A5032771410- Catalysis and Oxidation Reactions
- Aerogels and thermal insulation
- Mesoporous Materials and Catalysis
- Adsorption, diffusion, and thermodynamic properties of materials
- Spectroscopy and Laser Applications
- Spectroscopy and Chemometric Analyses
- Polymer Nanocomposites and Properties
- Epoxy Resin Curing Processes
- Ferroelectric and Piezoelectric Materials
- Spectroscopy Techniques in Biomedical and Chemical Research
- Synthesis and properties of polymers
- Liquid Crystal Research Advancements
- Pickering emulsions and particle stabilization
- Advanced ceramic materials synthesis
Cracow University of Technology
2014-2018
University of Strathclyde
2013-2016
Institute of Polymers
2016
We used 13C and 1H NMR spectroscopy to examine the equilibrium speciation in formaldehyde–methanol–water solutions at moderate formaldehyde concentrations such as those synthesis of formaldehyde-based organic gels. Concentrations small methylene glycol oligomers their methoxylated forms found these were quantitatively determined over a range methanol–water ratios, temperatures between 10 55 °C. Using measured concentrations, constants for dimer trimer formation well methoxylation calculated....
Nanoporous organic gels can be synthesized from aqueous solutions of formaldehyde and resorcinol in the presence basic electrolytes such as sodium carbonate. It is well known that present form methylene glycols or methoxy-glycols methanolic solutions, but influence pH on speciation these has not been previously studied. Here we investigated effects carbonate colloidal scale clustering formaldehyde-methanol-water absence resorcinol. We used (13)C NMR spectroscopy to quantitatively...