Rafael Furlan de Oliveira

ORCID: 0000-0001-8980-3587
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About
Contact & Profiles
Research Areas
  • Electrochemical sensors and biosensors
  • Analytical Chemistry and Sensors
  • Molecular Junctions and Nanostructures
  • Graphene research and applications
  • Conducting polymers and applications
  • Advanced Sensor and Energy Harvesting Materials
  • Organic Electronics and Photovoltaics
  • Advanced Memory and Neural Computing
  • Graphene and Nanomaterials Applications
  • 2D Materials and Applications
  • Advanced biosensing and bioanalysis techniques
  • Electrochemical Analysis and Applications
  • Nanowire Synthesis and Applications
  • MXene and MAX Phase Materials
  • Supercapacitor Materials and Fabrication
  • Gas Sensing Nanomaterials and Sensors
  • Quantum and electron transport phenomena
  • Luminescence and Fluorescent Materials
  • Semiconductor materials and devices
  • Mechanical and Optical Resonators
  • Carbon and Quantum Dots Applications
  • Perovskite Materials and Applications
  • Nanomaterials and Printing Technologies
  • Fluid Dynamics and Thin Films
  • Advanced Nanomaterials in Catalysis

Brazilian Center for Research in Energy and Materials
2016-2025

Université de Strasbourg
2019-2024

Centre National de la Recherche Scientifique
2019-2024

Universidade Estadual de Campinas (UNICAMP)
2023-2024

Laboratório Nacional de Nanotecnologia
2016-2024

Institut de Science et d'Ingénierie Supramoléculaires
2022

Laboratório Nacional de Ciência e Tecnologia do Bioetanol
2017-2022

Pontifícia Universidade Católica de Campinas
2020

Universidade Federal de Alfenas
2019

Universidade Estadual Paulista (Unesp)
2011-2016

Antibody-antigen (Ab-Ag) recognition is the primary event at basis of many biosensing platforms. In label-free biosensors, these events occurring solid-liquid interfaces are complex and often difficult to control technologically across smallest length scales down molecular scale. Here a molecular-scale technique, such as single-molecule force spectroscopy, performed areas real electrode functionalized for immunodetection an inflammatory cytokine, viz. interleukin-4 (IL4). The statistical...

10.1021/acsnano.5b00136 article EN ACS Nano 2015-04-14

The electronic properties of two-dimensional semiconductors can be strongly modulated by interfacing them with atomically precise self-assembled molecular lattices, yielding hybrid van der Waals heterostructures (vdWHs). While proof-of-concepts exploited assemblies held together lateral unspecific interactions, the use 2D supramolecular networks relying on specific non-covalent forces is still unexplored. Herein, prototypical hydrogen-bonded cyanuric acid (CA) and melamine (M) are onto MoS2...

10.1038/s41467-022-28116-y article EN cc-by Nature Communications 2022-01-26

The development of systems capable responding to environmental changes, such as humidity, requires the design and assembly highly sensitive efficiently transducing elements. Such a challenge can be mastered only by disentangling role played each component responsive system, thus ultimately achieving high performance optimizing synergistic contribution all functional Here, we designed synthesized novel [1]benzothieno[3,2-b][1]benzothiophene derivative equipped with hydrophilic oligoethylene...

10.1021/jacs.1c10119 article EN Journal of the American Chemical Society 2022-02-07

Abstract Graphene is regarded as the ultimate material for future flexible, high‐performance, and wearable electronics. Herein, a novel, robust, all‐green, highly reliable (yield ≥ 99%), upscalable technology reported applications comprising reduced graphene oxide (rGO) electroactive component in liquid‐gated transistors (LGTs). rGO formidable flexible due to its easy processability, excellent surface reactivity, large‐area coverage. A novel protocol established toward high‐yield fabrication...

10.1002/adfm.201905375 article EN Advanced Functional Materials 2019-09-15

Two-dimensional (2D) materials occupy a noteworthy place in nanophotonics providing for subwavelength light confinement and optical phenomena dissimilar to those of their bulk counterparts. In the mid-infrared, graphene-based heterostructures van der Waals crystals hexagonal boron nitride (hBN) overwhelmingly concentrate attention by exhibiting real-space nano-optics features from plasmons, phonon–polaritons, hybrid plasmon phonon–polaritons. Here we present prime study on mid-infrared talc,...

10.1021/acsphotonics.7b01017 article EN ACS Photonics 2018-04-11

Laser reduction of graphene oxide (GO) is a promising approach for achieving flexible, robust, and electrically conductive graphene/polymer composites. Resulting composite materials show significant technological potential energy storage, sensing, bioelectronics. However, in the case insulating polymers, properties electrodes severely limited performance. To overcome these challenges, we report on post-processing redox treatment that allows tuning electrochemical laser-induced rGO/polymer...

10.3390/polym17020192 article EN Polymers 2025-01-14

Abstract Inspired by the functioning of human brain, organic synaptic transistors represent a promising avenue for developing neuromorphic technologies. However, achieving sustainability while maintaining performance and functionality remains critical challenge. Here, we report on an innovative strategy where synthetic melanin (Mel) – natural pigment known its improved ionic-electronic coupling, high volumetric capacitance, environmentally friendly characteristics is blended with benchmark...

10.1088/2634-4386/adbccd article EN cc-by Neuromorphic Computing and Engineering 2025-03-05

Abstract Health monitoring is experiencing a radical shift from clinic‐based to point‐of‐care and wearable technologies, variety of nanomaterials transducers have been employed for this purpose. 2D materials (2DMs) hold enormous potential novel electronics, yet they struggle meet the requirements technologies. Here, aiming foster development 2DM‐based reduced graphene oxide (rGO)‐based liquid‐gated transistors (LGTs) cation sensing in artificial sweat endowed with distinguished performance...

