A5100376173- Metal-Organic Frameworks: Synthesis and Applications
- Covalent Organic Framework Applications
- Asymmetric Hydrogenation and Catalysis
- Luminescence and Fluorescent Materials
- Carbon dioxide utilization in catalysis
- Carbon Dioxide Capture Technologies
- Catalytic Processes in Materials Science
- Machine Learning and ELM
- Nanomaterials for catalytic reactions
- Catalysts for Methane Reforming
- Advanced Nanomaterials in Catalysis
- Advanced Photocatalysis Techniques
- Congenital Diaphragmatic Hernia Studies
- Electrohydrodynamics and Fluid Dynamics
- Synthesis and characterization of novel inorganic/organometallic compounds
- Mosquito-borne diseases and control
- Thermochemical Biomass Conversion Processes
- E-commerce and Technology Innovations
- Intestinal Malrotation and Obstruction Disorders
- Electric Vehicles and Infrastructure
- Microfluidic and Capillary Electrophoresis Applications
- CO2 Reduction Techniques and Catalysts
- Maritime Ports and Logistics
- Regional Economic and Spatial Analysis
- Wastewater Treatment and Nitrogen Removal
State Key Laboratory of Pollution Control and Resource Reuse
2025
Nanjing University
2023-2025
Shandong Provincial QianFoShan Hospital
2024
Shandong First Medical University
2024
Institute of High Energy Physics
2024
Chinese Academy of Sciences
2023-2024
Nanjing Tech University
2024
Institute of Advanced Science Facilities, Shenzhen
2024
Southwest University
2024
Guangxi University
2024
Stable metal-organic frameworks (MOFs) with mesopores (2-50 nm) are promising platforms for immobilizing nanosized functional compounds, such as metal-oxo clusters, metal-sulfide quantum dots, and coordination complexes. However, these species easily decompose under acidic conditions or high temperatures, hindering their in situ encapsulation stable MOFs, which usually synthesized harsh involving excess acid modulators temperatures. Herein, we report a route the room-temperature...
This review presents diverse growth methods employed in the fabrication of room temperature-synthesized MOF films, emphasizing their significant applications across various fields.
Photosensitization is a powerful approach for enhancing the photocatalyst performance by improving light absorption, energy transfer, and charge separation. However, achieving high efficiency requires precise control over photosensitizers, catalytic centers, their interactions, which remain challenging in heterogeneous systems. Herein, we develop multivariate zirconium metal-organic frameworks (MOFs) with mixing linkers tunable defects that enable unprecedented ratios, creating an efficient...
An efficient nanoscale Ni-based catalyst enabled the energy-efficient coupling of HzOR with CO 2 RR for production.
The structural characteristics of metal–organic framework (MOF)-derived materials are strongly influenced by synthesis solvents. Herein, Ni-BTC MOFs were solvothermally synthesized in different solvents, and their derived Ni@C catalysts achieved through a one-step pyrolysis. solvents significantly affect the microstructures catalytic performance during hydrogenation phenolic compounds. Remarkably, employing ternary solvent system composed deionised water (DI), N,N-dimethylformamide (DMF),...
Electric vehicles (EVs) are crucial for addressing the intertwined challenges of climate change and air pollution. The multiaspect benefits EVs highly dependent on local conditions, yet impacts regional heterogeneity in context future remain unclear. Here, we develop a systemic modeling framework integrating fleet modeling, emission projection, index decomposition analysis, detailed cost assessment to identify drivers potential trade-offs behind electrification. Our findings reveal...
Covalent organic frameworks (COFs) are a promising class of adsorption and separation materials that can meet the needs ecological sustainability, such as removal carbon dioxide dyes. The two synthesized (3,3)-connected triazine-based COFs demonstrate high specific surface area good thermal chemical stability. COFZ1 shows CO2 selectivities for different N2 volume percentage systems at 273 K 1 bar, with an ideal adsorbed solution theory (IAST) selectivity (i.e., factor) 35.09 simulated flue...
The Atherton-Todd-type reaction of pentacoordinate hydrospirophosphoranes with amines was investigated, and a novel CO2 insertion into the P-N bond under mild conditions developed. mechanism stereochemistry between secondary were proposed via carbon-13 labeling experiment, (31)P NMR tracing X-ray diffraction analysis. chlorinated spirophosphorane intermediate first generated stereoretention configuration at phosphorus subsequently attacked by carbamate anion formed from amine. It found that...
Covalent organic frameworks (COFs) possess good porosity, uniform channels, and tunable skeletons, as well excellent stability, which are well-suited for gas adsorption. In this study, we developed two pyrazine-based COFs, namely, TFPPz–MPA–COF TFPPz–BD(OMe)2–COF, by condensation reaction of C4 C2 axisymmetric monomers. Both COFs exhibited crystallinity, well-defined pore structures, outstanding thermal chemical stability. TFPPz–BD(OMe)2–COF demonstrated high iodine adsorption capabilities...
The structure of a Ni/Al2O3 monolithic catalyst after methanation reaction and its performance were studied by taking analogue syngas biomass gasification H2/CO/N2 as feed gas when the temperature ranged from 250 to 550 °C, weight hourly space velocity (WHSV) was between 6000 14,000 mL g–1 h–1. catalysts using cordierite honeycomb ceramics substrate prepared dipping sol–gel methods. results show that method (DIP-Ni/Al2O3) has better than (SG-Ni/Al2O3) through many tests such TEM, BET, XRD,...
Nitrate reduction reaction (NO3RR) involves an 8‐electron transfer process and competes with the hydrogen evolution process, resulting in lower yields Faraday efficiency (FE) of NH3 synthesis. Especially, Cu‐based catalysts (Cu0 Cu+) have been investigated field NO3RR due to energy levels d‐orbital least unoccupied molecular orbital (LUMO) π* nitrate's orbital. Based on above, we synthesized a compound containing Cu3N (Cu+) through simple one‐step pyrolysis method, applied it...
CO 2 adsorption IAST selectivities of phenoxazine-cored YCOF1 up to 70.97 (237 K) and 30.05 (298 under simulated flue gas conditions. High capacities 650.14 (YCOF1) 572.95 (YCOF2) mg g −1 for the dye MG in aqueous solution.
The objective of this study was to enhance removal chemical oxygen demand (COD), total nitrogen (TN) and phosphorus (TP) from domestic sewage in a sequencing batch reactor with added new materials. A modified anoxic/anaerobic/oxic (MAAO) process, integrating micro-electrolysis (ME) bed an anoxic tank, complex biological media (CBM) anoxic, anaerobic oxic tanks treat sewage, their performances were investigated. MAAO system operated at controlled hydraulic retention time (HRT) 8 h mixed...
This review highlights the recent advances of MOFs and their related hybrids in main implant intervention fields, while also discussing confronting challenges future perspectives.
Total knee arthroplasty is an effective method for treating severe joint diseases, but the changes in patellar height and psychological state of patients after surgery are still great concern. Select a group who have undergone total replacement as research subjects, use radioactive CT imaging to examine joints patients, input them into computer system analysis. Based on position, shape, surrounding structure patella images, process obtain specific value height. Radioactive examination showed...
Abstract Base‐mediated treatment of hydrospirophosphoranes with secondary amines results in the formation phosphorane carbamates via unexpected CO 2 insertion.