A5100441451- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Metal-Organic Frameworks: Synthesis and Applications
- Covalent Organic Framework Applications
- Magnetism in coordination complexes
- Advanced biosensing and bioanalysis techniques
- Carbon dioxide utilization in catalysis
- Lanthanide and Transition Metal Complexes
- Molecular Sensors and Ion Detection
- Advanced Nanomaterials in Catalysis
- Crystallography and molecular interactions
- Electrochemical Analysis and Applications
- Nanocluster Synthesis and Applications
- Polymer Surface Interaction Studies
- Electrochemical sensors and biosensors
- Enzyme Catalysis and Immobilization
- Electrocatalysts for Energy Conversion
- Geomagnetism and Paleomagnetism Studies
- Polyoxometalates: Synthesis and Applications
- Electrospun Nanofibers in Biomedical Applications
- Metal complexes synthesis and properties
- biodegradable polymer synthesis and properties
- Geology and Paleoclimatology Research
- Biosensors and Analytical Detection
- Sulfur Compounds in Biology
Ministry of Education of the People's Republic of China
2016-2025
Northwest University
2016-2025
Kunming Institute of Precious Metals
2025
PetroChina Southwest Oil and Gas Field Company (China)
2024
Helmholtz-Zentrum Hereon
2024
Zhengzhou University
2023-2024
Jinling Institute of Technology
2024
Institute of Oceanology
2011-2023
Chinese Academy of Sciences
2011-2023
Nanjing Tech University
2010-2023
An efficient multienzyme cascade system based on ultrathin, hybrid microcapsules was constructed for converting CO2 to methanol by combining the unique functions of catechol and gelatin. Gelatin modified with groups (GelC) via well-defined EDC/NHS chemistry, thus endowed ability covalently attach enzyme molecules. Next, first (FateDH)-containing CaCO3 templates were synthesized coprecipitation coated a GelC layer. Afterward, attached second (FaldDH) Michael addition Schiff base reactions....
Herein, three Cd(<sc>ii</sc>)-based MOFs were assembled, and the complex <bold>3</bold> showed a high selectivity in detection of nitrobenzene Fe<sup>3+</sup>.
Four new metal-organic frameworks (MOFs), {[Zn3(L)(OH)(H2O)5]·NMP·2H2O}n (1), {[H2N(Me)2][Zn2(L)(H2O)]·DMF·H2O}n (2), {[Co5(L)2(H2O)11]·2H2O}n (3) and {[Mn5(L)2(H2O)12]·6H2O}n (4), were assembled employing a symmetrical V-shaped rigid multicarboxylic acid ligand H5L (H5L = 2,4-di(3',5'-dicarboxylphenyl)benzoic acid) with different metal ions, resulting in versatile as well various types of coordination modes H5L. 1 forms three-dimensional (3D) 4-connected sra net based on trinuclear...
Abstract Rapid cost reduction of green hydrogen is essential for the large‐scale deployment hydrogen‐based energy system. A major component in achieving this development advanced water electrolyzers. Sluggish oxygen evolution reaction (OER) bottleneck electrolysis, and tremendous efforts have been devoted to develop electrocatalysts that accelerate OER kinetics. Recent advances highlighted potential precious metal‐free electrocatalyst capable stable operation at current densities above 1 cm...
Microcapsules with diverse wall structures may exhibit different performance in specific applications. In the present study, three kinds of mussel-inspired polydopamine (PDA) microcapsules have been prepared by a template-mediated method. More specifically, types CaCO3 microspheres (poly(allylamine hydrochloride), (PAH)-doped CaCO3; pure-CaCO3; and poly(styrene sulfonate sodium), (PSS)-doped CaCO3) were synthesized as sacrificial templates, which then treated dopamine to obtain corresponding...
Biofilms are significant hazards in the food industry. In this study, we investigated effects of additive such as citral, cinnamaldehyde, and tea polyphenols on mixed biofilm formation by foodborne Staphylococcus aureus Salmonella serotype Enteritidis. The adhesion rates strains sub-MIC additives were determined a microtiter plate assay bacterial communication signal autoinducer 2 (AI-2) production via bioluminescence reporter Vibrio harveyi BB170. structure was analyzed using scanning...
Four isostructural lanthanide metal–organic frameworks (Ln-MOFs) {[Ln(L)1.5(H2O)]·4H2O}n (1-Ln) (Ln = Sm, Eu, Gd, and Tb) have been successfully synthesized under solvothermal conditions with 2-(1H-1,2,4-triazol-1-yl) terephthalic acid (H2L) Ln(NO3)3·nH2O (n 0, 6). 1-Ln shows a binodal (3,8)-connected three-dimensional framework that possesses one-dimensional pore channel decorated uncoordinated Lewis basic triazolyl sites. 1-Eu 1-Tb exhibit bright red green emissions absolute quantum yields...
