Xi–Shi Tai

ORCID: 0000-0002-0050-1900
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About
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Research Areas
  • X-ray Diffraction in Crystallography
  • Crystallization and Solubility Studies
  • Crystal structures of chemical compounds
  • Metal complexes synthesis and properties
  • Metal-Organic Frameworks: Synthesis and Applications
  • Magnetism in coordination complexes
  • Synthesis and biological activity
  • Synthesis and Characterization of Heterocyclic Compounds
  • Lanthanide and Transition Metal Complexes
  • Crystallography and molecular interactions
  • Organometallic Compounds Synthesis and Characterization
  • Polyoxometalates: Synthesis and Applications
  • Electrocatalysts for Energy Conversion
  • Catalytic Processes in Materials Science
  • Advanced Photocatalysis Techniques
  • Molecular Sensors and Ion Detection
  • Phenothiazines and Benzothiazines Synthesis and Activities
  • Carbon dioxide utilization in catalysis
  • Fuel Cells and Related Materials
  • Synthesis of Organic Compounds
  • Catalysis and Hydrodesulfurization Studies
  • Covalent Organic Framework Applications
  • Organic Light-Emitting Diodes Research
  • Synthesis and Reactivity of Heterocycles
  • Synthesis and Reactivity of Sulfur-Containing Compounds

Weifang University
2016-2025

Chengdu University
2023

King Khalid University
2023

University of Electronic Science and Technology of China
2023

Shandong Normal University
2023

Ningxia University
2006-2007

Weifang Medical University
2007

Lanzhou University
2002-2004

A novel Mn–Cu bimetallic complex was synthesized which demonstrated enhanced chemodynamic therapy <italic>via</italic> generating a hydroxyl radical with simultaneous glutathione depletion.

10.1039/c9cc06040e article EN Chemical Communications 2019-01-01

Abstract: Seawater electrolysis is a promising and sustainable technology for green hydrogen production. However, some disadvantages include sluggish kinetics, competitive chlorine evolution reaction at the anode, chloride ion corrosion, surface poisoning, which has led to decline in activity durability low oxygen (OER) selectivity of anodic electrodes. Benefiting from lower interface resistance, larger active surface, superior stability, self-supported nanoarrays have emerged as advanced...

10.3866/pku.whxb202303012 article EN Acta Physico-Chimica Sinica 2023-01-01

A new bis-Schiff base (L) Ca(II) complex, CaL, was synthesized by the reaction of calcium perchlorate tetrahydrate, 1,3-diamino-2-hydroxypropane, and 2-formyl phenoxyacetic acid in an ethanol–water (v:v = 2:1) solution characterized IR, UV-vis, TG-DTA, X-ray single crystal diffraction analysis. The structural analysis indicates that complex crystallizes monoclinic system, space group P121/n1, ions are six-coordinated with four O atoms (O8, O9, O11, O12, or O1, O2, O4, O6) two N (N1, N2, N3,...

10.3390/molecules29051047 article EN cc-by Molecules 2024-02-28

The effective S‐scheme homojunction relies on the precise regulation of band structure and construction advantaged charge migration interfaces. Here, electronic structural properties g‐C3N4 were modulated through meticulous polymerization self‐assembled supramolecular precursors. Experimental DFT results indicate that both intrinsic bandgap surface characteristics adjusted, leading to formation an in‐situ reconstructed interface facilitated by van der Waals forces. catalyst, composed...

10.1002/anie.202425439 article EN Angewandte Chemie International Edition 2025-01-09

A bimetallic Cu(<sc>ii</sc>) complex was developed as a novel antitumor chemodynamic therapy agent with glutathione depletion properties.

10.1039/d0dt01742f article EN Dalton Transactions 2020-01-01

Selective hydrogenation of 1,3-butadiene is a crucial industrial process for the removing 1,3-butadiene, byproduct butene production. Developing catalysts with high catalytic performance at low temperatures has become research hotspot. In this study, bimetallic Pd–Co supported on Al2O3 derived from MIL-53(Al) various calcination were synthesised via co-impregnation method. These structurally characterised using powder X-ray diffraction, thermogravimetric analysis, N2 adsorption–desorption,...

