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Contact & Profiles
A5076741257
Research Areas
- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Nanocluster Synthesis and Applications
- Quantum Dots Synthesis And Properties
- Gold and Silver Nanoparticles Synthesis and Applications
- Neurological Complications and Syndromes
- Advanced Nanomaterials in Catalysis
Southern Methodist University
2021-2023
We report the first example of a chiral mixed thiolate/stibine-protected gold cluster, formulated as Au18(S-Adm)8(SbPh3)4Br2 (where S-Adm = 1-adamantanethiolate). Single crystal X-ray crystallography reveals origin chirality in cluster to be introduction rotating arrangement Au2(S-Adm)3 and Au(S-Adm)2 staple motifs on an achiral Au13 core subsequent capping remaining atoms by SbPh3 Br- ligands. Interestingly, structure properties this new Au18 are found different from other reported clusters...
10.1021/jacs.1c10778
article
EN
Journal of the American Chemical Society
2021-12-27
[Au 6 (SbP 3 ) 2 ][PF ] : the first gold nanocluster protected by multidentate coordination of stibine (Sb) and phosphine (P) moieties.
10.1039/d2nr05497c
article
EN
Nanoscale
2023-01-01
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