Gossypol (Gsp) and antibiotics present in water bodies become organic pollutants that are harmful to human health the ecological environment. Accurate effective detection of these has far-reaching significance many fields. A new three-dimensional metal-organic framework (MOF), {[Eu
A new synthesis strategy of continuous structure transformation has been studied to construct ordered vacancies for enlarging the pores and enhancing stability MOFs. The was confirmed by single crystal diffraction.
Summary Multicellular magnetotactic prokaryotes (MMPs) are a group of microorganisms composed 10–40 Gram‐negative cells. Currently, all the identified MMPs show spherical morphology and synthesize mainly iron sulfide magnetosomes. In this study, we report novel genus with peculiar ellipsoidal oxide magnetosomes, which were discovered in intertidal sediment Yellow Sea China. Optical fluorescence microscopy revealed that organism was ∼10 × 8 µm size ∼40 cells enveloped by an outer layer....
An exceptionally stable Zn<sub>4</sub>O-MOF has been rationally synthesized, which exhibits high CO<sub>2</sub> capture and efficient catalytic conversion for cycloaddition with epoxides under mild conditions.
We discuss early advances in the preparation of doped graphene and its unique properties as well applications bioanalysis.
Four similar Mn(II) metal–organic frameworks (MOFs), {[Mn2(nbtc)(H2O)2(S)]·S·0.5H2O}n [S = DMF (1), DMA (2), NMP (3), DEF (4)] (DMF N,N′-dimethylformamide, N,N′-dimethylacetamide, N-methyl-2-pyrrolidinone, N,N′-diethylformamide), have been assembled solvothermally from the nitro and carboxyl doubly functionalized ligand 6,6′-dinitro-2,2′,4,4′-biphenyl tetracarboxylic acid (H4nbtc) characterized by single-crystal X-ray diffraction, elemental analyses, infrared spectroscopy, thermogravimetric...
An unusual porous metal-organic framework has been synthesized by using Pb(II) and rigid V-shaped 4,4'-(pyridine-3,5-diyl)diisophthalic acid (H4L). Structure analysis reveals that there exist 1D cylindrical 14.26 Å triangular prism 10.69 × Å3 nanotubes in the framework. Gas sorption behavior of nanoporous MOF shows a relatively high capacity selectivity CO2 over CH4.
Pyroptosis mediated by gasdermin protein has shown great potential in cancer immunotherapies. However, the low expression of proteins and systemic toxicity nonspecific pyroptosis limit its clinical application. Here, we designed a synthetic biology strategy to construct tumor-specific pyroptosis-inducing nanoplatform M-CNP/Mn@pPHS, which plasmid (pPHS) was loaded onto manganese (Mn)-doped calcium carbonate nanoparticle wrapped tumor-derived cell membrane. M-CNP/Mn@pPHS showed an efficient...
Two 3D isostructural metal–organic frameworks with 1D ferrimagnetic chains, formulated as [M3(L)(μ3-OH)2(H2O)4] [H4L = (1,1′:4′,1″-terphenyl)-2′,3,3″,5′-tetracarboxylic acid, where M Mn for 1 and Co 2], have been successfully synthesized by employing different center metal ions a multicarboxylate ligand under identical reaction conditions in this work. The single-crystal X-ray diffraction data of 2 reveal that the complexes are two based on [M3(OH)2]n chains composed triangular subunits...
Three new three-dimensional (3D) luminescent metal–organic frameworks (MOFs), namely, [Zn2(L)2]·2DMA·3H2O (1), [Zn2(L)2]·H2O (2), and [Cd2(L)2]·H2O (3) [H2L = 2-(imidazol-1-yl)terephthalic acid], have been solvothermally synthesized by using d10 metal ions Zn(II)/Cd(II) H2L in different solvent systems, which well characterized elemental analysis, Fourier transform infrared spectroscopy, powder X-ray diffraction, thermogravimetric analysis. As influenced the solvents ions, single-crystal...
Abstract Anti‐UV radiation surface coating is a powerful approach to fabricate functional textile materials that are essential for outdoor workers protect their skin from several diseases. However, the achievement of such anti‐UV with facile procedure still very challenging, as current fabrication protocols usually require sophisticated equipment, complicated procedures, and using hazardous chemicals. In this work, novel technology involving in situ self‐assembly metal–organic frameworks...
A bifunctional ligand strategy for modification of the functional pores is great significance in structural design metal–organic frameworks (MOFs). Herein, a new 2-fold interpenetrated "pillared-layer" 3D Co-MOF, {[Co(HL)(4,4′-bipy)]·DMF·2H2O}n (1), was successfully synthesized by using two kinds ligands, imidazolecarboxylic acid and pyridine. The metal–carboxylic layers are pillared 4,4′-bipy ligand, displaying framework with rectangular channels (high BET surface 190.9 m2 g–1 maximum...