- Advanced Photocatalysis Techniques
- CO2 Reduction Techniques and Catalysts
- Electrocatalysts for Energy Conversion
- Advanced battery technologies research
- Advancements in Battery Materials
- Ionic liquids properties and applications
- Advanced Battery Materials and Technologies
- Covalent Organic Framework Applications
- Catalytic Processes in Materials Science
- Perovskite Materials and Applications
- Molecular Junctions and Nanostructures
- Advanced oxidation water treatment
- Arsenic contamination and mitigation
- Parasites and Host Interactions
- 2D Materials and Applications
- Parasitic Diseases Research and Treatment
- MXene and MAX Phase Materials
- Supercapacitor Materials and Fabrication
- Quantum Dots Synthesis And Properties
- Ga2O3 and related materials
- Parasite Biology and Host Interactions
- Nanomaterials for catalytic reactions
- Gas Sensing Nanomaterials and Sensors
- Electrochemical Analysis and Applications
- Advanced Nanomaterials in Catalysis
Zhengzhou University
2016-2024
Abstract Nanostructured metal-nitrides have attracted tremendous interest as a new generation of catalysts for electroreduction CO 2 , but these structures limited activity and stability in the reduction condition. Herein, we report method fabricating FeN/Fe 3 N nanoparticles with interface exposed on NP surface efficient electrochemical reaction (CO RR). The is populated Fe−N 4 coordination sites respectively that show desired catalysis synergy to enhance CO. Faraday efficiency reaches 98%...
Copper oxide (Cu2O) is considered a promising catalyst that can effectively reduce the overpotential of CO2 reduction reaction (CO2 RR) and increase selectivity for C2+ products. However, developing high-performance stable CO2-to-ethanol (C2H5OH) based-Cu2O electrocatalysts remains challenging. In this work, Cu2O@Cu2S twin heterojunction catalysts with multitwin boundaries are designed to afford C2H5OH productivity at low potential through electrocatalytic RR, highly dependent on facet...
2D/2D nitrogen-vacancy-rich Ti 3 C 2 T x /g-C N 4 (TC/CN) Schottky heterojunctions with interfacial N–Ti bonds have been successfully constructed as an efficient photocatalyst for simultaneous H evolution coupled selective aromatic alcohol oxidation.
Effective separation of photogenerated charge carriers, enhanced reduction ability conduction band electrons, and improved light harvesting are crucial for the significant improvement photocatalytic H 2 evolution activity over Z-scheme ZnIn S 4 /v-Nb O 5 heterojunction.
Z-scheme heterostructure-based photocatalysts consist of a reduction photocatalyst and an oxidation photocatalyst, enabling them to possess high capacity for both oxidation. However, the coupling reaction between photocatalytic H2 generation through water sterilization using systems has been rarely reported. Herein, 1D W18O49 nanowires embedded over 2D g-C3N4 nanosheets are well-constructed as integrated heterojunction. Experimental results density functional theory calculations not only...
Abstract Optimizing the electronic structure with increasing intrinsic stability is a usual method to enhance catalysts’ performance. Herein, series of cerium dioxide (CeO 2−δ ) based solid solution materials synthesized via substituting Ce atoms transition metal (Co, Cu, Ni, etc.), in which Co 0.07 0.93 O shows optimized band because electron reaction, namely 3+ (3d 6 4s 0 + (4f 1 5d 6s → 2+ 7 4+ ), more stable configuration. The situ Raman spectra show F2g peak at ≈452 cm −1 , while CeO...
Abstract Design the electrocatalysts without noble metal is still a challenge for oxygen evolution reaction (OER) in acid media. Herein, we reported manganese (Mn) doping method to decrease concentration of vacancy (V O ) and form Mn−O structure adjacent octahedral sites spinel NiCo 2 4‐δ (NiMn 1.5 Co 3 ), which highly enhanced activity stability with low overpotential ( η 280 mV at j =10 mA cm −2 long‐term 80 h The isotopic labelling experiment based on differential electrochemical mass...
Layered indium selenide is a new two-dimensional (2D) semiconductor material with high carrier mobility, widely adjustable band gap, and ductility. However, its ion storage behavior related electrochemical reaction mechanism have been rarely reported. In this study, InSe nanoflakes encapsulated in conductive polypyrrole was designed out consideration of restraining the severe volume change increasing conductivity via situ chemical oxidation polymerization. Density functional theory...
Copper (I) oxide (Cu2O) is considered a promising catalyst that can effectively reduce the overpotential of CO2 reduction reaction (CO2 RR) and increase selectivity for C2+ products. However, developing high performance CO2-to-ethanol (C2H5OH) based-Cu2O electrocatalysts still challenging. Herein, Cu2O@Cu2S twin heterojunction catalysts with multigrain boundaries are designed to afford C2H5OH productivity at low potential through electrocatalytic RR, highly dependent on facet nanocubes...
Metal selenides have been considered as credible candidates for electrodes sodium and potassium ion storage owing to their high energy density safety. Herein, N-doped carbon encapsulated Cu2Se (Cu2Se@NC) was prepared by dopamine polymerization high-temperature selenization using Cu2O nanocubes templates. The unique nanocubic structure uniform coating could shorten the transport distance, accelerate electron/charge diffusion, suppress volume varying, ultimately ensuring Cu2Se@NC excellent...