A5101693118- Membrane Separation and Gas Transport
- Membrane Separation Technologies
- Metal-Organic Frameworks: Synthesis and Applications
- MXene and MAX Phase Materials
- Covalent Organic Framework Applications
- Plasma Applications and Diagnostics
- Gas Sensing Nanomaterials and Sensors
National Taiwan University
2020-2023
National Synchrotron Radiation Research Center
2021
Structural flexibility is a critical issue that limits the application of metal-organic framework (MOF) membranes for gas separation. Herein we propose mixed-linker approach to suppress structural CAU-10-based (CAU = Christian-Albrechts-University) membranes. Specifically, pure CAU-10-PDC display high separation performance but at same time are highly unstable CO2/CH4. A partial substitution (30 mol.%) linker PDC with BDC significantly improves its stability. Such an also allows decreasing...
The separation of H2/CH4 or CO2/CH4 is critical to the purification natural gas. Herein, we report on novel membranes with a metal-organic framework CAU-10-PDC for these two mixtures. dense are fabricated porous alumina support using seeded growth method. An unexpected increase in selectivity was observed while testing mixed gas permeation either at molar ratio 50:50. Steady-state reached 101 and 62 CO2/CH4. Ideal measured from single 475 288 Molecular dynamics simulations time-resolved...
Abstract Structural flexibility is a critical issue that limits the applications of MOF membranes for gas separation. Herein we propose mixed-linker approach to suppress structural CAU-10-based membranes. Specifically, pure CAU-10-PDC membrane high separation performance but at same time highly unstable CO 2 /CH 4 . A partial substitution (30 mol.%) linker PDC with BDC significantly improves its stability. Such an also allows aperture size MOFs. The optimized CAU-10-PDC-H (70/30) possesses...