A5100453257- Metal-Organic Frameworks: Synthesis and Applications
- Advancements in Battery Materials
- Advanced battery technologies research
- Supercapacitor Materials and Fabrication
- Magnetism in coordination complexes
- Advanced Battery Materials and Technologies
- Crystal structures of chemical compounds
- Perovskite Materials and Applications
- Metal complexes synthesis and properties
- Advanced Battery Technologies Research
- MXene and MAX Phase Materials
- Electrocatalysts for Energy Conversion
- Graphene research and applications
- Polyoxometalates: Synthesis and Applications
- Organic Electronics and Photovoltaics
- Extraction and Separation Processes
- Covalent Organic Framework Applications
- Thin-Film Transistor Technologies
- Quantum Dots Synthesis And Properties
- Lanthanide and Transition Metal Complexes
- Conducting polymers and applications
- Crystallography and molecular interactions
- Advanced Sensor and Energy Harvesting Materials
- Analytical Chemistry and Sensors
- Luminescence Properties of Advanced Materials
Changzhou University
2016-2025
Nanjing University
2015-2025
Catalytic Materials (United States)
2025
Nanyang Normal University
2024
École Polytechnique Fédérale de Lausanne
2020-2023
Harbin Engineering University
2023
Nanjing Forestry University
2022
Anhui Polytechnic University
2022
Luoyang Institute of Science and Technology
2020
Hôpital de Sion
2020
Metal–organic frameworks (MOFs) have recently received increasing interest due to their potential application in the energy storage and conversion field. Herein, cobalt-based layered MOF ({[Co(Hmt)(tfbdc)(H2O)2]·(H2O)2}n, Co–LMOF; Hmt = hexamethylenetetramine; H2tfbdc 2,3,5,6-tetrafluoroterephthalic acid) has been evaluated as an electrode material for supercapacitors. The Co–LMOF exhibits a high specific capacitance excellent cycling stability. Its maximum is 2474 F g–1 at current density...
The phase transformation of a zinc-2-methylimidazole-based zeolitic-imidazolate framework (ZIF), from recently discovered ZIF-L to ZIF-8, was reported. is made up the same building blocks as having two-dimensional crystal lattices stacked layer-by-layer. Results indicated that occurs in solid via geometric contraction model (R2), kinetic new ZIF. monitored by means ex situ powder X-ray diffraction, nitrogen sorption, Fourier transform infrared spectroscopy, selected-area electron scanning...
A 3D Mn-based MOF [Mn(BGPD)(H 2 O) ] (Mn-BGPD) was synthesized. The asymmetrical supercapacitor of Mn-BGPD exhibits an excellent energy density and better cycling stability.
Manganese-based layered coordination polymer ([Mn(tfbdc)(4,4'-bpy)(H2O)2], Mn-LCP) with microporous structure was synthesized by reaction of 2,3,5,6-tetrafluoroterephthalatic acid(H2tfbdc) and 4,4'-bipyridine(4,4'-bpy) manganese(II) acetate tetrahydrate in water solution. Mn-LCP characterized elemental analysis, IR spectra, thermogravimetric X-ray single-crystal powder diffraction. Magnetic susceptibility data from 300 to 1.8K show that there is a weak antiferromagnetic exchange between...
Toluene was discovered as the structure template for synthesis of large-cage RHO-type zeolitic imidazolate frameworks (ZIF-11 and ZIF-12) in an alcohol-based solution where benzimidazole-toluene interactions play a decisive structure-directing role; otherwise it leads to small-cage SOD-type ZIF-7 ZIF-9 without toluene. The specific π-π make toluene molecules adopt oriented arrangement unit cell. XRD intensity (100) plane is strongly dependent on amount toluene: apparent degradation observed...
The layered Mn-based metal–organic framework (Mn-LMOF) displayed good performance as an electrode material for supercapacitors.
Hexafluorohexaazatrinaphthylene, a compound containing strong electron-withdrawing group, presents high capacity, high-rate performance and stability as cathode material for aqueous zinc batteries/flexible batteries.
Chemically self-charging aqueous zinc-ion batteries (AZIBs) via air oxidation will provide new opportunities for future wearable electronic devices. Herein, we display two high-performance flexible AZIBs based on a trifluorohexaazatrinaphthylene (TFHATN)/trichlorohexaazatrinaphthylene (TCLHATN) cathode, which can be recharged without using an external power supply. The Zn//TFHATN/Zn//TCLHATN battery presents good mechanical flexibility and high volumetric energy density of 9.2/10.7 mWh cm–3....
A layered copper-based coordination polymer ([Cu(hmt)(tfbdc)(H<sub>2</sub>O)], Cu-LCP) has been synthesized, which shows ferromagnetic interactions between the adjacent copper(<sc>ii</sc>) ions and an excellent capacitive performance in supercapacitors.
Recently, metal-organic frameworks (MOFs), which are porous inorganic-organic hybrid materials consisting of metal ions (clusters or secondary building units) and organic ligands through coordination bonds, have attracted wide attention because their high surface area, huge ordered porosity, uniform structural cavities, excellent thermal/chemical stability. In this work, durian shell biomass carbon fiber Fe3O4 functionalized framework composite material (durian fiber-Fe3O4-MOF, DFM) was...
Our method hinders the Ostwald ripening of polycrystalline MOF film during solvothermal synthesis, allowing growth high-quality films in just 8 min at room temperature.
Distinguishing the delicate structural differences among molecules is a critical and challenging task in biological/chemical analysis. A molecular decoding strategy has recently become promising to differentiate similar molecules, which advantageous over common sensing methods mostly used for detecting single target. However, design of an ideal decoder still strictly hindered by tailored preparation probes particular severe lack widespread feasibility. We herein first time proposed use...
A zinc-based one-dimensional (1D) coordination polymer ([Zn(H2mpca)2(tfbdc)(H2O)], Zn-ODCP) has been synthesized and characterized by spectroscopic physicochemical methods, single-crystal X-ray diffraction, thermogravimetric analysis (H2mpca = 3-methyl-1H-pyrazole-4-carboxylic acid; H2tfbdc 2,3,5,6-tetrafluoroterephthalic acid). Zn-ODCP shows blue luminescence in the solid state. When acts as an anode material for lithium ion batteries, it exhibits a good cyclic stability higher reversible...
A three-dimensional (3D) copper-based coordination polymer, ([Cu(H2mpca)(tfbdc)], Cu-CP; H2mpca = 3-methyl-1H-pyrazole-4-carboxylic acid; H2tfbdc 2,3,5,6-tetrafluoroterephthalic acid), has been synthesized and characterized by IR spectroscopy, thermogravimetric analysis, elemental single-crystal X-ray diffraction. In Cu-CP, each Cu(II) ion is located in a triangular bipyramid geometry, these ions are linked tfbdc2– ligands to produce 3D network. Variable-temperature magnetic susceptibility...
Layered cobalt-based coordination polymer ([Co(tfbdc) (4,4′-bpy)(H<sub>2</sub>O)<sub>2</sub>], Co-LCP) nanosheets have been synthesized, which show an excellent performance as anode materials for lithium ion batteries.