10.1038/s41598-024-84707-3 article EN cc-by-nc-nd Scientific Reports 2025-01-02

The effective S‐scheme homojunction relies on the precise regulation of band structure and construction advantaged charge migration interfaces. Here, electronic structural properties g‐C3N4 were modulated through meticulous polymerization self‐assembled supramolecular precursors. Experimental DFT results indicate that both intrinsic bandgap surface characteristics adjusted, leading to formation an in‐situ reconstructed interface facilitated by van der Waals forces. catalyst, composed...

10.1002/ange.202425439 article EN Angewandte Chemie 2025-01-09

Abstract The “Solar Sabatier” reaction has emerged as a promising sustainable method for the CO 2 hydrogenation. development of advanced metal‐support catalysts based on Strong Metal‐Support Interaction (SMSI) offers significant advantages in activation and regulation selectivity. Herein, novel composite Ni/CaTiO 3 catalyst consisting Ni Ni‐doped CaTiO is synthesized utilized methanation. A noteworthy finding that incorporation into matrix instrumental formation oxygen vacancies...

10.1002/adfm.202503531 article EN Advanced Functional Materials 2025-03-07

The metal-organic zeolite imidazolate framework-8 (ZIF-8) supported gold-silver bimetallic catalysts with a core-shell structure (Au@Ag/ZIF-8 and Ag@Au/ZIF-8) cluster (AuAg/ZIF-8) were successfully prepared by the deposition-redispersion method. Energy dispersive X-ray spectroscopy (EDS) elemental mapping images displayed that in Au@Ag/ZIF-8 catalyst, Ag atoms deposited on an exposed Au surface, structured Au@Ag particles highly dispersed as shell formed. Additionally, XPS investigation at...

10.3390/polym10101089 article EN Polymers 2018-10-01

A novel Schiff base ligand derived from 2,2'-bis(p-methoxyphenylamine) and salicylicaldehyde its transition metal complexes with Cu (Ⅱ), Co (Ⅱ) Mn have been synthesized. Their spectral properties electrochemical behavior were investigated.

10.3390/80500439 article EN cc-by Molecules 2003-05-31

The Au–Sn bimetallic catalysts supported on GO and rGO prepared by two-step immobilization showed the excellent catalytic performance for selective oxidation of benzyl alcohol to benzaldehyde under moderate conditions.

10.1039/d3ra03496h article EN cc-by-nc RSC Advances 2023-01-01

A Cd-MOF was constructed based on 3,5-bis(4-carboxyphenyl) pyridine under solvothermal conditions. Its structure and phase purity were verified by single-crystal X-ray diffraction. Thereafter, some studies the morphology, structure, luminescent properties of compound carried out. The exhibited a highly sensitive response to Fe3+, Cr(IV), trinitrophenol (TNP), colchicine fluorescence-quenching mechanism. possible mechanism luminescence quenching discussed in detail.

10.1021/acsomega.3c07110 article EN cc-by-nc-nd ACS Omega 2024-02-29

A new binuclear Gd(III) complex, [Gd2(L)6(Phen)2]·4H2O, was synthesized via the reaction of gadolinium(III) nitrate hexahydrate, 4-acetylphenoxyacetic acid (HL), NaOH, and 1,10-phenanthroline (Phen) in a solution water–ethanol (v:v = 1:1). The complex characterized using IR, UV–vis, TG-DSC, fluorescence, single-crystal X-ray diffraction analyses. results showed that crystallizes triclinic system, space group P-1, each ion coordinated with two nitrogen atoms (N1, N2, or N1a, N2a) from Phen...

10.3390/molecules29133039 article EN cc-by Molecules 2024-06-26

Three bimetallic Cu–Ni nanoparticle-supported catalysts were synthesized by co-immobilization followed H2 reduction. A chromium(III) terephthalate metal organic framework (MIL-101), titanium dioxide (TiO2), and carbon (C) with different properties (acidity Brunauer–Emmett–Teller surface area) selected as supports for studying the effect of support nature on catalytic activity selectivity in oxidation benzyl alcohol. The physicochemical Cu–Ni-supported characterized XRD, NH3-TPD, nitrogen...

10.3390/catal9060538 article EN Catalysts 2019-06-17
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