A5085316369- Fluorine in Organic Chemistry
- Synthesis and Catalytic Reactions
- Sulfur-Based Synthesis Techniques
- Click Chemistry and Applications
- Oxidative Organic Chemistry Reactions
- CO2 Reduction Techniques and Catalysts
- Chemical Synthesis and Reactions
- Organic Chemistry Cycloaddition Reactions
- Radical Photochemical Reactions
University of Michigan
2024
Pomona College
2020-2023
A method to activate sulfamoyl fluorides, fluorosulfates, and sulfonyl fluorides with calcium triflimide DABCO for SuFEx amines is described. The reaction was applied a diverse set of sulfamides, sulfamates, sulfonamides at room temperature under mild conditions. Additionally, we highlight this transformation parallel medicinal chemistry generate broad array nitrogen-based S(VI) compounds.
This report benchmarks a tris(amino)cyclopropenium (TAC) salt as an electron-transfer mediator for anodic oxidation reactions in comparison to two known mediators: triarylamine and triarylimidazole derivative. The three mediators have redox potentials, diffusion coefficients, heterogeneous electron transfer rates similar those of glassy carbon electrodes acetonitrile/KPF6. However, they differ significantly their performance electro-organic reactions: fluorination dithiane 4-methoxybenzyl...
<p><br></p> <p>A method to activate sulfamoyl fluorides, fluorosulfates, and sulfonyl fluorides with calcium triflimide, DABCO for SuFEx amines is described. The reaction was applied a diverse set of sulfamides, sulfamates, sulfonamides at room temperature under mild conditions. Additionally, we highlight the application this transformation parallel medicinal chemistry generate broad array nitrogen-based S(VI) compounds. </p>
A method to activate sulfamoyl fluorides, fluorosulfates, and sulfonyl fluorides with calcium triflimide, DABCO for SuFEx amines is described. The reaction was applied a diverse set of sulfamides, sulfamates, sulfonamides at room temperature under mild conditions. Additionally, we highlight the application this transformation parallel medicinal chemistry generate broad array nitrogen-based S(VI) compounds.