- biodegradable polymer synthesis and properties
- Advanced Polymer Synthesis and Characterization
- Bone Tissue Engineering Materials
- Nanoparticle-Based Drug Delivery
- Dendrimers and Hyperbranched Polymers
- Liquid Crystal Research Advancements
- Orthopaedic implants and arthroplasty
- Electrohydrodynamics and Fluid Dynamics
- Chemical Synthesis and Analysis
- Polymer Surface Interaction Studies
- Synthetic Organic Chemistry Methods
- Polymer Nanocomposites and Properties
- Surface Modification and Superhydrophobicity
- Click Chemistry and Applications
- Chemical Synthesis and Reactions
- Membrane Separation Technologies
- Asymmetric Hydrogenation and Catalysis
Indian Institute of Chemical Technology
2012-2016
University of Hyderabad
2016
Glycopolymers with three different pendant alkyl chain lengths (0, 4 and 6) of conjugated glucose moieties were prepared by deacetylation synthesized acetylated polymers their<italic>in vitro</italic>responses osteoblast cell adhesion, viability proliferation investigated. The increase in spacer length moiety the glycopolymer had enhanced cytocompatibility even at higher concentration.
Poly(ethylene oxide)-block-poly(methacryl-d-glucopyranoside) (PEO-GP) and poly(methacryl-d-glucopyranoside) (H-GP) glycopolymers were synthesized by deacetylation of acetylated polymers which via atom transfer radical polymerization. The characterized using 1H NMR, 13C NMR Fourier transform infrared (FTIR) spectroscopies, gel permeation chromatography (GPC), thermogravimetric analysis (TGA) differential scanning calorimetry (DSC). deacetylated exhibited onset decomposition temperatures about...
We report a strategy to quantify the relative binding affinity of glycopolymers on FITC-AuNP by release FITC <italic>via</italic> self-assembly process and which was improved introducing PEG segment glycopolymer similar functionalities.
The telechelic polystyrene (tPS) was used as a macro-reversible addition fragmentation chain transfer (RAFT) agent to prepare the ABA-type tri-block copolymers (TBCs), poly{4-[4-(11-acryloyloxyundecyloxy)phenylazo]benzonitrile}-b-polystyrene-b-poly{4-[4-(11-acryloyloxyundecyloxy)phenylazo]benzonitrile} [poly(AUPAB)-b-PS-b-poly(AUPAB)] with 4-[4-(11-acryloyloxyundecyloxy)phenylazo]benzonitrile (AUPAB) monomer by RAFT polymerization process. poly(AUPAB) reference probe role of block in...
Di-block copolymers of poly(ethylene oxide) (PEO) and glycopolymers at three different pendant spacer lengths glucose moiety were synthesized by deacetylation moieties 2,3,4,6-tetra-O-acetyl-d-glucopyranosides which prepared reversible addition-fragmentation chain-transfer (RAFT) process. The water soluble deacetylated copolymers, PEO-b-poly(acryl-d-glucopyranoside) (PEO-b-PAG, 2a), PEO-b-poly[4′-(acryloxy)butyl-d-glucopyranoside] (PEO-b-PABG, 2b),...
Abstract Solvent‐free cyanoethylation of selected alcohols with acrylonitrile (AN) using a weakly basic polymer resin, Amberlyst A‐21 (AA‐21) was studied at 75°C. The conversion primary alcohols, 1‐octadecanol, hexane‐1,6‐diol, pentaerythritol, but‐2‐yne‐1,4‐diol, N ‐methyldiethanolamine, triethanolamine and diethanolamine is higher than secondary isopropanol glycerol in the presence resin. Of various but‐2‐yne‐1,4‐diol gave product high (87%) resin/AN weight ratio 0.04. resin showed...