A5101440540- Inorganic Chemistry and Materials
- Advanced Condensed Matter Physics
- Iron-based superconductors research
- Topological Materials and Phenomena
- Transition Metal Oxide Nanomaterials
- MXene and MAX Phase Materials
- 2D Materials and Applications
- Chalcogenide Semiconductor Thin Films
- Polyoxometalates: Synthesis and Applications
- Magnetic and transport properties of perovskites and related materials
- Advanced Thermoelectric Materials and Devices
- Quantum Dots Synthesis And Properties
- Radioactive element chemistry and processing
- Nuclear Materials and Properties
- Boron and Carbon Nanomaterials Research
- Crystallization and Solubility Studies
- Advanced Photocatalysis Techniques
- X-ray Diffraction in Crystallography
- Rare-earth and actinide compounds
- Electronic and Structural Properties of Oxides
- Catalysis and Oxidation Reactions
Iowa State University
2021-2024
Metavanadates MV2O6−δ (M = Zn and Cu) are synthesized by using a deep eutectic solvent (DES), mixture of hydrogen bond donor acceptor, as reaction medium. Dissolution stable binary metal oxides in DES followed heat treatment yields phase-pure vanadates. According to situ powder X-ray diffraction, ternary phases (α-Zn2V2O7 β-Cu2–xV2O7, x ∼ 0.27) intermediates the pathway taken. Identifying polymorphic phase transformation temperature for CuV2O6 well narrow range between formation...
A precipitation method involving a deep eutectic solvent (DES)─a mixture of hydrogen bond donor and acceptor─is used to synthesize ternary metal oxide. Without toxic reagents, precipitates consisting Zn3(OH)2V2O7·nH2O Zn5(OH)6(CO3)2 are obtained by simply introducing deionized H2O the DES solution containing dissolved ZnO V2O5. Manipulation synthetic conditions demonstrates high tunability in size/morphology two-dimensional nanosheets precipitated during dynamic equilibrium process....
Kagome compounds have garnered attention in the past few years for their intriguing magnetic properties arising from spin frustration dictated by geometry of sublattice. In this paper, we highlight success unconventional hydride route fast and easy synthesis compound $\mathrm{K}{\mathrm{V}}_{6}{\mathrm{Sb}}_{6}$. High-temperature situ powder x-ray diffraction (PXRD) studies proved to be useful hinting at existence $\mathrm{K}{\mathrm{V}}_{6}{\mathrm{Sb}}_{6}$, identifying its conditions,...
AgBiS2 and Cu3BiS3 were synthesized via a microwave-assisted solution route using deep eutectic solvent (DES). The DES of choice consists choline chloride thiourea, with thiourea acting as sulfur source. synthesis provides fast, environmentally friendly, low-temperature alternative to high-temperature (HT) synthesis. We compared the from an aqueous determined that is preferred for Cu3BiS3, while deionized water better AgBiS2. syntheses proceed Bi2S3 intermediate reacts +1 cations in when...
2D materials showcase unconventional properties emerging from quantum confinement effects. In this work, a "soft chemical" route allows for the deintercalation of K
Achieving kinetic control to synthesize metastable compounds is a challenging task, especially in solid-state reactions where the diffusion slow. Another challenge unambiguous crystal structure determination for when high-quality single crystals suitable single-crystal X-ray diffraction are inaccessible. In this work, we report an unconventional means of synthesis and effective strategy solve unprecedented compound LiNi12B8. This can only be produced upon heating layered boride, HT-Li0.4NiB...
The intermetallic compound LiMnBi was synthesized by the two-step solid-state reaction from elements. A synthesis temperature of 850 K selected based on in situ high-temperature powder X-ray diffraction data. crystalizes layered-like PbClF structure type (a = 4.3131(7) Å, c 7.096(1) Å at 100 K, P4/nmm space group, Z 2). is built alternating [MnBi] and Li layers, as determined single-crystal Magnetic property measurements 7Li nuclear magnetic resonance data collected for polycrystalline...
Investigating material properties is essential to assessing their application potential. While computational methods allow for a fast prediction of the structure and properties, experimental validation determining ultimate Herein, we report synthesis magnetic three previously reported Kagome compounds in Li-Fe-Ge system. LiFe