high tap density. However, the excessive O → Co charge transfer at delithiation leads irreversible reduction, release, and structural degradation, deteriorating high-voltage performance of LCO. Herein, we propose regulate intrinsic Fermi level via uneven trace Zr/Mg doping. First, increase electron density in mitigates both oxidation/coupled reduction through alleviating transfer, restraining formations Co2+ O2. This elevates redox activity...
We describe the synthesis of β-fluorinated porpholactones by oxidation fluorinated CC bond pyrrolic subunit in porphyrin using “RuCl<sub>3</sub> + Oxone®” protocol.