A5069875922- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Electrocatalysts for Energy Conversion
- Metal-Organic Frameworks: Synthesis and Applications
- Advanced Nanomaterials in Catalysis
- Metal complexes synthesis and properties
- Chemical Synthesis and Characterization
- Polyoxometalates: Synthesis and Applications
- Carbon and Quantum Dots Applications
- Gas Sensing Nanomaterials and Sensors
- Metal-Catalyzed Oxygenation Mechanisms
- ZnO doping and properties
- CO2 Reduction Techniques and Catalysts
- Water Quality Monitoring and Analysis
- Advanced Sensor and Energy Harvesting Materials
- Conducting polymers and applications
- TiO2 Photocatalysis and Solar Cells
- Ammonia Synthesis and Nitrogen Reduction
- Advanced oxidation water treatment
Dartmouth College
2022-2023
Institut Català d'Investigació Química
2020-2022
Universitat Rovira i Virgili
2020-2022
National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”
2014
A new Ru complex containing the deprotonated 2,2′:6′,2′′-terpyridine-6,6′′-diphosphonic acid (H4tPa) and pyridine (py) of general formula [RuII(H3tPa-κ-N3O)(py)2]+, 2+, has been prepared thoroughly characterized by means spectroscopic electrochemical techniques, X-ray diffraction analysis, density functional theory (DFT) calculations. Complex 2+ presents a dynamic behavior in solution that involves synchronous coordination decoordination dangling phosphonic groups tPa4– ligand. However, at...
This paper describes a novel synthetic approach for the conversion of zero-valent copper metal into conductive two-dimensional layered metal-organic framework (MOF) based on 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) to form Cu
Ammonia (electro)oxidation with molecular catalysts is a rapidly developing topic wide practical applications ahead. We report here the catalytic ammonia oxidation reaction (AOR) activity using [Ru(tda-κ-N3O)(py)2], 2, (tda2– 2,2′:6′,2′′-terpyridine-6,6′′-dicarboxylate; py pyridine) as catalyst precursor. Furthermore, we also describe rich chemistry associated of Ru-tda and Ru-tPa (tPa–4 2,2′:6′,2′′-terpyridine-6,6′′-diphosphonate) complexes NH3 N2H4 [RuII(tda-κ-N3O)(dmso)Cl] (dmso dimethyl...
The present work uncovers the oxidative transformations of a recently reported polypyridyl phosphonate–phenoxo Ru-based water oxidation catalyst [RuIII(tPaO-κ-N2OPOC)(py)2]2–, 22– {tPaO5– is 3-(hydroxo-[2,2′:6′,2″-terpyridine]-6,6″-diyl)bis(phosphonate)}, under turnover conditions. We show how suffers from degradation during catalysis and generates phosphonate–carboxylate Ru complex [RuII(Hbpc)(py)2], 3H, where bpc3– 6′-phosphonato-[2,2′-bipyridine]-6-carboxylate. Complex 3H has been...
Abstract Owing to high modularity and synthetic tunability, metal–organic frameworks (MOFs) on textiles are poised contribute the development of state‐of‐the‐art wearable systems with multifunctional performance. While these composite materials have demonstrated promising functions in sensing, filtration, detoxification, biomedicine, their applicability is only beginning materialize. This review highlights multifunctionality versatility MOF‐integrated textile systems. It summarizes...
The research revealed that Fenton reagent is to be utilized remove the dye (active bright orange CS/5K) from industrial sewage.Hypercube Hyperchem Professional v8.01 software (trial) was used carry out quantum-chemical calculation of colouring agent structure and heat energy.Based on information references received experimental data, oxidation mechanism by photo-Fenton system has been introduced.