Bo Cao

ORCID: 0000-0002-9324-261X
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About
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Research Areas
  • Advancements in Battery Materials
  • Advanced Battery Materials and Technologies
  • Supercapacitor Materials and Fabrication
  • Electrocatalysts for Energy Conversion
  • Electrochemical Analysis and Applications
  • Extraction and Separation Processes
  • Advanced Battery Technologies Research
  • Advanced Memory and Neural Computing
  • Minerals Flotation and Separation Techniques
  • Inflammatory mediators and NSAID effects
  • Eicosanoids and Hypertension Pharmacology
  • Phosphodiesterase function and regulation
  • Advanced battery technologies research
  • Medicinal Plants and Bioactive Compounds
  • Calcium Carbonate Crystallization and Inhibition
  • Metal-Organic Frameworks: Synthesis and Applications
  • Nuclear Receptors and Signaling
  • Computational Drug Discovery Methods
  • Multiferroics and related materials
  • Blood Pressure and Hypertension Studies
  • Mine drainage and remediation techniques
  • Epilepsy research and treatment
  • Pharmacological Effects of Natural Compounds
  • Ferroelectric and Piezoelectric Materials
  • Fuel Cells and Related Materials

Peking University
2010-2025

Inner Mongolia University
2021-2024

The cathode materials work as the host framework for both Li+ diffusion and electron transport in Li-ion batteries. property is always research focus, while less studied. Herein, we propose a unique strategy to elevate rate performance through promoting surface electric conductivity. Specifically, disordered rock-salt phase was coherently constructed at of LiCoO2 , conductivity by over one magnitude. It increased effective voltage (Veff ) imposed bulk, thus driving more extraction/insertion...

10.1002/anie.202218595 article EN Angewandte Chemie International Edition 2023-01-02

Abstract As one of the most promising cathodes for Li‐ion batteries, Li‐rich layered oxides suffer from low Coulombic efficiency, severe capacity fading, and voltage decay, which are related to aggregated Li@Mn 6 superstructure units. Herein, a Co‐free oxide Li[Li 1/4 Mn 1/2 Ni 1/6 Al 1/12 ]O 2 through substitution Co in , is designed. Combining average structural refinement with detailed local structural/chemical analysis, it found that introduced ions occupy sites units, further induces...

10.1002/aenm.202101962 article EN Advanced Energy Materials 2021-08-18

Understanding the mechanism of rate-dependent electrochemical performance degradation in cathodes is crucial to developing fast charging/discharging for Li-ion batteries. Here, taking Li-rich layered oxide Li1.2 Ni0.13 Co0.13 Mn0.54 O2 as model cathode, mechanisms at low and high rates are comparatively investigated from two aspects, transition metal (TM) dissolution structure change. Quantitative analyses combining spatial-resolved synchrotron X-ray fluorescence (XRF) imaging, diffraction...

10.1002/smll.202301834 article EN Small 2023-06-20

Abstract Li + /Na exchange has been extensively explored as an effective method to prepare high‐performance Mn‐based layered cathodes for Li‐ion batteries, since the first report in 1996 by P. G. Bruce (Nature, 1996. 381, 499–500). Understanding detailed structural changes during ion‐exchange process is crucial implement synthetic control of cathodes, but less studied. Herein, situ synchrotron X‐ray diffraction, density functional theory calculations, and electrochemical tests are combined...

10.1002/adfm.202214921 article EN Advanced Functional Materials 2023-02-17

Sodium-ion batteries (SIBs) are now emerging as a low-cost alternative to the current lithium-ion batteries, but their performance is limited by sluggish transportation of large Na ions in electrodes. Expanded graphite has been employed enhancing transport kinetics. However, high-performance should be synthesized at high temperatures when using traditional methods, which inevitably increases total cost material production. To tackle kinetic issue for SIBs, we develop three-dimensional...

