A5040459397- Metal-Organic Frameworks: Synthesis and Applications
- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Covalent Organic Framework Applications
- Catalytic Processes in Materials Science
- Zeolite Catalysis and Synthesis
- Carbon Dioxide Capture Technologies
- Carbon dioxide utilization in catalysis
- Membrane Separation and Gas Transport
- Magnetism in coordination complexes
- Advanced Photocatalysis Techniques
- Fire dynamics and safety research
- Gas Sensing Nanomaterials and Sensors
- Flame retardant materials and properties
- Hydrocarbon exploration and reservoir analysis
- Chemical Synthesis and Reactions
- Nanomaterials for catalytic reactions
- Ammonia Synthesis and Nitrogen Reduction
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry
2021-2024
Jilin University
2021-2024
Here, a Y(III)-based metal-organic framework, JLU-MOF112 {[Y3(μ3-O)2(μ3-OH)(H2O)2(BTCTBA)2]·2[(CH3)2NH2]·5DMF·C6H5Cl·4H2O}, has been successfully synthesized under solvothermal conditions. was constructed with amide-functionalized tricarboxylate ligands and infinite chains, where the Y3 repeating units are arranged in trans order. The overall framework could be viewed as novel (3,5)-connected net two types of channels along [100] [010] directions. possesses large BET surface area (1553 m2...
Based on function-oriented synthesis, high-density multiple active sites were successfully introduced into two novel In 3 -based MOF materials. Both compounds exhibit high catalytic performances for CO 2 cycloaddition and Knoevenagel condensation.
Based on the hard-soft acid base (HSAB) theory, three robust isoreticular metal-organic frameworks (MOFs) with nia topology were successfully synthesized by solvothermal reaction {[In3O(BHB)(H2O)3]NO3·3DMA (JLU-MOF110(In)), [Fe3O(BHB)(H2O)3]NO3 (JLU-MOF110(Fe)), and [Fe2NiO(BHB)(H2O)3] (JLU-MOF110(FeNi)) (DMA = N,N-dimethylacetamide, H6BHB 4,4″-benzene-1,3,5-triyl-hexabenzoic acid)}. Both JLU-MOF110(In) JLU-MOF110(Fe) are cationic frameworks, their BET surface areas 301 446 m2/g,...
A novel copper-organic framework was synthesized by a linker desymmetrization strategy. Synergistic catalysis with Lewis and Brønsted acid sites promoted high catalytic efficiency towards the CO 2 -propylene oxide cycloaddition reaction.
Zeolites with small-pores (8-ring) are widely used in separation of small-molecule gas, however, the precise tuning aperture sizes to achieve ideal selectivity still remains challenge due their limited topology structures. In this work, SAPO-14 zeolite AFN featuring by different 8-ring windows three-dimension directions has been synthesized and studied CO2/N2 or CO2/CH4. Aiming further adjust pores channels adsorbents, composite zeolites SAPO-34 (CHA) prepared seed-assisted method,...
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Acetylene and carbon dioxide share similar physical properties, which poses a significant challenge for their industrial separation. Therefore, it is crucial to design synthesize specific adsorbents this purpose. In study, two pcu topological MOFs materials named JLU-MOF102 {[Ni(HPyC)2(BPY)] (DMF)2(H2O)2} JLU-MOF103 {[Ni(HPyC)2(PYZ)] (H2O)2} (4-pyrazolecarboxylic acid = H2PyC, 4,4’-bipyridine BPY, pyrazine PYZ, DMF N, N- dimethylformamide), were successfully synthesized facilitate the...