A5008141064- Carbon dioxide utilization in catalysis
- biodegradable polymer synthesis and properties
- Catalysis for Biomass Conversion
- Research Data Management Practices
- Asymmetric Hydrogenation and Catalysis
- Machine Learning in Materials Science
- Data Quality and Management
- CO2 Reduction Techniques and Catalysts
- Crystallization and Solubility Studies
- Ionic liquids properties and applications
- Scientific Computing and Data Management
- X-ray Diffraction in Crystallography
- Crystallography and molecular interactions
- Coordination Chemistry and Organometallics
- Chemical Synthesis and Reactions
Leibniz Institute for Catalysis
2016-2021
University of Rostock
2016
Polymers are used in simple consumer items like carpets, furniture, glues, and clothing but also advanced engineering, including materials the aerospace industry. Therefore, polymers consequently their monomers play an important role our everyday life. Currently, most of produced from fossil resources, supply which is diminishing. In this paper we review strategies catalytic processes to obtain currently potentially new renewable bio-based feedstocks platform chemicals. This Review divided...
Abstract Bifunctional phosphorus‐based organocatalysts proved to be highly efficient for the atom‐economic reaction of CO 2 and epoxidized oleochemicals. Notably, those products are obtained from renewable feedstocks only. Structure–activity relationships have been deduced a screening 22 in test reaction. catalysts based on phosphonium salt bearing simple phenolic moiety extraordinarily active under comparatively mild solvent‐free conditions. In presence most organocatalyst 12 oleochemical...
Abstract Modern research methods produce large amounts of scientifically valuable data. Tools to process and analyze such data have advanced rapidly. Yet, access high‐quality remains limited in many fields, including catalysis research. Implementing the concept FAIR (Findable, Accessible, Interoperable, Reusable) community would improve this situation dramatically. The German NFDI initiative (National Research Data Infrastructure) aims create a unique infrastructure covering all scientific...
The synthesis of non-isocyanate polyurethanes (NIPUs) has recently gained great attention. In this respect, a bifunctional catalyst and an abundant metal system were investigated for the conversion polyfunctional epoxides to gain general access corresponding cyclic carbonates as monomers NIPU synthesis. A Ca-based catalytic ammonium salt established these monomers. total, 14 terminal converted in yields up 99% high purities. With regard one-pot NIPUs directly from CO2, influence systems was...
Bifunctional ammonium and phosphonium salts have been identified as potential organocatalysts for the synthesis of glycerol carbonate methacrylate (GCMA). Three these catalysts showed high efficiency allowed conversion glycidyl with CO2 to desired product in >99 % selectivity. Subsequently, immobilized analogues selected were prepared tested. A phenol-substituted salt on a silica support proved be promising candidate recycling experiments. The same catalyst was used 12 consecutive runs,...
Simple zinc organyls (R<sub>2</sub>Zn) efficiently catalyze the copolymerization of CO<sub>2</sub> and cyclohexene oxide. The effect various reaction parameters has been studied. proceeds under halogen-free conditions no co-catalyst is required.
The title compound, (BenzMIm)Br (BenzMIm=1-benzyl-3-methyl-imidazo-l-ium), C
Die Katalyse ist ein sehr komplexes und interdisziplinares wissenschaftliches Gebiet, das die effiziente Herstellung einer Vielzahl von Produkten fur verschiedene Branchen in unterschiedlichen Produktionsgrosen ermoglicht. Somit eine der Schlusseltechnologien zur Bewaltigung wesentlicher Herausforderungen wie nachhaltigen Energieversorgung oder des Klimawandels. Das Datenmanagement derzeit uberwiegend auf institutioneller Arbeitsgruppenebene organisiert basiert lokalen Konventionen....