A5054025314- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Crystal Structures and Properties
- Metal-Organic Frameworks: Synthesis and Applications
- Catalytic Processes in Materials Science
- Catalysis and Oxidation Reactions
- Zeolite Catalysis and Synthesis
- Catalysts for Methane Reforming
- Nanocluster Synthesis and Applications
- Quantum Dots Synthesis And Properties
- Inorganic Chemistry and Materials
- Chalcogenide Semiconductor Thin Films
- Mesoporous Materials and Catalysis
- Covalent Organic Framework Applications
- Carbon dioxide utilization in catalysis
- Magnetism in coordination complexes
- Gas Sensing Nanomaterials and Sensors
- Organoboron and organosilicon chemistry
- Organometallic Compounds Synthesis and Characterization
- Ionic liquids properties and applications
- Crystallography and molecular interactions
- Polyoxometalates: Synthesis and Applications
- Chemical Synthesis and Reactions
- Advanced Photocatalysis Techniques
- CO2 Reduction Techniques and Catalysts
Dalian University of Technology
2016-2025
Dalian University
2014-2025
Jiangnan University
2025
Chinese Academy of Sciences
1998-2019
Fujian Institute of Research on the Structure of Matter
2014-2019
Yanshan University
2018-2019
State Council of the People's Republic of China
2017
University of Shanghai for Science and Technology
2016
Nankai University
2009-2010
State Key Laboratory of Optoelectronic Materials and Technology
2008
The key to photocatalysis lies in the efficient separation and migration of photogenerated carriers surface for participation reaction. However, recombination electrons holes is a major hindrance that reduces activity. Herein, we developed method introduce lattice strain by regulating crystallinity material, thus resulting an intensive polarization internal electric field, which can promote process improve efficiency photocatalysis. degree be controlled solvothermal temperature. Compared...
Phosphorized SnO<sub>2</sub>/graphene nanocomposite was designed and synthesized for superior Li-ion storage properties due to the synergistic effect of multiple components.
The electronically excited state and luminescence property of metal–organic framework MOF-5 were investigated using relativistic density functional theory (DFT) time-dependent DFT (TDDFT). geometry, IR spectra, UV–vis spectra in the ground calculated DFT, leading to good agreement between experimental theoretical results. frontier molecular orbitals electronic configuration indicated that mechanism follows ligand-to-ligand charge transfer (LLCT), namely, π* → π, rather than emission with ZnO...
Photocatalysis is promising for the reduction of CO2 into fuels and chemicals under mild conditions but still a challenge due to inert nature CO2. Herein, ZnIn2S4/In(OH)3–x (ZIOS) heterojunction was developed visible-light-driven reduction, where ZnIn2S4 (ZIS) harvests light In(OH)3–x with frustrated Lewis pairs (FLPs) activates The hydroxyl-deficient vacancies (OHVs) act as acid, adjacent hydroxyl groups serve base form FLPs. ZIOS composites are fabricated via partial sulfurization Zn–In–O...
A novel functionalized MOF material, Brönsted acidic ionic liquid (BAIL) confined inside well-defined MIL-101 nanocages, was developed for the first time based on tandem post-synthetic strategy. The catalytic performance of BAIL in material evaluated by using acetalization benzaldehyde with glycol as a probe reaction. resulting BAIL/MIL-101 exhibited superior performance, which is mainly due to combination advantageous merits catalyst desirable microenvironment nanocages.
This critical review presents the fundamentals, challenges, and outlooks in MTHMs according to state-of-the-art progress first-hand experience.
(H(2)en)(2)Cu(8)Sn(3)S(12) contains a trigonal CuS(3)-based framework into which Sn(4+) ions are incorporated, and exhibits multiple channel systems interesting ion-exchange properties.
A bipyridinium ligand with a charge separated skeleton has been introduced into metal–organic framework to yield porous material charge-polarized pore space, which exhibits selective adsorption for polar guest molecules and can be further used in gas chromatography the separation of alcohol–water mixtures.
A novel heterogeneous catalyst, the ionic liquid (IL) of 1-butyl-3-methylimidazolium acetate (BmimOAc) immobilized on MIL-101-NH2, denoted as IL(OAc–)-MIL-101-NH2, was prepared by "ship-in-a-bottle" strategy. The IL BmimOAc in MIL-101-NH2 nanocages primordially, which condensation product MIL-101-NH2's amine group with 1,1′-carbonyldiimidazole (CDI) reacted 1-bromo butane, and then intermediate exchanged potassium acetate. structure physicochemical properties IL(OAc–)-MIL-101-NH2 were...
A recyclable and magnetic nanocomposite catalyst (IL/Fe3O4@HKUST-1) was synthesized via grafting ionic liquid (IL) [AEMIm]BF4 into magnetically functionalized metal–organic framework Fe3O4@HKUST-1 in a water–ethanol media. The properties of IL/Fe3O4@HKUST-1 were fully characterized by powder X-ray diffraction, electron microscopy, Fourier-transform infrared spectroscopy, nitrogen adsorption–desorption, density-functional theory, property measurement system. showed high activity the...
Using CO
The overly simplistic geometric and electronic structures of single‐atom catalysts have become a significant bottleneck in the field sensing, impeding both design highly efficient electrochemical sensors establishment structure‐activity relationships. To address these challenges, we present novel strategy to boost sensing performance by precisely tuning single‐atomic interdistance (SAD) correlated (c‐SACs). A series Ru‐based c‐SACs (Rud=6.2 Å, Rud=7.0 Rud=9.3 Å) are synthesized with...
B(C6F5)3-based frustrated Lewis pairs (FLPs) have made remarkable progress in metal-free catalytic reduction. However, the high affinity of B(C6F5)3 for oxygen makes it susceptible to irreversible poisoning when exposed H2O, limiting its widespread application reductive amination. To overcome influence a hydrophobic catalyst, B(C6F5)3@Rn–1-MIL-101 (n = 3, 5, 7), was developed by confining within nanocages metal–organic frameworks (MOFs) modified with alkyl chains. The strength catalyst could...
Two novel framework compounds, Zn(en)3Ag2I4 (1) and Ni(en)3Ag2I4 (2), have been synthesized by a self-assembly reaction. Both of them contain an unexpected framework, Ag2I42− with tridymite topolopy, the discrete M(en)32+ cations are located in channels. Their thermal properties circular dichroism spectra were investigated.
Two copper-rich open-framework sulfides, K(4)Cu(8)Ge(3)S(12) (1) and Rb(4)Cu(8)Ge(3)S(12) (2), have been synthesized under solvothermal conditions. Compounds 1 2 are isostructural contain icosahedral [Cu(8)S(12)](16-) clusters as basic building blocks. These primitive cubic packed connect to one another by discrete Ge(4+) ions generate 3D Cu-Ge-S framework form channels along 100 directions where the alkali metal cations reside. two sulfides crystallize in perovskite structure.