A5019281384- Carbon dioxide utilization in catalysis
- Catalysis for Biomass Conversion
- biodegradable polymer synthesis and properties
- Ionic liquids properties and applications
- Advanced Photocatalysis Techniques
- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Porphyrin and Phthalocyanine Chemistry
- Quantum Dots Synthesis And Properties
- TiO2 Photocatalysis and Solar Cells
- Crystallography and molecular interactions
- Advanced battery technologies research
- Photodynamic Therapy Research Studies
- Turfgrass Adaptation and Management
- Electrocatalysts for Energy Conversion
- Transition Metal Oxide Nanomaterials
- Gas Sensing Nanomaterials and Sensors
- Advancements in Battery Materials
- Advanced Cellulose Research Studies
- Nanoplatforms for cancer theranostics
- Conducting polymers and applications
- Chalcogenide Semiconductor Thin Films
- Rangeland and Wildlife Management
- Luminescence and Fluorescent Materials
- Photochromic and Fluorescence Chemistry
Shanghai University of Medicine and Health Sciences
2025
Zhejiang University of Technology
2024
Chinese Academy of Sciences
2011-2024
Ningbo Institute of Industrial Technology
2024
Institute of Process Engineering
2019-2024
Tarim University
2023
Beijing Institute of Technology
2020-2021
State Key Laboratory of Multiphase Complex Systems
2019-2021
Ionic Liquids Technologies (Germany)
2019-2021
Third People's Hospital of Hefei
2021
The balance between band structure, composition, and defect is essential for improving the optoelectronic properties of ternary quaternary quantum dots corresponding photovoltaic performance. In this work, ascorbic acid (AA) as capping ligand introduced into reaction system to prepare green Zn–Cu–In–Se (ZCISe) dots. Results show that addition AA can increase Zn content while decrease content, resulting in enlarged gap, high conduction energy level, suppressed charge recombination. When AA/Cu...
A high-molecular weight bio-based polycarbonate was successfully synthesized by breaking the hydrogen bond of <italic>endo</italic>-OH group using an ionic liquid.
Green synthesis of poly(isosorbide carbonate) (PIC) with remarkable properties is a huge challenge in industrial applications due to low molecular weight and harsh reaction conditions. We reported novel pathway synthesize high PIC through melt polymerization isosorbide (ISB) dimethyl carbonate (DMC), which are derived from the biomass CO2, respectively. The effects metal ion-containing compound catalyst on chemical structures, terminal groups, process polycondensation were studied. Compared...
The structure-controllable imidazole-based dicationic ionic liquids were used to precisely adjust the molecular weight and thermal properties of isosorbide-based polycarbonate.
A synthetic strategy for bio-based polycarbonate was developed <italic>via</italic> one-pot polymerization of renewable monomer isosorbide and dimethyl carbonate using eco-friendly organo-catalysts.
A synthetic pathway for high molecular weight isosorbide-based polycarbonate was developed <italic>via</italic> one-step direct melt polycondensation of isosorbide and dimethyl carbonate catalyzed by dual site-functionalized ionic liquids.
The utilization of biomass to produce plastic is one the key ways minimize negative impacts climate change and alleviate depletion petroleum resources. However, there still a lack bioderived polymers with properties comparable those commercial petroleum-based polymers. Isosorbide-based polycarbonate (PIC) most promising substitute for traditional petroleum-derived polycarbonate, but its application limited by low reactivity poor ductility isosorbide. In this study, we developed new strategy...
An unsymmetrical phthalocyanine conjugated with an RGDyK moiety (6) was synthesized and characterized. Its photophysical properties, including electronic absorption, fluorescence emission (ΦF = 0.20), singlet oxygen quantum yield (ΦΔ 0.63) two-photon absorption cross section (TPACS) at different wavelengths were studied. The in vitro cell study data demonstrate that this Pc conjugate possesses significantly high cellular uptake toward the ανβ3 positive DU145 prostate cancer cells along...
Intrinsically weak interaction between oil-soluble quantum dots (QDs) and TiO2 in a direct adsorption process limits QD loading the performance of QD-sensitized solar cells (QDSCs). Herein, underlying chemistry mechanisms governing on were studied to improve cell performance. Experimental results indicate that solvent polarity plays crucial role determining loading. Compared with single-component solvents, substantially greater can be realized at critical point (CP) bicomponent where QDs...
Electrosynthesis of hydrogen peroxide (H2O2) is an energy-efficient and environmentally friendly approach with the potential for on-site generation application but severely constrained by lack efficient stable catalysts to activate two-electron oxygen reduction reaction high selectivity generate H2O2 in yield. Herein, we report a nickel vanadate catalyst (Ni3V2O8-NS) featuring selectivity, activity, stability. The Ni3V2O8-NS exhibited across pH-universal electrolytes (acidic 92.28%, neutral...
Abstract High-resolution non-emissive displays based on electrochromic tungsten oxides (WO x ) are crucial for future near-eye virtual/augmented reality interactions, given their impressive attributes such as high environmental stability, ideal outdoor readability, and low energy consumption. However, the limited intrinsic structure of inorganic materials has presented a significant challenge in achieving precise patterning/pixelation at micron scale. Here, we successfully developed direct...
Cyclic tetramerization of 3-(dibutylamino)phthalonitrile in refluxing n-pentanol the presence magnesium pentanoate afforded four regioisomer-containing nonperipheral 1,8-/11,15-/18,22-/25-tetrakis(dibutylamino)phthalocyaninato complexes with 1,8,15,22-tetrakis(dibutylamino)phthalocyanine isomer Mg{Pc[α-N(C4H9)2]4-C4} (2). This, combination its much superior crystallinity over remaining three isomers, renders easy isolation 2 only through two simple recrystallizations from THF and methanol....
A catalytic system containing an acylamido-based anion was developed for the synthesis of bio-based polycarbonate by efficient activation monomers.
Flexible counter electrode (CE) plays an important role in portable quantum dot sensitized solar cells (QDSCs). However, the present power conversion efficiency (PCE) of bendable QDSC is rather limited partly due to unsatisfactory conductivity, flexibility, catalytic activity, and fabrication technique CE. In this work, flexible CEs composed CuxS graphite paper (GP) are built fabricated through a facile successive ionic layer adsorption reaction (SILAR) method. Through designing optimizing...
In this work, metal acetylacetonates were used to catalyze the reaction of dimethyl carbonate (DMC) and bisphenol A (BPA) high conversion BPA excellent selectivity carboxymethylation products achieved. Among these, zirconium(IV) acetylacetonate (Zr(acac)4) exhibited best catalytic performance with 85.2% up 99.0%, which has been most efficient catalyst so far our knowledge. According Fourier transform infrared (FT-IR) characterization density functional theory (DFT) calculations, we found...
Abstract Smart materials with circularly polarized luminescence (CPL) tunable ability show great potential for advanced information storage and encryption. While an effective integration of high photoluminescence quantum yield (PLQY) facile regulation CPL property in thin films are significance, it is challenging due to the scarcity suitable complexity systems. Herein, a novel acid‐responsive molecule designed by combining aggregation‐induced emission (AIE) component (TPE), luminophore...