Mir Sadra Hosseini

ORCID: 0009-0007-9458-0569
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About
Contact & Profiles
Research Areas
  • Chemical Synthesis and Reactions
  • Electrochemical Analysis and Applications
  • Concrete Corrosion and Durability
  • Corrosion Behavior and Inhibition
  • Synthesis and Catalytic Reactions
  • Asymmetric Hydrogenation and Catalysis

K.N.Toosi University of Technology
2016-2023

A novel and practical approach to access saturated ketones from unsaturated ketone derivatives via a CS2/t-BuOK system in dimethyl sulfoxide (DMSO) is reported. The situ generation of xanthate salt through the reaction carbon disulfide potassium tert-butoxide essential this transformation. Deuterium-labeling experiments demonstrated that DMSO can act as hydrogen donor.

10.1021/acs.joc.3c00903 article EN The Journal of Organic Chemistry 2023-07-20
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