A5076407642- Metal-Organic Frameworks: Synthesis and Applications
- Covalent Organic Framework Applications
- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Viral-associated cancers and disorders
- Animal Diversity and Health Studies
- Cytomegalovirus and herpesvirus research
- Catalytic Processes in Materials Science
- Extracellular vesicles in disease
- Minerals Flotation and Separation Techniques
- Carbon dioxide utilization in catalysis
- Cancer-related molecular mechanisms research
- Nanocluster Synthesis and Applications
- Parvovirus B19 Infection Studies
- Membrane Separation and Gas Transport
- Advancements in Battery Materials
- Advanced Photocatalysis Techniques
- Rangeland Management and Livestock Ecology
- Zeolite Catalysis and Synthesis
- TiO2 Photocatalysis and Solar Cells
- Advanced Nanomaterials in Catalysis
- Advanced biosensing and bioanalysis techniques
- Machine Learning in Materials Science
- Advanced NMR Techniques and Applications
- Circular RNAs in diseases
University of California, Riverside
2019-2025
PLA Navy General Hospital
2024
Xi'an University of Science and Technology
2019-2024
Xiamen Institute of Rare-earth Materials
2024
Chinese Academy of Sciences
2024
ShanghaiTech University
2024
University of Chinese Academy of Sciences
2024
Second Military Medical University
2017-2023
Inner Mongolia Agricultural University
2019-2022
Xiamen University
2021
Flexi-MOFs are typically limited to low-connected (<9) frameworks. Here we report a platform-wide approach capable of creating family high-connected materials (collectively called CPM-220) that integrate exceptional framework flexibility with high rigidity. We show the multi-module nature pore-space-partitioned pacs (partitioned acs net) platform allows us introduce as well simultaneously impose rigidity in tunable module-specific fashion. The inter-modular synergy has remarkable...
Metal-organic frameworks (MOFs) have many attractive features, including tunable composition, rigid structure, controllable pore size, and large specific surface area, thus are highly applicable in molecular analysis. Depending on the MOF a high number of unsaturated metal sites can be exposed to catalyze chemical reactions. In present work, we report that using both Co(II) Fe(III) prepare MIL-88(NH2) MOF, produce bimetallic conversion 3,3',5,5″-tetramethylbenzidine (TMB) color product...
Multi-module design of framework materials with multiple distinct building blocks has attracted much attention because such are more amenable to compositional and geometrical tuning thus offer opportunities for property optimization. Few examples known that use environmentally friendly cost-effective solvent-free method synthesize materials. Here, we report the (also modulator-free) a series multi-module MOFs high stability separation C2 H2 /CO2 . The synthesis only requires simple mixing...
Although metal‐organic frameworks are coordination‐driven assemblies, the structural prediction and design using metal‐ligand interactions can be unreliable due to other competing interactions. Leveraging non‐coordination develop porous assemblies could enable new materials applications. Here, we use a multi‐module MOF system explore important pervasive impact of ligand‐ligand on as well co‐assembly process. It is found that play critical roles scope or breakdown isoreticular chemistry. With...
Molybdenum disulfide with a layered structure and high theoretical capacity is attracting extensive attention for high-performance lithium-ion batteries. In this study, simple scalable method by freeze-drying of (NH4)2MoS4 dopamine mixed solutions along subsequent calcination developed to realize the self-assembly hierarchical MoS2/carbon composite nanosheets via effect dopamine-induced morphology transformation, in which ultrasmall few-layer MoS2 were homogeneously embedded into N-doped...
Antibacterial peptides were isolated and purified from whey proteins of camel milk (CaW) cow (CoW) their antimicrobial activities studied. The hydrolyzed using trypsin, the degree hydrolysis was identified by gel electrophoresis. hydrolysate (WH) ultrafiltration Dextran chromatography to obtain small with antibacterial activity. effect on morphology bacterial strains investigated transmission electron microscopy. Their amino acid composition then determined. Polypeptides CaWH-III (<3 kDa)...
