Alyssa F. J. van den Boom

ORCID: 0000-0002-7206-202X
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Research Areas
  • Organic Electronics and Photovoltaics
  • Silicon Nanostructures and Photoluminescence
  • Silicon and Solar Cell Technologies
  • Sulfur-Based Synthesis Techniques
  • Chemical Synthesis and Analysis
  • Nanowire Synthesis and Applications
  • Chemical and Physical Properties of Materials
  • Conducting polymers and applications
  • Click Chemistry and Applications
  • Advanced Physical and Chemical Molecular Interactions
  • Catalytic Cross-Coupling Reactions
  • Quantum Dots Synthesis And Properties
  • Catalytic Processes in Materials Science
  • Cholinesterase and Neurodegenerative Diseases
  • Molecular Junctions and Nanostructures
  • Semiconductor materials and interfaces
  • Chemical synthesis and alkaloids

Wageningen University & Research
2020-2023

Singlet fission in tetracene generates two triplet excitons per absorbed photon. If these can be effectively transferred into silicon (Si), then additional photocurrent generated from photons above the bandgap of Si. This could alleviate thermalization loss and increase efficiency conventional Si solar cells. Here, we show that a change polymorphism deposited on due to air exposure facilitates transfer Magnetic field-dependent measurements confirm contribute photocurrent. The decay delayed...

10.1021/acs.jpclett.0c02163 article EN cc-by-nc-nd The Journal of Physical Chemistry Letters 2020-09-22

Silicon solar cells are operating close to the theoretical maximum efficiency limit. To increase their beyond this limit, it is necessary decrease energy losses occurring for high-energy photons. A sensitizing layer of singlet-fission material can in principle double current generated by photons, and significantly reduce from photons within cell. Here, we construct a model such cell, using Si(111) surfaces tetracene. transfer between two layers, series tetracene derivatives was synthesized,...

10.1021/acs.jpclett.3c00589 article EN cc-by The Journal of Physical Chemistry Letters 2023-05-08

SuFEx chemistry has recently evolved as next-generation click chemistry. However, in most syntheses, additional reagents/catalysts and carefully controlled conditions are still needed. Here, we aim to further generalize S(VI) exchange chemistry, using 4-nitrophenyl phenylmethanesulfonate example, which the nitrophenolate group is exchanged for a wide range of (substituted) phenols alkyl alcohols. Quantitative yields were reached within 10 min under ambient required only filtering through...

10.1021/acs.orglett.2c03421 article EN cc-by Organic Letters 2022-11-16

Silicon nanoparticles (Si NPs) are a good alternative to conventional heavy metal-containing quantum dots in many applications, due their low toxicity, cost, and the high natural abundance of starting material. Recently, much synthetic progress has been made, crystalline Si NPs can now be prepared matter hours. However, passivation these particles is still time-consuming difficult process, usually requiring temperatures and/or harsh reaction conditions. In this paper, we report an easy...

10.1039/c9fd00102f article EN cc-by-nc Faraday Discussions 2020-01-01

Sulfonamides have many important biological applications, yet their synthesis often involves long reaction times under dry and non-ambient conditions. Here we report the of a large range sulfonamides at room temperature using 4-nitrophenyl benzylsulfonate as starting material. were prepared from wide aliphatic, linear, cyclic amines, anilines,

10.1021/acs.orglett.2c04292 article EN cc-by Organic Letters 2023-01-31

Singlet fission in tetracene generates two triplet excitons per absorbed photon. If these can be effectively transferred into silicon (Si) then additional photocurrent generated from photons above the bandgap of Si. This could alleviate thermalization loss and increase efficiency conventional Si solar cells. Here we show that a change polymorphism deposited on due to air exposure, facilitates transfer Magnetic field-dependent measurements confirm contribute photocurrent. The decay delayed...

10.48550/arxiv.2007.06910 preprint EN other-oa arXiv (Cornell University) 2020-01-01
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