A5086354799- Atmospheric chemistry and aerosols
- Atmospheric aerosols and clouds
- Atmospheric Ozone and Climate
- Air Quality and Health Impacts
University of Michigan
2022-2025
Institute for Literature
2025
At fixed aerosol acidity, we recently demonstrated that dimers in isoprene epoxydiol-derived secondary organic (IEPOX-SOA) can heterogeneously react with hydroxyl radical (·OH) at faster rates than monomers. Aerosol acidity influences this aging process by enhancing the formation of oligomers freshly generated IEPOX-SOA. Therefore, systematically examined role on kinetics and products resulting from heterogeneous ·OH oxidation IEPOX reacted inorganic sulfate varying initial pH (0.5, 1.5,...
Oxidation of isoprene, the biogenic volatile organic compound (BVOC) with highest emissions globally, is a large source secondary aerosol (SOA) in atmosphere. Particulate organosulfates formed from acid-driven reactions oxidation products isoprene epoxydiol (IEPOX) isomers are important contributors to SOA mass. Most studies have focused on organosulfate formation ammonium sulfate particles, often at low pH. However, recent work has shown that sea spray (SSA) accumulation mode (∼100 nm)...
ADVERTISEMENT RETURN TO ARTICLES ASAPPREVFirst ReactionsNEXTScratching the Surface of Individual Aerosol Particle PropertiesTrapping individual aerosol particles atmospherically relevant sizes reveals dramatic differences in surface tension from bulk solutions.Andrew P. AultAndrew AultDepartment Chemistry, University Michigan, Ann Arbor, Michigan 48109, United StatesEmail: [email protected]More by Andrew Aulthttps://orcid.org/0000-0002-7313-8559 and Cara M. WatersCara WatersDepartment...