10.1002/smll.202201861 article EN Small 2022-06-08

The advent of immunotherapies with biological drugs has revolutionized the treatment cancers and auto-immune diseases. However, in some patients, production anti-drug antibodies (ADAs) hampers drug efficacy. concentration ADAs is typically range 1-10 pm; hence their immunodetection challenging. toward Infliximab (IFX), a used to treat rheumatoid arthritis other diseases, are focussed. An ambipolar electrolyte-gated transistor (EGT) immunosensor reported based on reduced graphene oxide (rGO)...

10.1002/adma.202211352 article EN cc-by Advanced Materials 2023-07-12

Abstract Ethanol is a biofuel used worldwide. However, the presence of excessive water either during distillation process or by fraudulent adulteration major concern in use ethanol fuel. High levels may cause engine malfunction, addition to being considered illegal. Here, we describe development simple, fast and accurate platform based on nanostructured sensors evaluate samples. The device fabrication facile, standard microfabrication thin-film deposition methods. sensor operation relies...

10.1038/srep43432 article EN cc-by Scientific Reports 2017-02-27

A new and green blend based on PEDOT:PSS synthetic melanin is demonstrated as an organic mixed ionic electronic conductor (OMIEC) with enhanced ionic–electronic coupling for electrochemical transistors supercapacitors.

10.1039/d3ma00573a article EN cc-by-nc Materials Advances 2023-01-01

This review summarizes a decade of research on oxidative debris (ODs) in graphene oxide (GO) and discusses the protocols for isolating ODs, their structural characteristics, influence several GO properties.

10.1039/d3tc02057f article EN Journal of Materials Chemistry C 2023-01-01

Abstract Ambipolar electrolyte‐gated transistors (EGTs) based on reduced graphene oxide (rGO) have been demonstrated as ultra‐sensitive and highly specific immunosensors. However, the physics chemistry ruling device operation are still not fully unraveled. In this work, aim is to elucidate nature of observed sensitivity device. Toward aim, a physical–chemical model that, coupled with experimental characterization rGO‐EGT, allows one quantitatively correlate biorecognition events at gate...

10.1002/adfm.202313871 article EN cc-by Advanced Functional Materials 2024-01-14

Organic thin-film transistors (OTFTs) are an ever-growing subject of research, powering recent technologies such as flexible and wearable electronics. Currently, many studies being carried out to push forward the state-of-the-art OTFT technology achieve characteristics that include high carrier mobility, low power consumption, flexibility, ability operate under harsh conditions. Here, we tackle this task by proposing a novel architecture exploring so-called rolled-up nanomembrane fabricate...

10.1021/acs.nanolett.8b01958 article EN Nano Letters 2018-08-23

The charge transport in molecular systems is governed by a series of carrier-molecule quantum interactions, which result broad set chemical and physical phenomena. precise control such phenomena one the main challenges toward development novel device concepts. In systems, direct tunneling across 1–10 nm barriers activated hopping over longer distances have been described as mechanisms. continuous transition from mechanism to other, increasing distance, has mainly reported for chains...

10.1021/acs.jpcc.7b02528 article EN The Journal of Physical Chemistry C 2017-05-25

Nanomembranes (NMs) are freestanding structures with few-nanometer thickness and lateral dimensions up to the microscale. In nanoelectronics, NMs have been used promote reliable electrical contacts distinct nanomaterials, such as molecules, quantum dots, nanowires, well support comprehension of condensed matter down nanoscale. Here, we propose a tunable device architecture that is capable deterministically changing both contact geometry current injection in nanoscale electronic junctions....

10.1021/acsami.8b12212 article EN ACS Applied Materials & Interfaces 2018-10-23

Ensemble molecular diodes employing carbon-based nanomaterials reveal a controllable current rectification ratio and direction inversion, both driven by temperature.

10.1039/c9nr10601d article EN Nanoscale 2020-01-01

Abstract The monitoring of K + in saliva, blood, urine, or sweat represents a future powerful alternative diagnostic tool to prevent various diseases. However, several sensors are unable meet the requirements for development point‐of‐care (POC) sensors. To tackle this grand‐challenge, fabrication chemiresistors (CRs) based on 3D networks Au nanoparticles covalently bridged by ad‐hoc supramolecular receptors , namely dithiomethylene dibenzo‐18‐crown‐6 ether is reported here. A multi‐technique...

10.1002/adfm.202008554 article EN cc-by Advanced Functional Materials 2020-11-16

Control of supramolecular architectures inherent in layer-by-layer (LbL) films allows for synergistic effects between the film components, as reactions under controlled conditions. In this paper we show that a bienzyme system can be produced LbL films, which product reaction catalyzed by invertase (INV) is used catalysis process involving glucose oxidase (GOx). As proof principle, simultaneous detection and sucrose demonstrated an optimized architecture comprising poly allyllamine...

10.1021/jp207610w article EN The Journal of Physical Chemistry C 2011-08-30

Graphene is a breakthrough 2D material due to its unique mechanical, electrical, and thermal properties, with considerable responsiveness in real applications. However, the coverage of large areas pristine graphene challenge derivatives have been alternatively exploited produce hybrid composite materials that allow for new developments, considering also handling using distinct methodologies. For electronic applications there significant interest investigation electrical properties related...

10.1088/1361-6528/aa91c2 article EN Nanotechnology 2017-10-06
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