A5083339404- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Catalytic Cross-Coupling Reactions
- Asymmetric Synthesis and Catalysis
- Microwave-Assisted Synthesis and Applications
- Oxidative Organic Chemistry Reactions
- Cyclopropane Reaction Mechanisms
- Asymmetric Hydrogenation and Catalysis
- Bioactive Compounds and Antitumor Agents
- Advanced Synthetic Organic Chemistry
- Enzyme Structure and Function
- Catalytic C–H Functionalization Methods
- Click Chemistry and Applications
- Synthesis and Characterization of Heterocyclic Compounds
- Microbial Natural Products and Biosynthesis
- Inorganic and Organometallic Chemistry
- Synthesis and Reactions of Organic Compounds
- Porphyrin and Phthalocyanine Chemistry
- Biochemical and Molecular Research
- Photochromic and Fluorescence Chemistry
- Nanoparticle-Based Drug Delivery
- Nanotechnology research and applications
- Synthesis and biological activity
- Graphene and Nanomaterials Applications
Hampton University
2017
University of Maryland, College Park
2015-2016
Louisiana State University
2012
College of Charleston
2010-2011
A new family of donor-functionalized photoswitchable arylazopyrazole-based ligands (3–5) was synthesized and characterized. The have been employed to prepare a series novel half-sandwich ruthenium(II) cymene complexes the type [(η6-p-cymene)Ru(L)Cl]+ (L = 1-(2-methylenepyridyl)-4-(phenyldiazenyl)-3,5-dimethyl-1H-pyrazole (6a), 1-(2-methylenepyridyl)-4-((4-bromophenyl)diazenyl)-3,5-dimethyl-1H-pyrazole (6b), 1-(2-benzothiazolyl)-3,5-dimethyl-4-arylazopyrazole (7)). All fully characterized by...
Carbene and metal carbenoid species, originally viewed as too reactive to be useful for complex molecule synthesis, have now emerged attractive intermediates the construction of highly functionalized heterocyclic compounds. A popular route carbenoids involves decomposition diazo starting materials, using various transition metals. In this review we highlight some utilities in synthesis biologically-active or natural product-like Some reaction classes that feature prominently these syntheses...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis and electrochemical reduction of [2-(1,4-benzoquinonyl)ethyl]-1,4-benzoquinoneLeon Mandell, S. M. Cooper, B. Rubin, C. F. Campana, R. A. Day Jr.Cite this: J. Org. Chem. 1983, 48, 18, 3132–3134Publication Date (Print):September 1, 1983Publication History Published online1 May 2002Published inissue 1 September 1983https://pubs.acs.org/doi/10.1021/jo00166a049https://doi.org/10.1021/jo00166a049research-articleACS PublicationsRequest reuse...
Abstract Review: 138 refs.
Abstract ortho,ortho′‐Substituted aryl bromides are vinylated in a Pd‐catalyzed Suzuki—Miyaura reaction.
In the title compound, C(32)H(28), central cyclo-octa-tetra-ene ring has a boat conformation, and mol-ecule is saddle shaped. The seat defined by mean plane of four-atom attachment points (r.m.s. deviation = 0.014 Å) two bicyclo-heptenyl substituents. These substituents comprise pommel cantle, with each four atoms proximate to deviations 0.002 0.004 Å). Relative seat, cantle bend up 31.16 (4) 29.40 (5)°, while benzo units (flaps, r.m.s. 0.006 0.009 down 36.75 38.46 (4)°. planes...
Abstract 2,5‐Dimethoxy‐benzylalkohol (Ia) liefert über das mit HCl erhaltene Chlorid (Ib) bei der Kondensation Natrium Dibenzylderivat (IIa), dessen Ethergruppen durch HBr gespalten werden.