10.1021/acsami.9b07206 article EN ACS Applied Materials & Interfaces 2019-06-19

Background: Atherosclerosis (AS) is a leading cause of cardiovascular diseases, characterized by lipid accumulation in arterial walls. The enzyme Ephx2 (soluble epoxide hydrolase, sEH) implicated AS development, but its precise mechanisms and therapeutic potential are not fully understood. Objectives: This study aimed to analyze gene expression data from low-density lipoprotein receptor knockout (LDLR⁸/⁸) LDLR⁸/⁸sEH⁸/⁸ mice identify significant genes associated with AS. Methods: A directed...

10.2174/0113862073345542250220051427 article EN Combinatorial Chemistry & High Throughput Screening 2025-03-27

Transition metal nitrides (TMNs) have received special concern as important energy storage materials, owing to their high conductibility, good mechanical strength, and superior corrosion resistance. However, insufficient capacitance poor cycling stability limit practical applications for supercapacitors. Here, a novel three-dimensional (3D) self-supported integrated electrode consisted of porous nanowall arrays ultrafine cobalt nitride (Co4N) nanoparticles encapsulated in lanthanum...

10.1021/acsami.2c09377 article EN ACS Applied Materials & Interfaces 2022-10-14

Lithium-excess manganese layered oxide Li2 MnO3 , attracts much attention as a cathode in Li-ion batteries, due to the low cost and ultrahigh theoretical capacity (≈460 mA h g-1 ). However, it delivers reversible practical (<200 ) irreversible oxygen redox at high potentials (>4.5 V). Herein, heavy fluorination (9.5%) is successfully implemented anionic framework of Li-Mn-O-F (LMOF) through unique ion-exchange route. F substitution with O stabilizes framework, completely inhibits O2...

10.1002/smll.202103499 article EN Small 2021-12-01

High-surface-area carbon (HSAC) has been regarded as one of the most promising anode materials for sodium-ion batteries. However, it generally suffers from low initial Coulombic efficiency (ICE), which is closely related to formation process a solid electrolyte interface (SEI). Herein, impact different salts on electrochemical performance and SEI commercial HSAC studied. It found that use NaCF3SO3 enables much higher ICE (69.28%) reversible capacity (283 mA h g-1) compared with NaPF6...

10.1021/acsami.1c14334 article EN ACS Applied Materials & Interfaces 2021-10-08

The purpose of this study is to compare the effects and safety azelnidipine amlodipine in Chinese essential hypertensive patients. Patients were randomized receive administration 8–16 mg/day or 2.5–5 for 8 weeks. blood pressure pulse rate evaluated an outpatient clinic by ambulatory monitoring. There 220 patients enrolled study. both groups was decreased significantly (P < 0.001). Compared with amlodipine, received had better response systolic (SBP) diastolic (DBP) 0.01). No significant...

10.3109/10641961003628510 article EN Clinical and Experimental Hypertension 2010-10-01

Heterostructured Electrocatalysts In article number 2102413, Baocang Liu, Rui Gao, Jun Zhang, Bin and co-workers report the construction of a novel heterostructured electrocatalyst CePO4/MoP/carbon cloth (CC) constituting MoP nanobelts with surface-decorated CePO4 nanoparticles on CC for hydrogen evolution reaction (HER). The CePO4/MoP/CC exhibits low overpotential 48 mV at 10 mA cm−2 in alkaline medium due to optimized electronic structure more exposed active sites.

10.1002/smll.202170208 article EN Small 2021-10-01

Houshiheisan (HSHS) has been effective in the treatment of ischemic stroke (IS) for centuries. However, its mechanisms are still underexplored.

10.2174/1386207326666230810094557 article EN Combinatorial Chemistry & High Throughput Screening 2023-08-11

In the practical operations of Li-ion batteries, inevitable deep charge/discharge happens locally due to intrinsic (de)lithiation inhomogeneity at electrode and particle level, which would damage health batteries even cause safety concern. It is essential develop stable cathodes operating in a wide voltage window ensure batteries. Herein, we comprehensively investigate behaviors representative Li-rich cathode Li1.2Mn0.54Ni0.13Co0.13O2 1.0-4.8 V, reveal that, deep-lithiation drive violent TM...

10.2139/ssrn.4157514 article EN SSRN Electronic Journal 2022-01-01
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