A5047867173- Metal-Organic Frameworks: Synthesis and Applications
- Chemical Synthesis and Reactions
- Covalent Organic Framework Applications
- Catalytic Processes in Materials Science
- Advanced Photocatalysis Techniques
- Nanomaterials for catalytic reactions
- Multicomponent Synthesis of Heterocycles
- Polyoxometalates: Synthesis and Applications
- Carbon dioxide utilization in catalysis
- Magnetism in coordination complexes
- Oxidative Organic Chemistry Reactions
- X-ray Diffraction in Crystallography
- Catalysis and Hydrodesulfurization Studies
- Asymmetric Hydrogenation and Catalysis
- Molecular Sensors and Ion Detection
- Zeolite Catalysis and Synthesis
- Crystallization and Solubility Studies
- Biodiesel Production and Applications
- Nanocluster Synthesis and Applications
- Graphene research and applications
- Sulfur-Based Synthesis Techniques
- Metal complexes synthesis and properties
- Advanced Nanomaterials in Catalysis
- Supercapacitor Materials and Fabrication
- Catalytic Cross-Coupling Reactions
Universitat Politècnica de València
2013-2025
Madurai Kamaraj University
2016-2025
Instituto de Tecnología Química
2010-2023
Universidad Autónoma de Madrid
2022
Madurai Medical College
2014-2020
Kiel University
2018
Institute of Inorganic Chemistry of the Slovak Academy of Sciences
2017
Centro Médico Sanitas Valencia
2015
Green Chemistry
2014
Consejo Superior de Investigaciones Científicas
2012-2013
The shortage of fossil fuels and the need to find alternative renewable sustainable for transportation are triggering an increasing interest in photocatalytic reduction CO2. In this review, we have focused on titanium containing photocatalysts that effect CO2 fuels. various products more generally formed CH4, CH3OH, CO as well HCOOH. This review has been organized primarily depending type material used photocatalyst. list includes pure TiO2 metal- non metal-doped titania, noble metals...
Metal–organic frameworks (MOFs) are porous crystalline materials that have promising applications as heterogeneous catalysts. After describing the composition, textural properties and crystal structure of four commercially available MOFs, we summarize organic transformations for which these commercial MOFs exhibit higher catalytic activity than corresponding soluble metal salts or ion-exchanged zeolites. In present article, focused on reactions requiring Lewis-acid sites redox centers to...
In this Perspective, we describe the use of metal–organic frameworks (MOFs) as heterogeneous catalysts for oxidations using hydroperoxides or molecular oxygen. These two types oxidants fulfill requirements green chemistry in terms environmental benignity and sustainability. For sake clarity to illustrate possibilities MOFs oxidation catalysts, have constrained ourselves present results obtained cycloalkanes, benzylic positions, cycloalkenes aerobic alcohols. The enantioselective has been...
This review focuses on the use of metal organic frameworks (MOFs) as catalysts for synthesis fine chemicals. While petrochemistry is characterized by gas phase reactions, in which MOFs cannot compete with robust zeolites, are better suited liquid reactions performed at moderate temperatures. These conditions typically employed production chemicals being more complex and diverse molecules low volatility, but high added value. For preparation this type compound, offer advantage wide open...
Abstract Metal organic frameworks (MOFs) are currently attracting considerable attention as heterogeneous catalysts at moderate temperatures, mainly for liquid‐phase reactions. Since structural stability is one of the major concerns use MOFs in catalysis, particularly considering that frequently some reported MOF materials very unstable, interest this area has been focused on those exhibiting highest robustness, UiO‐66 being among most widely used. Two introductory sections deal with...
Two porous iron trimesates, namely, commercial Basolite F300 (Fe(BTC); BTC = 1,3,5-benzenetricarboxylate) with unknown structure and synthetic MIL-100(Fe) (MIL stands for Material of Institut Lavoisier) well-defined crystalline structure, have been compared as heterogeneous catalysts four different reactions. It was found that while catalytic processes requiring strong Lewis acid sites, Fe(BTC) performs better, is the preferred catalyst oxidation These results rationalized by a combined in...
This review illustrates the recent developments in heterogeneous catalysis using mixed metal or linker MOFs.
This article reviews some of the compelling evidence showing that colloidal gold nanoparticles without any solid support exhibit intrinsic catalytic activity for typical gold-catalyzed reactions including CO oxidation, aerobic oxidation alcohols and diols, borohydride reductions carbon–carbon cross coupling reaction among other reactions. A critical view state-of-the-art indicating open issues such as role nature concentration ligand possibility preparing samples with preferential...
Abstract This review summarizes the use of metal organic frameworks (MOFs) as solid catalysts for condensation reactions. After an introductory section, in which reactions are generally presented, a list MOFs employed catalyst is given. The main part present organized according to acids, bases or bi‐functional solids containing both acid and basic sites. Throughout review, emphasis has been made on discussing stability MOFs, their reusability providing comparison performance with respect...
The present review describes the state of art use metal organic framework (MOF)-encapsulated Au nanoparticles (NPs) as heterogeneous catalysts. purpose is to show that catalysts with very good performance, frequently among most active reported so far, can be obtained by incorporation NPs inside MOFs. available data indicate high catalytic activity MOF-encapsulated derives from (i) small particle size, (ii) dispersion and homogeneous distribution MOFs crystals, (iii) stabilization size...
Abstract Mixed‐metal metal–organic frameworks (MM‐MOFs) can be considered to those MOFs having two different metals anywhere in the structure. Herein we summarize various strategies for preparation of MM‐MOFs and some their applications adsorption, gas separation, catalysis. It is shown that compared homometallic MOFs, bring about opportunity take advantage complexity synergism derived from presence metal ions structure MOFs. This reflected a superior performance even stability respect...