A5006867634- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Metal-Organic Frameworks: Synthesis and Applications
- Metal complexes synthesis and properties
- Crystal structures of chemical compounds
- Crystallography and molecular interactions
- Magnetism in coordination complexes
- Crystal Structures and Properties
- Molecular Sensors and Ion Detection
- Organometallic Complex Synthesis and Catalysis
- Organometallic Compounds Synthesis and Characterization
- Advanced biosensing and bioanalysis techniques
- Advanced Nanomaterials in Catalysis
- Synthesis and biological activity
- Synthesis and Characterization of Heterocyclic Compounds
- DNA and Nucleic Acid Chemistry
- Advanced SAR Imaging Techniques
- Luminescence and Fluorescent Materials
- Nanocluster Synthesis and Applications
- Lanthanide and Transition Metal Complexes
- Synthesis and Reactivity of Heterocycles
- Carbon and Quantum Dots Applications
- Polyoxometalates: Synthesis and Applications
- Radar Systems and Signal Processing
- Synthesis and Biological Evaluation
Aviation Industry Corporation of China (China)
2020-2024
Zhejiang University
2018-2024
China University of Geosciences (Beijing)
2022-2024
Zhejiang Lab
2024
National University of Singapore
2023
Beijing Institute of Technology
2015-2021
Capital Normal University
2011-2017
Universität Innsbruck
2016
Walter de Gruyter (Germany)
2016
Beijing University of Technology
2014
The synthesis of nanomaterials with specific properties and functions as biomimetic nanoenzymes has attracted extensive attention in the past decades due to their great potential substitute natural enzymes. Herein, a facile simple method for preparation platinum nanoparticle (PtNP)-decorated two-dimensional metal-organic framework (MOF) nanocomposites was developed. A ligand heme-like structure, Fe(III) tetra(4-carboxyphenyl)porphine chloride (TCPP(Fe)), applied synthesize MOF nanosheets...
Recently, two-dimensional metal–organic framework (2D MOF) nanosheets have drawn a lot of attention on account their various advantages, like ultrathin thickness, ultralarge specific surface area, abundant accessible active sites, favorable solution dispersion properties, and ease designability. However, until now, it is still difficult to produce 2D MOF in large scale, which hinders the practical applications nanosheets. Here, for first time, we introduced novel shear exfoliation method...
Two D–A type asymmetrical Zn(<sc>ii</sc>) coordination complexes, [ZnL<sup>1</sup>(C<sub>2</sub>H<sub>5</sub>OH)] (<bold>1</bold>) and [ZnL<sup>2</sup>(DMF)]·DMF (<bold>2</bold>) were designed, synthesized, studied. Through the strategy of expanding π–π stacking interaction, fluorescence emission is red-shifted remarkably.
Focusing on renewable energy, we are devoted to developping efficient, robust and low cost water reduction catalysts (WRCs). Two new Cu-based borate catalysts, namely H2Na2K2[(μ4-O)Cu4@B20O32(OH)8]·21H2O (1) H2Rb1.6K2.4[(μ4-O)Cu4@B20O32 (OH)8]·15H2O (2), with cubic supramolecular cages were synthesized under a hydrothermal condition. Moreover, copper complexes applied as (WRCs) in the presence of [Ir(ppy)2(dtbbpy)][PF6] photosensitizer triethanolamine (TEOA) sacrificial electron donor....
Rare-earth phosphine-oxygen complexes based on [PW 12 O 40 ] 3− for photocatalytic degradation of MB – rate reached 98.48–99.78% within 65 minutes.
A new acentric borate, K2 Na3 [{B6 O10 (OH)}-{B3 O4 (OH)3 }] ⋅ H2 O (1) has been made under solvothermal condition. 1 layered structure by B6 O13 (OH)-based chains and B3 O5 -bridging clusters. Second-harmonic generation (SHG) measurements reveal that is a phase-matchable nonlinear optical (NLO) material, showing the SHG signal intensity of 1.8 times KDP (KH2 PO4 ). Besides, UV-Vis diffuse reflectance spectrum shows short deep UV (DUV) absorption cutoff edge 198 nm. Thermogravimetric...
The base-pair sequences are the foundation for biological processes of DNA or RNA, and mismatch is very important to reveal genetic diseases rearrangements. However, lack well-defined structural information about obstructing investigation this issue. challenge crystallize materials containing mismatch. Engineering small-molecule mimics model an effective strategy solve Here, six cytidine-5'-monophosphate (CMP) 2'-deoxycytidine-5'-monophosphate (dCMP) coordination polymers were reported...
Compared with conventional bulk 3D metal-organic framework (MOF), the MOF nanosheets possess large surface area, ultrathin thickness, and well solution dispersion properties, which is suitable to be used as novel templates synthesize functional composites. However, up now, it remains difficult grow noble metal nanoplates on 2D due complexity of synthetic process. Here, for first time, we (Cu-TCPP or Cu-TCPP(Fe)) an template solution-phase growth silver (Ag), gold (Au), palladium (Pd) at...
Abstract A colorimetric and fluorescent sensor for trace water in methanol has been designed characterized, which is a kind of aluminium‐Schiff base coordination complex derived from diaminomaleonitrile. The fluorescence properties this have studied based on excited state intramolecular proton transfer (ESIPT) charge (ICT) mechanism. emission Al‐L can be quenched by 0.1% distinguished naked eyes. detection limitation 0.01% recognized spectra.
By tuning the synthetic conditions, borates with 0D clusters were transformed into a 1D chain, 2D layer and 3D framework.
Different crystalline complexes of CMP–bpe–M(<sc>ii</sc>) are synthesized based on pH control and their pre-organization mode in aqueous solution under different was studied by fluorescence spectroscopy.
The complex AgDpq exhibits excellent photophysical properties and TADF characteristics than Cu( i ) complex, which is related to the unique one-dimensional infinite chain structure smaller contribution of metal excited states.