A5027523191- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Organometallic Complex Synthesis and Catalysis
- Advanced Photocatalysis Techniques
- Asymmetric Hydrogenation and Catalysis
- Synthetic Organic Chemistry Methods
- Metal complexes synthesis and properties
- Advanced oxidation water treatment
- Crystal structures of chemical compounds
- Crystallography and molecular interactions
- Asymmetric Synthesis and Catalysis
- Advanced battery technologies research
- Electrocatalysts for Energy Conversion
- Magnetism in coordination complexes
- Oxidative Organic Chemistry Reactions
- Chemical Synthesis and Analysis
- Coordination Chemistry and Organometallics
- Catalytic Cross-Coupling Reactions
- Advanced Nanomaterials in Catalysis
- Advanced Vision and Imaging
- Synthesis and characterization of novel inorganic/organometallic compounds
- Organoboron and organosilicon chemistry
- Catalytic Alkyne Reactions
- Water Quality Monitoring and Analysis
- Surface Chemistry and Catalysis
Hangzhou Dianzi University
2011-2025
Fujian Agriculture and Forestry University
2021-2025
Beihang University
2012-2025
Fuzhou University
2018-2025
Virtual Reality Medical Center
2024
State Key Laboratory of Virtual Reality Technology and Systems
2024
Huawei Technologies (China)
2024
Kunming University of Science and Technology
2024
Chinese Academy of Sciences
2017-2022
Institute of Computing Technology
2022
Driving tasks are vulnerable to the effects of sleep deprivation and mental fatigue, diminishing driver's ability respond effectively unusual or emergent situations. Physiological brain activity analysis could help understand how provide useful feedback alert signals drivers for avoiding car accidents. In this study we analyze insurgence fatigue drowsiness during driving in a simulated environment by using high resolution EEG techniques as well neurophysiologic variables such heart rate (HR)...
Ultrathin Co LDHs synthesized<italic>via</italic>a one-pot reaction of cobalt(<sc>ii</sc>) nitrate with 2-methylimidazole in water–methanol exhibit outstanding OER performance.
Z-scheme CdS/ZnS heterostructures with cation defects show enhanced photocatalytic activity and stability of water splitting.
Although many metallabenzenes are known, complex 1 appears to be the first well-characterized example of a metallabenzyne. It has been synthesized by treatment [OsCl2(PPh3)3] with an excess HC≡CSiMe3 in wet benzene. The structure novel was confirmed single-crystal X-ray diffraction, which showed six-membered ring essentially planar maximum deviation from least-squares plane 0.047 Å.
The reactivities of benzynes and metal-carbyne complexes are normally associated with the triple bond units. However, we have now found that electrophiles do not attack formal osmium-carbon osmabenzyne complex 1. Instead, 1 undergoes electrophilic substitution reactions-the typical reactions aromatic systems.
Abstract The perchlorate salt of the dicationic bipy–ruthenium complex cis ‐[Ru(6,6′‐Cl 2 bipy) (H O) ] 2+ effectively catalyzes addition β‐diketones to secondary alcohols and styrenes yield α‐alkylated β‐diketones. In a catalytic reaction acetylacetone 1‐phenylethanol, κ ‐acetylacetonate [Ru(6,6′‐Cl ( ‐acac)]ClO 4 was isolated after catalysis; this is readily synthesized by reacting ](ClO ) with acetylacetone. unreactive toward 1‐phenylethanol in presence HClO ; it also fails catalyze...
Non-radical advanced oxidation processes (AOPs) are increasingly recognized as an appealing alternative for the removal of persistent contaminants from water, effectively mitigating impact coexisting anions compared to traditional radical-based methods. Here, a singlet oxygen (1O2)-dominated process is developed degradation metronidazole (MNZ), with hollow bimetallic metal-doped carbon spheres (CuCo-HCS) catalysts and peroxymonosulfate (PMS) oxidant. Experimental results indicated that 1O2...
ABSTRACT Pan‐tilt‐zoom (PTZ) cameras, which dynamically adjust their field of view (FOV), are pervasive in large‐scale scenes, such as train stations, squares, and airports. In real scenarios, PTZ cameras required to quickly judge directions using contextual clues from the surrounding environment. To achieve this goal, some research projects camera videos into three‐dimensional (3D) models or panoramas allows operators establish spatial relationships. However, these works face several...
CoP nanowires are transformed to 0D Z-scheme CoP/NGQDs heterojunctions in the present of NGQDs, which exhibit currently highest POE rate on molecule (350 μmol g<sup>−1</sup> h<sup>−1</sup>) due generation a new excited state (CoP<sup>+</sup>·NGQDs<sup>−</sup>)*.
Treatment of OsCl2(PPh3)3 with 1,3-(PPh2CH2)2C6H4 led to the formation coordinatively unsaturated complex OsCl(PPh3)(PCP) (PCP = 2,6-(PPh2CH2)2C6H3). Reactions RC⋮CH (R Ph, t-Bu, C(OH)Ph2) gave OsCl(CCHR)(PPh3)(PCP). OsCl(CCHPh)(PPh3)(PCP) and OsCl(CCHC(OH)Ph2)(PPh3)(PCP) HCl produced carbyne complexes OsCl2(⋮CCH2Ph)(PCP) OsCl2(⋮CCHCPh2)(PCP), respectively. The solid-state structures have been determined by X-ray diffraction.
Ein Metallaarin wurde mit dem cyclischen Osmiumkomplex 1 erstmals hergestellt und charakterisiert. Die Synthese gelang durch Umsetzung von [OsCl2(PPh3)3] einem Überschuss an HC≡CSiMe3 in Benzol Gegenwart Wasser. Der Röntgenstrukturanalyse zufolge ist der sechsgliedrige Ring praktisch planar, die maximale Abweichung Ebene beträgt 0.047 Å.
Treatment of [OsCl2(PPh3)3] with HC⋮CC(OH)Ph2 in benzene at room temperature produces [(PPh3)2ClOs(μ-Cl)3Os(CCHC(OH)Ph2)(PPh3)2], fac-[OsCl3(⋮C−CHCPh2)(PPh3)2], mer-[OsCl3(⋮C−CHCPh2)(PPh3)2], and [OsCl2(CCCPh2)(CO)(PPh3)2]. The latter two complexes are the major products when reaction is carried out refluxing toluene. presence HCl fac-[OsCl3(⋮C−CHCPh2)(PPh3)2] mer-[OsCl3(⋮C−CHCPh2)(PPh3)2]. HPPh3BF4 [OsCl2(⋮C−CHCPh2)(H2O)(PPh3)2]BF4. structures all new have been confirmed by X-ray diffraction.