- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Natural Products and Biological Research
- Lanthanide and Transition Metal Complexes
- Magnetism in coordination complexes
- Essential Oils and Antimicrobial Activity
- Plant Pathogens and Fungal Diseases
- Crystallography and molecular interactions
- Archaeological and Historical Studies
- Metal complexes synthesis and properties
- Chemical Thermodynamics and Molecular Structure
- Crystal structures of chemical compounds
- Biofuel production and bioconversion
- Radioactive element chemistry and processing
- Archaeological and Geological Studies
- Composting and Vermicomposting Techniques
- Medieval Architecture and Archaeology
- Nanocomposite Films for Food Packaging
- Organic Light-Emitting Diodes Research
- Phytochemicals and Antioxidant Activities
- Building materials and conservation
- Advanced Photocatalysis Techniques
- Cultural Heritage Materials Analysis
- Thermal and Kinetic Analysis
- Organometallic Compounds Synthesis and Characterization
Universidad de Valladolid
2016-2025
University Vascular Associates
2020-2023
Hospital Universitario Quirónsalud Madrid
2020
Hospital Nuestra Señora de Alarcos
2018-2019
Universidad de Zaragoza
2016-2018
Complejo Hospitalario de Salamanca
2017
Universidade Federal de Pelotas
2017
Hospital Universitario Río Hortega
1999-2016
University of Chile
2006-2016
Complejo Asistencial Universitario de Palencia
2014-2016
Advancements in polymer science and nanotechnology hold significant potential for addressing the increasing demands of food security, by enhancing shelf life, barrier properties, nutritional quality harvested fruits vegetables. In this context, biopolymer-based delivery systems present themselves as a promising strategy encapsulating bioactive compounds, improving their absorption, stability, functionality. This study provides an exploration synthesis, characterization, postharvest...
The use of nanocarriers (NCs), i.e., nanomaterials capable encapsulating drugs and releasing them selectively, is an emerging field in agriculture. In this study, the synthesis, characterization, vitro vivo testing biodegradable NCs loaded with natural bioactive products was investigated for control certain phytopathogens responsible wood degradation. particular, based on methacrylated lignin chitosan oligomers, extracts from Rubia tinctorum, Silybum marianum, Equisetum arvense, Urtica...
Solution-processed near-infrared organic light-emitting diodes (NIR-OLEDs) with structure glass/indium–tin oxide/poly(3,4-ethylenedioxythiophene)-poly(styrene sulfonate)/Er-complex/Ca/Al based on a novel Er(III) complex, [Er(tfnb)3(bipy)] (Htfnb = 4,4,4-trifluoro-1-(2-naphthyl)-1,3-butanedione and bipy 2,2′-bipyridine) have been manufactured their properties studied. A complete quenching of the ligand visible emission is shown, only sensitized 1.5 μm electroluminesce from results. From...
Three novel ternary Er3+ complexes emitting in the C band transmission window for fiber optic communications have been synthesised and their structures elucidated by single crystal X-ray diffraction. The fluorinated β-diketonate ligand, 1,1,1-trifluoro-5,5-dimethyl-2,4-hexanedione, combines a good absorption cross-section ultraviolet region with reduction of non-radiative quenching emission, while rigidity bulkiness three different N,N-donors (2,2′-bipyridine, bathophenanthroline...
SUMMARY Objective: The aim was to evaluate the color longevity after nine months of in-office bleaching with gel (6% hydrogen peroxide), compare this a control concentration 35% in split-mouth study model, and assess dental confidence psychosocial impact on patients. Methods Materials: Twenty-seven patients were assessed at nine-month recall. procedure 6% or peroxide performed randomly upper hemi-arch each patient. measured baseline one week, month, procedure, using Vita Easyshade...
This study reports evidence on the feasibility of a classification natural resins by ATR-FTIR spectroscopy based specific absorbance band positions. A set twelve selected were used to assess position variability and this vibrational data was put in relationship with chemical composition resins. As result, into following four main families is proposed: 1) those correlated communic acids (sandarac, black copal, pine pitch amber); 2) associated abietic acid (rosin mastic); 3) ketone groups...
