Amarajothi Dhakshinamoorthy

ORCID: 0000-0003-0991-6608
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About
Contact & Profiles
Research Areas
  • Metal-Organic Frameworks: Synthesis and Applications
  • Chemical Synthesis and Reactions
  • Covalent Organic Framework Applications
  • Catalytic Processes in Materials Science
  • Advanced Photocatalysis Techniques
  • Nanomaterials for catalytic reactions
  • Multicomponent Synthesis of Heterocycles
  • Polyoxometalates: Synthesis and Applications
  • Carbon dioxide utilization in catalysis
  • Magnetism in coordination complexes
  • Oxidative Organic Chemistry Reactions
  • X-ray Diffraction in Crystallography
  • Catalysis and Hydrodesulfurization Studies
  • Asymmetric Hydrogenation and Catalysis
  • Molecular Sensors and Ion Detection
  • Zeolite Catalysis and Synthesis
  • Crystallization and Solubility Studies
  • Biodiesel Production and Applications
  • Nanocluster Synthesis and Applications
  • Graphene research and applications
  • Sulfur-Based Synthesis Techniques
  • Metal complexes synthesis and properties
  • Advanced Nanomaterials in Catalysis
  • Supercapacitor Materials and Fabrication
  • Catalytic Cross-Coupling Reactions

Universitat Politècnica de València
2013-2025

Madurai Kamaraj University
2016-2025

Instituto de Tecnología Química
2010-2023

Universidad Autónoma de Madrid
2022

Madurai Medical College
2014-2020

Kiel University
2018

Institute of Inorganic Chemistry of the Slovak Academy of Sciences
2017

Centro Médico Sanitas Valencia
2015

Green Chemistry
2014

Consejo Superior de Investigaciones Científicas
2012-2013

The shortage of fossil fuels and the need to find alternative renewable sustainable for transportation are triggering an increasing interest in photocatalytic reduction CO2. In this review, we have focused on titanium containing photocatalysts that effect CO2 fuels. various products more generally formed CH4, CH3OH, CO as well HCOOH. This review has been organized primarily depending type material used photocatalyst. list includes pure TiO2 metal- non metal-doped titania, noble metals...

10.1039/c2ee21948d article EN Energy & Environmental Science 2012-01-01

Metal–organic frameworks (MOFs) are porous crystalline materials that have promising applications as heterogeneous catalysts. After describing the composition, textural properties and crystal structure of four commercially available MOFs, we summarize organic transformations for which these commercial MOFs exhibit higher catalytic activity than corresponding soluble metal salts or ion-exchanged zeolites. In present article, focused on reactions requiring Lewis-acid sites redox centers to...

10.1039/c2cc34329k article EN Chemical Communications 2012-01-01

In this Perspective, we describe the use of metal–organic frameworks (MOFs) as heterogeneous catalysts for oxidations using hydroperoxides or molecular oxygen. These two types oxidants fulfill requirements green chemistry in terms environmental benignity and sustainability. For sake clarity to illustrate possibilities MOFs oxidation catalysts, have constrained ourselves present results obtained cycloalkanes, benzylic positions, cycloalkenes aerobic alcohols. The enantioselective has been...

10.1039/c1cy00068c article EN Catalysis Science & Technology 2011-01-01

This review focuses on the use of metal organic frameworks (MOFs) as catalysts for synthesis fine chemicals. While petrochemistry is characterized by gas phase reactions, in which MOFs cannot compete with robust zeolites, are better suited liquid reactions performed at moderate temperatures. These conditions typically employed production chemicals being more complex and diverse molecules low volatility, but high added value. For preparation this type compound, offer advantage wide open...

10.1039/c3cy00350g article EN Catalysis Science & Technology 2013-01-01

Abstract Metal organic frameworks (MOFs) are currently attracting considerable attention as heterogeneous catalysts at moderate temperatures, mainly for liquid‐phase reactions. Since structural stability is one of the major concerns use MOFs in catalysis, particularly considering that frequently some reported MOF materials very unstable, interest this area has been focused on those exhibiting highest robustness, UiO‐66 being among most widely used. Two introductory sections deal with...

10.1002/cctc.201801452 article EN ChemCatChem 2018-11-26

Two porous iron trimesates, namely, commercial Basolite F300 (Fe(BTC); BTC = 1,3,5-benzenetricarboxylate) with unknown structure and synthetic MIL-100(Fe) (MIL stands for Material of Institut Lavoisier) well-defined crystalline structure, have been compared as heterogeneous catalysts four different reactions. It was found that while catalytic processes requiring strong Lewis acid sites, Fe(BTC) performs better, is the preferred catalyst oxidation These results rationalized by a combined in...

10.1021/cs300345b article EN ACS Catalysis 2012-08-17

This review illustrates the recent developments in heterogeneous catalysis using mixed metal or linker MOFs.

10.1039/c6cy00695g article EN Catalysis Science & Technology 2016-01-01

This article reviews some of the compelling evidence showing that colloidal gold nanoparticles without any solid support exhibit intrinsic catalytic activity for typical gold-catalyzed reactions including CO oxidation, aerobic oxidation alcohols and diols, borohydride reductions carbon–carbon cross coupling reaction among other reactions. A critical view state-of-the-art indicating open issues such as role nature concentration ligand possibility preparing samples with preferential...

10.1039/c2cy20068f article EN Catalysis Science & Technology 2012-06-13

The present review describes the state of art use metal organic framework (MOF)-encapsulated Au nanoparticles (NPs) as heterogeneous catalysts. purpose is to show that catalysts with very good performance, frequently among most active reported so far, can be obtained by incorporation NPs inside MOFs. available data indicate high catalytic activity MOF-encapsulated derives from (i) small particle size, (ii) dispersion and homogeneous distribution MOFs crystals, (iii) stabilization size...

10.1021/acscatal.6b03386 article EN ACS Catalysis 2017-03-07

Abstract Mixed‐metal metal–organic frameworks (MM‐MOFs) can be considered to those MOFs having two different metals anywhere in the structure. Herein we summarize various strategies for preparation of MM‐MOFs and some their applications adsorption, gas separation, catalysis. It is shown that compared homometallic MOFs, bring about opportunity take advantage complexity synergism derived from presence metal ions structure MOFs. This reflected a superior performance even stability respect...

10.1002/ange.201902229 article EN Angewandte Chemie 2019-04-12

This perspective summarizes the catalytic activity of K10 montmorillonite as a multifunctional catalyst for organic reactions.

10.1039/c4cy00112e article EN Catalysis Science & Technology 2014-01-01
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