A5020247266- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Catalytic Cross-Coupling Reactions
- Antibiotics Pharmacokinetics and Efficacy
- Catalytic C–H Functionalization Methods
- Solid-state spectroscopy and crystallography
- Synthesis and Biological Evaluation
- Crystallography and molecular interactions
- Molecular Spectroscopy and Structure
- Analytical Chemistry and Chromatography
University of Ljubljana
2020-2025
Hydrogen-bonded cocrystals have attracted considerable attention as they allow fine-tuning of properties through the choice hydrogen-bond donors and acceptors. In this study, triphenylarsine oxide (Ph3AsO) is introduced a strong acceptor molecule. Due to its higher Lewis basicity compared triphenylphosphine (Ph3PO), it acts acceptor, which demonstrated in six new with H2O2 gem-di(hydroperoxy)cycloalkanes. All formed large, high-quality single crystals, were analyzed by X-ray diffraction IR...
Herein we present a mild, simple and environmentally friendly diazotization protocol of aromatic heteroaromatic anilines into stable diazonium salts that surpass previously reported procedures. The reaction proceeds with tert-butyl nitrite in the presence an equimolar amount or small excesses p-toluenesulfonic acid ethyl acetate, at room temperature. o-Phenylenediamines yield benzotriazolium tosylates. resulting tosylates proved to be bench over long period time. In selected examples, were...
The crystal structure of 3-nitrobenzonitrile, C 7 H 4 N 2 O , was elucidated by low-temperature single-crystal X-ray diffraction. compound crystallizes in the Sohncke space group P 1 and features two molecules unit cell. Aromatic π–π stacking leads to stacks [100] direction. absolute established from anomalous dispersion.