A new perspective is proposed in the design of pore-space-partitioned MOFs that focused on ligand symmetry properties sub-divided here into three hierarchical levels: 1) overall ligand, 2) substructure such as backbone or core, and 3) substituent groups. Different combinations above exist. Given close correlation between nature chemical moiety its symmetry, a unique sub-symmetry MOF translates influences properties. Five have been prepared exhibit excellent hydrothermal stability...
Metal–Organic Frameworks (MOFs) can deliver many advantages when acting as enzyme mimics to assist with signal amplification in molecular detection: they have abundant active catalytic sites per unit volume of the material; their structures and elemental compositions are highly tunable, high specific surface area porous property target separation enrichment. In present work, we demonstrated that, by adding pore partition agent, 2,4,6-tris(4-pyridyl)pyridine (TPY) during synthesis bimetallic...
Compared to exploratory development of new structure types, pushing the limits isoreticular synthesis on a high-performance MOF platform may have higher probability achieving targeted properties. Multi-modular platforms could offer even more opportunities by expanding scope chemistry. However, navigating chemistry towards best properties multi-modular is challenging due multiple interconnected pathways. Here pacs (partitioned acs) platform, we demonstrate accessibility regime pore geometry...
Camel milk is considered as an essential source of nutrition for desert people. However, few studies have investigated how geography affects Bactrian camel in Mongolia. In this study, we evaluated the differences gross composition, fatty acid and amino composition among samples collected from 102 camels five different Mongolian regions. The proportion long-chain acids, out total was high all milk. primary acids detected were palmitic (23.99-30.72%), oleic (17.21-24.24%), stearic...
Morbidity and mortality as a result of liver disease are major problems around the world, especially from alcoholic (ALD), which is characterized by hepatic inflammation intestinal microbial imbalance. In this study, we investigated hepatoprotective effects camel milk (CM) in mouse model acute ALD underlying mechanism at gut microbiota transcriptome level. Male Institute Cancer Research mice (n = 24; Beijing Weitong Lihua Experimental Animal Technology Co. Ltd., China) were divided into 3...
Abstract Zeolitic imidazolate frameworks (ZIFs) are traditionally synthesized solvothermally by using cost‐ and waste‐incurring organic solvents. Here, a direct synthesis method is reported for ZIF‐8, ZIF‐67, their heterometallic versions from solid precursors only. This solvent‐free crystallization not only completely avoids solvents, but also provides an effective path the of homogeneous mixed‐metal ZIFs. Furthermore, under templating NaCl/ZnCl 2 eutectic salt, carbonization ZIF materials...
To investigate the determining risk factors for 1-year postoperative mortality in elderly patients with hip fracture and to assess efficacy of age-adjusted Charlson comorbidity index (ACCI) predicting death. This study adopted a retrospective analysis method focus on 652 who underwent surgery between January 2018 November 2022 our hospital. By systematically combing patients’ medical records, relevant data were collected analyzed depth their association morbidity rates within 1 year. In...
Although metal‐organic frameworks are coordination‐driven assemblies, the structural prediction and design using metal‐ligand interactions can be unreliable due to other competing interactions. Leveraging non‐coordination develop porous assemblies could enable new materials applications. Here, we use a multi‐module MOF system explore important pervasive impact of ligand‐ligand on as well co‐assembly process. It is found that play critical roles scope or breakdown isoreticular chemistry. With...
The mechanical behavior of pure Pt at elevated temperatures is critical for its high-temperature processing and applications. To understand thermal deformation reach better control, compression was conducted in this work with a strain rate 0.01 s−1 ranging from 500 to 700 °C, followed by microstructure characterization using electron backscatter diffraction (EBSD) technique. results indicate that the grain size, fraction low-angle boundaries, dislocation density are generally reduced...
Significance Kaposi's sarcoma-associated herpesvirus (KSHV) and EBV are cancer-causing human herpesviruses. Their smallest capsid proteins (SCPs) were shown to be required for assembly potential drug targets curbing viral infections, but how they work is unclear. By cryoEM genetic engineering, we determine the structures of KSHV capsids bearing full-length or truncated SCPs localize regions SCP that important assembly. We show a long kinked helix cross-links neighboring subunits major...