Despite extensive research on the chemical composition of elderberries and their numerous uses in pharmaceutical, beverage, food production, there is still a lack knowledge about Sambucus nigra leaves flowers' antimicrobial activity against plant pathogens. In this study, phytoconstituents aqueous ammonia extracts were first characterized by infrared spectroscopy gas chromatography-mass spectrometry. The major phytocompounds identified flower extract octyl 2-methylpropanoate;...
French tamarisk, Tamarix gallica L. (family Tamaricaceae) is a deciduous tree that, like other halophytes, grows in wide variety of saline habitats thanks to its powerful phenolics-based antioxidant system. Given that properties are usually linked the presence compounds with antifungal properties, work presented herein antimicrobial activity T. bark extract was investigated against four phytopathogenic species genus Fusarium. According results gas chromatography–mass spectroscopy,...
Santolina chamaecyparissus L. (cotton-lavender) is receiving increasing attention due to its potential for modern medicine and considered both a functional food nutraceutical. In this work, the phytochemical profile of flower hydromethanolic extract was investigated by gas chromatography-mass spectrometry, applications as biorational crop protection were explored against Neocosmospora spp., in vitro planta. The profiling analysis identified several terpene groups. Among sesquiterpenoids,...
Erbium complexes featuring β-diketonate ligand 2,4-hexanedione (Hh) and N,N-donor-ligands 2,2′-bipyridine (bipy), 5-nitro-1,10-phenanthroline (5NO2phen) bathophenanthroline (bath) have been synthesized. The structures of the ternary [Er(h)3(bipy)], [Er(h)3(5NO2phen)] [Er(h)3(bath)] determined by single crystal X-ray diffraction. Excitation in ultraviolet region (337 nm) led to near infrared (NIR) luminescence at 1532 nm characteristic trivalent erbium ion three compounds, with an improved...
Most people who make the transition to renal replacement therapy (RRT) are treated with a fixed dose thrice-weekly hemodialysis réegimen, without considering their residual kidney function (RKF). Recent papers inform us that incremental is associated preservation of RKF, whenever compared conventional hemodialysis. The objective present controlled randomized trial (RCT) determine if start HD one sessions per week (1-Wk/HD), it better patient survival and other safety parameters. IHDIP...
In the work presented herein, we analyze efficacy of three basic substances that comply with European Regulation (EC) No 1107/2009, namely chitosan, horsetail (Equisetum arvense L.) and nettle (Urtica dioica L.), for control grapevine trunk diseases (GTDs) in organic farming. The E. U. aqueous extracts, prepared according to SANCO/12386/2013 SANTE/11809/2016, have been studied by gas chromatography–mass spectrometry (GC-MS), identifying their main active constituents. substances, either...
Phytopathogenic bacteria represent a risk to global food production by impacting variety of crops. The aim this study was characterize the contents bioactive constituents in extracts from Ginkgo biloba L. leaves and fruits test their activity against six phytopathogenic that affect horticultural Gas chromatography–mass spectrometry (GC−MS) used for chemical profiling aqueous methanol extracts, bacteriostatic Clavibacter michiganensis subsp. michiganensis, Pseudomonas cichorii, syringae pv....
A carbon-nitride compound with defect zincblende structure (P4̄3m) has been discovered in samples prepared by a chemical precursor route. Crystallographical (high-resolution electron microscopy and nanodiffraction) energy loss measurements performed to identify the material as cubic C3N4 composition. Nanoindentation indicates high elastic recovery hardness. The results agree detailed ab initio calculations on metastable structures compressibility. Our synthesis method is projected be process...
Seven new tris(β-diketonear-nate)ytterbium(III) complexes with the general formula [Yb(β-diketonate)3(5NO2phen)] (where β-diketone is either 4,4,4-trifluoro-1-(2-naphthyl)-1,3-butanedione, 4,4,4-trifluoro-1-(2-furyl)-1,3-butanedione, 1,1,1-trifluoro-2,4-pentanedione, 1,1,1-trifluoro-5,5-dimethyl-2,4-hexanedione, 1,1,1,5,5,6,6,7,7,7-decafluoro-2,4-heptanedione, 2,4-hexanedione or 2,6-dimethyl-3,5-heptanedione, and 5NO2phen = 5-nitro-1,10-phenanthroline) were synthesized characterized by...