A5055760800- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Catalytic C–H Functionalization Methods
- Oxidative Organic Chemistry Reactions
- Radical Photochemical Reactions
- Chemical Synthesis and Reactions
- Porphyrin and Phthalocyanine Chemistry
- Sulfur-Based Synthesis Techniques
- Polyoxometalates: Synthesis and Applications
- Metal complexes synthesis and properties
- Synthesis and Catalytic Reactions
- Cyclopropane Reaction Mechanisms
- Synthesis and biological activity
- Metal-Organic Frameworks: Synthesis and Applications
- Organometallic Compounds Synthesis and Characterization
- Vanadium and Halogenation Chemistry
- Asymmetric Hydrogenation and Catalysis
- Synthesis and Reactivity of Sulfur-Containing Compounds
- Thermal and Kinetic Analysis
- Free Radicals and Antioxidants
- N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
- Ferrocene Chemistry and Applications
- Crystal structures of chemical compounds
- Synthesis and Biological Activity
- Electrochemical Analysis and Applications
NS Kurnakova Institute of General and Inorganic Chemistry
2018-2022
N.D. Zelinsky Institute of Organic Chemistry
2012-2021
D. Mendeleyev University of Chemical Technology of Russia
2014-2018
Abstract Catalytic reaction of arylhydroxamic acids with alkenes represents a convenient method for preparation biologically active dihydroisoquinolones. Here, the rhodium(III) complex [(C 5 H 2 t Bu CH Bu)RhCl ] , which allows one to carry out such reactions high regioselectivity obtain 4‐substituted dihydroisoquinolones in 72–97 % yields, is described. The provided by bulky cyclopentadienyl ligand catalyst, formed through [2+2+1] cyclotrimerization tert ‐butylacetylene. catalytic tolerates...
Abstract N‐oxyphthalimides are stable and easily accessible compounds that can produce oxygen radicals upon 1‐electron reduction. We present a systematic study of electrochemical properties N‐oxyphthalimide derivatives (PI‐ORs) in DMF by cyclic voltammetry. In all cases, electron transfer to the substrate leads decomposition intermediate radical anion via N―O bond cleavage. case benzyloxyphthalimide or its containing electron‐donating substituents, reductive induces chain phthalimide (PI)...
A method was developed for the bisperoxidation of styrenes with tert-butyl hydroperoxide in presence a catalytic amount manganese(III) acetate. It shown that compounds manganese oxidation states 2, 4, and 7 also catalyze this reaction. The target [1,2-bis(tert-butylperoxy)ethyl]arenes were synthesized yields from 46 to 75%.
Abstract Sodium and potassium tert- butyl peroxide hydrates 2Na + ·2C 4 H 9 $${\text{O}}_{2}^{ - }$$ ·7H 2 O ( I ) 2K · 2C ·4H II were prepared. According to X-ray diffraction data (CIF files CCDC no. 2081025 2081024 )), the compounds are coordination polymers in which alkali metal atoms have C.N.(Na) of 6 or C.N.(K) 8. The crystal packings comprise layers with clearly defined hydrophobic surfaces consisting hydrocarbon groups hydrophilic inner areas including water molecules, cations,...
Abstract Phthalimide (I) plays a dual role in the oxidative cross‐coupling reaction with alkylarenes (II) and (IV).