- Conducting polymers and applications
- Radical Photochemical Reactions
- Catalytic C–H Functionalization Methods
- Metal-Organic Frameworks: Synthesis and Applications
- Advanced biosensing and bioanalysis techniques
- Sulfur-Based Synthesis Techniques
- Perovskite Materials and Applications
- Covalent Organic Framework Applications
- Advanced Photocatalysis Techniques
- Caching and Content Delivery
- Additive Manufacturing Materials and Processes
- Advanced Combustion Engine Technologies
- Peer-to-Peer Network Technologies
- Electrowetting and Microfluidic Technologies
- 2D Materials and Applications
- Membrane Separation and Gas Transport
- Organic Electronics and Photovoltaics
- Crystallization and Solubility Studies
- Cellular and Composite Structures
- Atmospheric chemistry and aerosols
- Advanced Biosensing Techniques and Applications
- Metal Alloys Wear and Properties
- Additive Manufacturing and 3D Printing Technologies
- Advanced materials and composites
- Electrochemical sensors and biosensors
University of Arizona
2025
Nanjing Normal University
2024
University of Göttingen
2023-2024
Alibaba Group (United States)
2024
Nankai University
2024
Southeast University
2021
Georgia Institute of Technology
2021
China University of Mining and Technology
2020-2021
Central South University
2020-2021
Nanjing Agricultural University
2021
Abstract All‐optical modulators, where one light modulates the parameters of another (intensity, phase, frequency, etc.) without external electronic control, have drawn extraordinary attention in all‐optical information processing. In this contribution, by taking advantage two‐pass structure Michelson interferometer and strong photothermal conversion efficiency MXene nanomaterials, an modulator is demonstrated with a modulation depth >27 dB, free spectrum range 16.8 nm pump‐induced phase...
Chiral metal–organic frameworks have attracted interest for enantioselective separations and catalysis because of their high crystallinity pores with tunable shapes, sizes, chemical environments. the type M2(dobpdc) (M = Mg, Mn, Fe, Co, Ni, Zn; dobpdc4– 4,4′-dioxidobiphenyl-3,3′-dicarboxylate) seem particularly promising potential applications excellent stability, internal surface areas, strongly polarizing open metal coordination sites within channels, but to date these materials been...
The photo-induced azole C–H arylation was realized with a dual-catalytic copper-based system. Exceedingly mild reaction conditions at ambient temperature and visible light irradiation enabled broad scope high functional group tolerance.
Rhodium(III)-catalyzed enantioselective C–H activation has emerged as a powerful tool for assembling enabling chiral molecules. However, this approach is significantly hampered by the cumbersome synthetic routes preparing rhodium catalysts. In sharp contrast, we herein report on an electrochemical domino catalysis system that exploits achiral Cp*-rhodium catalyst along with easily accessible Brønsted base activation/annulation reaction of alkenes benzoic acids. Our strategy offers...
C–O axially chiral diaryl ethers play important roles in natural products and bioactive molecules, but because of the low rotational barrier strict steric hindrance requirements, catalytic asymmetric construction still remains a challenge. Herein, we devised strategy employing achiral azlactone for desymmetrization prochiral diamines under catalysis phosphoric acid. The targeted were obtained very good yields (up to 98%) high enantioselectivities >99.5:0.5 er). synthetic utility was...
Mitochondrial antiviral-signaling protein (MAVS) is a key adapter required for inducing type I interferons (IFN-Is) and other antiviral effector molecules. The formation of MAVS aggregates on mitochondria essential its activation; however, the regulatory mitochondrial factor that mediates aggregation process unknown. Our recent work has identified Aggregatin as critical seeding β-amyloid peptide aggregation. Here we show serves cross-seed to orchestrate innate immune signaling. primarily...
Abstract The production of ammonia (NH 3 ) from nitrogen sources involves competitive adsorption different intermediates and multiple electron proton transfers, presenting grand challenges in catalyst design. In nature nitrogenases reduce dinitrogen to NH using two component proteins, which electrons protons are delivered Fe protein the active site MoFe for transfer bound N 2 . We draw inspiration this structural enzymology, design a two‐component metal–sulfur–carbon (M−S−C) composed...
An electrochemical strategy for the dual functionalizations of unactivated alkenes through an intramolecular migration process was realized in absence sacrificial chemical oxidants and noble-metal catalysts under mild reaction conditions. The electrochemistry enabled a (hetero)aryl while providing access to alkenyl/alkynyl-migration products. Thus, electricity employed formation functionalized fluoroalkyl radicals activation C-H/C-Br bonds from fluorinated esters. Thereby, we obtained...
The reaction between an iridium(III) solvent complex and the histidine site of biomolecules as one kind novel bioconjugation approaches has received much attention during past few years. To extend this approach into electrochemiluminescence (ECL) immunoassay optimize performances, three complexes with different C∧N bidentate main ligands have been designed synthesized in work. Bovine serum albumin (BSA) standard histidine-rich protein is initially employed to evaluate labeling performances...
We have synthesized nitrogen-rich polymers by copolymerization of tetraethynyl monomers with tris(4-iodophenyl)amine or 4,4′-diiodoazobenzene. Azobenzene-based exhibited excellent CO<sub>2</sub> adsorption selectivity against N<sub>2</sub>.