A5102973204- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Metal-Organic Frameworks: Synthesis and Applications
- Crystallography and molecular interactions
- ZnO doping and properties
- Ga2O3 and related materials
- Magnetism in coordination complexes
- Advanced Nanomaterials in Catalysis
- Lanthanide and Transition Metal Complexes
- Gas Sensing Nanomaterials and Sensors
- Polyoxometalates: Synthesis and Applications
- Crystal structures of chemical compounds
- Electronic and Structural Properties of Oxides
- Polymer composites and self-healing
- Advanced biosensing and bioanalysis techniques
- Metal complexes synthesis and properties
- High voltage insulation and dielectric phenomena
- Surface Modification and Superhydrophobicity
- Covalent Organic Framework Applications
- Advanced Photocatalysis Techniques
- Electrochemical sensors and biosensors
- Magnesium Oxide Properties and Applications
- Receptor Mechanisms and Signaling
- Flame retardant materials and properties
- Molecular Sensors and Ion Detection
Sichuan University
2025
Heilongjiang University of Chinese Medicine
2024
Shaanxi University of Science and Technology
2019-2024
Ministry of Education of the People's Republic of China
2023-2024
Northwest University
2021-2024
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry
2008-2023
Jilin University
2011-2023
Changzhou University
2022
Jilin Medical University
2018-2019
Nanjing Tech University
2016
A 3d–4f luminescent metal–organic framework (MOF), [Tb2(Cu8I8)(C12H8NO2)6(H2O)4]·5C4H8O2 (4), and three analogues {[La2(Cu8I8)(C12H8NO2)6(C4H8O2)2(H2O)2]·3C4H8O2·2H2O (1), [Ce2(Cu8I8)(C12H8NO2)6(H2O)4]·5C4H8O2 (2), [Eu2(Cu8I8)(C12H8NO2)6(H2O)4]·5C4H8O2 (3)}, were self-assembled from copper(I) halide clusters lanthanide metal ions with an organic linker [3-(pyridin-4-yl)benzoic acid] under solvothermal conditions. Compound 4 high quantum yield (Φ = 68%) exhibits reversible luminescence...
A copper(I) halide-based compound with a formula of [Cu4I3(DABCO)2]I3 (DABCO = N,N'-dimethyl-1,4-diazabicyclo[2.2.2]octane) has been prepared by solvothermal reactions. This characterized single-crystal X-ray diffraction, elemental analysis, IR, TG, XPS and powder diffractions. Structure analyses reveal that this is constructed unprecedented cationic cluster [Cu8I6](2+) organic ligand DABCO the channels are occupied I2 I(-). The guest I(-) can move freely in out host-framework. UV/vis...
The KNO<sub>3</sub> supported on 3DOM La<sub>0.8</sub>Ce<sub>0.2</sub>Mn<sub>1−x</sub>Fe<sub>x</sub>O<sub>3</sub> perovskites have been prepared and used for soot removal. presence of potassium nitrate can accelerate the combustion at both low high temperature. catalysts exhibit activities combustion.
We demonstrate a magnetic technique for assembling bidisperse and tridisperse colloidal particle fluids into variety of complex structures with dimensionality ranging from 0-D (rings) to 1-D (chains) 2-D (tiles). Compared prior work on particles that are commensurate in size, here we explore the assembly different sized particles, show due packing constraints, new can be realized experimentally. Extending these experiments system, at low concentrations smallest does not change underlying...
Two coordination polymers of {[Mn(maleate)(μ-4,4'-bipy)]·0.5(H2O)}∞ (1) and {[Mn(fumarate)(μ-4,4'-bipy)(H2O)]·0.5(4,4'-bipy)}∞ (2) (bipy = bipyridine) were synthesized structurally characterized. The 1-D [Mn(maleate)]8 chains formed by maleate molecules chelating Mn atoms, these connected with 4,4'-bipy to form a 2-D structure (structure 1). [Mn(fumarate)(H2O)]∞ layers composed the fumarate coordinating different ions, linked give 3-D open framework 2).
Two three-dimensional metal−organic frameworks, [Zn2(OH)(btc)]2(4,4‘-bipy) and Zn2(OH)(btc)(pipe) (btc = 1,3,5-benzenetricarboxylate; 4,4‘-bipy 4,4‘-bipyridine; pipe piperazine) with respectively the largest pure zinc clusters of Zn8(OH)4(O2C−)12 interpenetrating networks, were synthesized by hydrothermal reactions characterized single-crystal X-ray diffraction.
Here we report the anion-induced changes of structures and magnetic properties in binuclear lanthanide compounds. Firstly, two Dy(3+)-based compounds, [Dy2(Mq)4(NO3)6] (1) [Dy2(Mq)4Cl6](EtOH)2 (2) (Mq = 8-hydroxy-2-methylquinoline), were synthesized characterized. They contain similar Dy2O2 cores, while different peripheral anions lead to quite coordination environments Dy(3+) ion. In compound 1, ion is nine-coordinated characterized by a distorted 4,4,4-tricapped trigonal prism environment....
Hydrothermal reactions between mixed ligands (4,4′-oxybis(benzoate) and 1,3-bis(4-pyridyl)propane) Co(NO3)2·6H2O afford two novel helical metal–organic networks Co(C14H8O5)(C13H14N2) 1 Co(C14H8O5)(C13H14N2)·H2O 2. Compound has a 2-D layer network the main body of is composed alternate right-handed left-handed chains by sharing cobalt ions. The distance repeating parts ca. 10.0 Å size channels 7.0 × Å. In contrast, compound 2 interpenetrated double-layer each monolayer homochiral 12.1...
Affinity binding‐induced DNA assembly is a fundamental principle for designing proximity biosensors sensitive and wash‐free protein detection imaging. However, current design strategies these face an intrinsic trade‐off between binding affinity background signal. Here, we demonstrate that this issue can be addressed by using constitutional dynamic chemistry as guiding in the rational of biosensors. As exists equilibrium, network (CDN)‐based adjusted to maximize target while minimize...
Affinity binding‐induced DNA assembly is a fundamental principle for designing proximity biosensors sensitive and wash‐free protein detection imaging. However, current design strategies these face an intrinsic trade‐off between binding affinity background signal. Here, we demonstrate that this issue can be addressed by using constitutional dynamic chemistry as guiding in the rational of biosensors. As exists equilibrium, network (CDN)‐based adjusted to maximize target while minimize...
Charge transfer between LaCoO<sub>3</sub> and La<sub>0.67</sub>Sr<sub>0.33</sub>MnO<sub>3</sub> interface shortens the distance O p-band center Fermi level.