A5046237947- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Crystallography and molecular interactions
- Supramolecular Chemistry and Complexes
- Metal-Organic Frameworks: Synthesis and Applications
- Organometallic Complex Synthesis and Catalysis
- Magnetism in coordination complexes
- Boron Compounds in Chemistry
- Metal complexes synthesis and properties
- Supramolecular Self-Assembly in Materials
- Chemical Synthesis and Reactions
- Coordination Chemistry and Organometallics
- Asymmetric Hydrogenation and Catalysis
- Radiopharmaceutical Chemistry and Applications
- Synthesis and characterization of novel inorganic/organometallic compounds
- Heme Oxygenase-1 and Carbon Monoxide
- Porphyrin and Phthalocyanine Chemistry
- Molecular Sensors and Ion Detection
- N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
- biodegradable polymer synthesis and properties
- Polyoxometalates: Synthesis and Applications
University of Göttingen
2021
Pondicherry University
2014-2018
Indian Institute of Technology Hyderabad
2017
Multicomponent self-assembly of Re2(CO)10, diaryl dichalcogenide ligands (REER), and phenyl-1,3,5-tris(isonicotinate) (ptin) under solvothermal conditions has resulted in the formation chalcogen-bridged trigonal metallaprisms general formula [{(CO)3Re(μ-ER)2Re(CO)3}3(μ3-ptin)2] (1–5), wherein E = S, Se R phenyl, p-tolyl, benzyl. Oxidative addition disulfide/diaryl diselenide to Re2(CO)10 with ester-functionalized tritopic linker ptin yielded 1–5 facile reaction conditions. The have been...
A new series of thiolato-bridged manganese(I)-based supramolecular rectangles have been achieved by three-precursor self-assembly Mn2(CO)10, diaryl disulfides (RSSR), and linear ditopic azine ligands (L) [L = pyrazine (pz), 4,4′-bipyridine (bpy), trans-1,2-bis(4-pyridyl)ethylene (bpe)] using a one-pot synthetic strategy. Oxidative addition RSSR (diphenyl disulfide p-tolyl disulfide) to manganese decacarbonyl in the presence rigid bidentate afforded metallarectangles general formula...
Flexible dimanganese metallacycles have been achieved using Mn(CO)<sub>5</sub>Br and adaptable ditopic pyridyl linkers. The host–guest chemistry of Mn(<sc>i</sc>)-dinuclear has explored.
GRAPHICAL ABSTRACTRecent development of aminophosphine chalcogenides and boranes as ligands in s-block metal chemistryAll authorsChowan Ashok Kumar & Tarun K. Panda http://orcid.org/0000-0003-0975-0118https://doi.org/10.1080/10426507.2017.1322967Published online:12 July 2017
Abstract Synthesis of four and five coordinated aluminum amidinate (PhC(N t Bu) 2 =L) compounds are reported herein along with their single‐crystal X‐ray structures detailed characterizations using both, experimental computational techniques. LAlCl ( 1 ) L AlCl were synthesized by treating 3 PhC(N Li in an equivalent ratio : 2, respectively. [LAl(C H 5 )Cl] was prepared from a reaction (C 1. Reactivity , based organo‐aluminum compound is explored for the various reactions. produced )(μ‐F)] 4...