A5057988449- Magnetism in coordination complexes
- Organic and Molecular Conductors Research
- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Molecular Junctions and Nanostructures
- Electron Spin Resonance Studies
- Crystallography and molecular interactions
- Porphyrin and Phthalocyanine Chemistry
- Lanthanide and Transition Metal Complexes
- Photochemistry and Electron Transfer Studies
- Synthesis and Properties of Aromatic Compounds
- Metal-Organic Frameworks: Synthesis and Applications
- Luminescence and Fluorescent Materials
- Organic Electronics and Photovoltaics
- Organic Light-Emitting Diodes Research
- Conducting polymers and applications
- Perovskite Materials and Applications
- Solid-state spectroscopy and crystallography
- Fullerene Chemistry and Applications
- Molecular spectroscopy and chirality
- Advanced NMR Techniques and Applications
- Molecular Sensors and Ion Detection
- Phase Equilibria and Thermodynamics
- Surface Chemistry and Catalysis
- Graphene research and applications
Institut de Ciència de Materials de Barcelona
2016-2025
Biomedical Research Networking Center in Bioengineering, Biomaterials and Nanomedicine
2016-2025
Instituto de Ciencia de Materiales de Sevilla
2006-2025
Technical University of Munich
2004-2025
Instituto de Salud Carlos III
2022-2024
Universitat Autònoma de Barcelona
2007-2022
Centro de Investigación Biomédica en Red
2014-2021
Bioengineering Center
2014-2020
Centre for Research on Ecology and Forestry Applications
2015-2019
Weatherford College
2019
The use of organic molecules as an alternative strategy for achieving new nanoporous metal–organic materials has become attractive prospect. So far, the chemical coordination or crystal engineering techniques allows systematic design open-framework structures with a considerable range modulatable pore sizes and functionalities using different ligands such phosphane, cyano groups, N,N′-type polycarboxylic acids. Furthermore, transition metal ions opens possibility to obtain additional...
Two new chemosensors that exhibit high affinity and selectivity for Hg2+ in aqueous environment which operate through two different channels, optic/redox optic/fluorescent, are reported. The optical change sensing can be used even a "naked-eye" detection of ions, whereas the fluorescent response modulated by varying solvent polarity.
Recently, it was reported that crystals of the organic material dithiophene-tetrathiafulvalene (DT-TTF) have a high field-effect charge carrier mobility 1.4 cm2/(V·s). These were formed by simple drop-casting method, making this interesting to investigate for possible applications in low-cost electronics. Here, single-crystal transistors based on materials related DT-TTF are presented and clear correlation between crystal structure electrical characteristics is observed. The observed...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTInert carbon free radicals. 8. Polychlorotriphenylmethyl radicals: synthesis, structure, and spin-density distributionO. Armet, J. Veciana, C. Rovira, Riera, Castaner, E. Molins, Rius, Miravitlles, S. Olivella, BrichfeusCite this: Phys. Chem. 1987, 91, 22, 5608–5616Publication Date (Print):October 1, 1987Publication History Published online1 May 2002Published inissue 1 October...
The two-dimensional self-assembly of a terbium(III) double-decker phthalocyanine on highly oriented pyrolitic graphite (HOPG) was studied by atomic force microscopy (AFM), and it shown that forms regular rectangular nanocrystals the surface, are aligned with symmetry axes, in which molecules organized lattice as scanning tunneling microscopy. Molecular dynamics simulations were run order to model behavior collection complexes HOPG. results excellent agreement experiment, showing that—after...
The novel and exciting field of molecular spintronics has recently attracted a great deal interest promising results have already been reported. utilisation organic radicals that could favour spin polarisation conservation during transport offers new possibilities; however, first fundamental investigation these materials, especially those deposited on surfaces, is required. Here we highlight our recent regarding the functionalisation surfaces with polychlorotriphenylmethyl (PTM) following...
A terbium double-decker phthalocyanine complex has been prepared and characterized. The mesomorphism of the liquid-crystalline is used as a tool to reversibly adjust its magnetic properties, thus allowing coexistence two different relaxation processes, which can be modified by simple thermal treatments, observed. Detailed facts importance specialist readers are published "Supporting Information". Such documents peer-reviewed, but not copy-edited or typeset. They made available submitted...
Organic radicals are neutral, purely organic molecules exhibiting an intrinsic magnetic moment due to the presence of unpaired electron in molecule its ground state. This property, added low spin–orbit coupling and weak hyperfine interactions, make neutral good candidates for molecular spintronics insofar as radical character is stable solid state electronic devices. Here we show that paramagnetism polychlorotriphenylmethyl form a Kondo anomaly preserved two- three-terminal solid-state...
In electronics, the field‐effect transistor (FET) is a crucial cornerstone and successful integration of this semiconductor device into circuit applications requires stable ideal electrical characteristics over wide range temperatures environments. Solution processing, using printing or coating techniques, has been explored to manufacture organic transistors (OFET) on flexible carriers, enabling radically novel electronics applications. Ideal characteristics, in materials, are typically only...
General-purpose quantum computation and simulation require multi-qubit architectures with precisely defined, robust interqubit interactions, coupled local addressability. This is an unsolved challenge, primarily due to scalability issues. These issues often derive from poor control over interactions. Molecular systems are promising materials for the realization of large-scale architectures, their high degree positionability possibility tailor The simplest architecture two-qubit system, which...
Magnetic avalanches: A chiral polymeric manganese(II) complex with an enantiopure nitronyl nitroxide ligand (see structure of repeating unit; red: oxygen, green: nitrogen, blue: manganese) shows unusual magnetic behavior. The polymer orders magnetically in the bulk at 3 K, and reveals dynamic hysteretic effects as well a remarkable avalanche phenomenon below 0.3 K.
Magnetische Lawinen: Ein chiraler, polymerer Mangan(II)-Komplex mit einem enantiomerenreinen Nitronylnitroxid-Liganden (siehe Struktur der Wiederholungseinheit; O rot, N grün, Mn blau) zeigt ungewöhnliches magnetisches Verhalten. Bei 3 K liegt im Festkörper magnetische Ordnung vor, unterhalb von 0.3 jedoch wurden dynamische und Hystereseeffekte sowie das bemerkenswerte Phänomen einer „magnetischen Lawine“ beobachtet.
An attractive read: Magnetic Mn12 clusters are patterned by molding a dispersion in polymer matrix onto structured master (e.g., DVD). The protrusions of the replica surface disappear on exposure to solvent vapor, and concentrate at positions original protrusions. cluster distribution produces magnetic contrast, which can be imaged force microscopy (see picture).
We report on the fabrication and characterization of field-effect transistors based single crystals organic semiconductor dibenzo-tetrathiafulvalene (DB-TTF). demonstrate that it is possible to prepare very-good-quality DB-TTF from solution. These devices show high mobilities typically in range 0.1–1cm2∕Vs. The temperature dependence was also studied revealing an initial increase mobility when lowering until reached a maximum, after which decreased following thermally activated behavior with...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStable polyradicals with high-spin ground states. 2. Synthesis and characterization of a complete series derived from 2,4,6-trichloro-.alpha.,.alpha.,.alpha.',.alpha.',.alpha.'',.alpha.''-hexakis(pentachlorophenyl)mesitylene S = 1/2, 1, 3/2 statesJaume Veciana, Concepcio Rovira, Nora Ventosa, Maria Isabel Crespo, Fernando PalacioCite this: J. Am. Chem. Soc. 1993, 115, 57–64Publication Date (Print):January 1993Publication History Published online1...