A5040085831- Polyoxometalates: Synthesis and Applications
- Advanced Photocatalysis Techniques
- Electrocatalysts for Energy Conversion
- Advanced Nanomaterials in Catalysis
- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Advanced battery technologies research
- Ammonia Synthesis and Nitrogen Reduction
- Fuel Cells and Related Materials
- Metal-Organic Frameworks: Synthesis and Applications
- Nanocluster Synthesis and Applications
- Electrochemical sensors and biosensors
- Photochromic and Fluorescence Chemistry
- CO2 Reduction Techniques and Catalysts
- Covalent Organic Framework Applications
- Electrochemical Analysis and Applications
- Conducting polymers and applications
- Vanadium and Halogenation Chemistry
- Crystallography and molecular interactions
- Catalytic Processes in Materials Science
- Nanomaterials for catalytic reactions
- Quantum Dots Synthesis And Properties
- Gas Sensing Nanomaterials and Sensors
- Copper-based nanomaterials and applications
- Hydrogen Storage and Materials
University of Chinese Academy of Sciences
2019-2024
Institute of Process Engineering
2015-2024
Henan Polytechnic University
2024
China University of Geosciences
2009-2024
Chinese Academy of Sciences
2012-2023
Shandong Academy of Agricultural Machinery Sciences
2022
Ji Hua Laboratory
2021-2022
State Key Laboratory of Multiphase Complex Systems
2016-2021
Beijing Meteorological Bureau
2020
Constructor University
2016
One-dimensional (1-D) nanostructures are of great importance due to their superior charge transport properties. Anchoring 1-D semiconductor nanomaterials on graphene offers potential advantages in photoelectrochemical and sensing applications. This paper presents a systematic investigation the incorporation WO3 nanorods for high-efficiency visible-light-driven photocatalysis NO2 gas sensing. novel composite shows remarkably enhanced performance compared pure these The high photocatalytic...
Abstract Electrocatalytic C−N bond coupling to convert CO 2 and N molecules into urea under ambient conditions is a promising alternative harsh industrial processes. However, the adsorption activation of inert gas then driving C–N reaction energetically challenging. Herein, novel Mott–Schottky Bi‐BiVO 4 heterostructures are described that realize remarkable yield rate 5.91 mmol h −1 g Faradaic efficiency 12.55 % at −0.4 V vs. RHE. Comprehensive analysis confirms emerging space–charge region...
Fuel cells and metal–air batteries will only become widely available in everyday life when the expensive platinum-based electrocatalysts used for oxygen reduction reactions are replaced by other efficient, low-cost stable catalysts. We report here use of nitrogen-doped graphdiyne as a metal-free electrode with comparable electrocatalytic activity to commercial Pt/C catalysts reaction alkaline fuel cells. Nitrogen-doped has better stability increased tolerance cross-over effect than conventional
Abstract A green, facile, one‐pot synthesis of well‐defined Au NPs@POM–GNSs tricomponent nanohybrids is reported (POM stands for polyoxometalate and GNSs graphene nanosheets). The convenient, rapid environmentally friendly. POMs serve as both reducing, encapsulating molecules, bridging molecules; this avoids the introduction other organic toxic molecules. Characterization using transmission electron microscopy, X‐ray diffraction, photoelectron spectroscopy, Raman spectroscopy analysis...
Electrocatalytic C-N coupling reaction by co-activation of both N2 and CO2 molecules under ambient conditions to synthesize valuable urea opens a new avenue for sustainable development, while the actual catalytic activity is limited poor adsorption capability gas on catalyst surface. Herein, theoretical calculation predicts that well-developed built-in electric field in perovskite hetero-structured BiFeO3/BiVO4 hybrids can accelerate local charge redistribution thus promote targeted...
Precisely fabricated frustrated Lewis pairs in the Ni 3 (BO ) 2 nanocrystal achieve integration of active sites and effective electrocatalytic C–N bond coupling to synthesize urea.
Radioresistance is one of the undesirable impediments in hypoxic tumors, which sharply diminishes therapeutic effectiveness radiotherapy and eventually results failure their treatments. An attractive strategy for attenuating radioresistance developing an ideal radiosensitization system with appreciable capacity to attenuate tumor hypoxia reinforce response tumors. Therefore, we describe development Gd-containing polyoxometalates-conjugated chitosan (GdW10@CS nanosphere) as a simultaneous...
A precisely fabricated conductive MOF incorporating unique host–guest interactions can be used to achieve active-site integration and effective electrocatalytic C–N bond coupling for the synthesis of urea.
A bottom-up method is used to construct novel metal-free catalysts for deeper study of oxygen reduction reaction (ORR) catalysis. Through controlling the structural evolution a 2D covalent triazine-based framework, conductivity, nitrogen configurations, and multidoping structures as-prepared can be easily tuned, which makes great platform both studying mechanisms ORR optimizing performances catalysts. As service our authors readers, this journal provides supporting information supplied by...
A 3D configuration of high-quality graphene sheets and a polyoxometalate [H<sub>7</sub>P<sub>8</sub>W<sub>48</sub>O<sub>184</sub>]<sup>33−</sup> showing excellent hydrogen evolution activity at extremely low overpotential.
N, F co-doped graphdiyne was synthesized, which showed comparable electrocatalytic activity to Pt/C for ORR.
Homogeneous coating of carbon nanotubes with metallic nanoparticles was achieved using supramolecular auto-organization amphiphilic molecules as template. The resulting Pd nanoparticles/carbon nanotube nanohybrids were then evaluated in electrocatalysis experiments, showing superior activity ethanol oxidation compared to analogous systems.
The heterostructured CoSe/MoSe<sub>2</sub> hybrids was fabricated by a non-metal induced growth method for efficient oxygen evolution reaction (OER).
CdS nanorods/reduced graphene oxide (RGO) composites were fabricated through a facile one-pot hydrothermal synthesis. The sample CdS/RGO-1% possesses excellent photocatalytic properties under visible light for the degradation of methyl orange with rate constant 1.76 × 10−2 min−1, which is about three times higher than that pure nanorods. novel composite material can also be used as an enzyme-free biosensor H2O2 based on its electrocatalytic behaviour. low-cost sensor shows rapid response and...
Novel Co atoms immobilized carbon nanotubes (CoSAs@CNTs) are synthesized by structural engineering of the zeolitic imidazolate framework (ZIF-67) upon treatment with dicyandiamide (DCD). A unique morphology and promising electrochemical performance shown CNTs. The electrocatalyst remarkably exhibits a highly positive onset potential 0.99 V half-wave 0.86 V, both even more than commercial Pt/C catalyst, current density is also greater that catalyst in alkaline media. decent observed acidic...
A facile strategy is adopted to synthesize bismuth nanostructure for efficient CO<sub>2</sub> electroreduction formate.
Electrochemical sensors for detecting micromolecule organics are desirable improving the perception of environmental quality and human health. However, currently, electrochemical formaldehyde substantially limited on market due to long-term unsolved problems low electrooxidation efficiency CO poisoning issue commercial Pd catalysts. Here, a 2D Cr-doped metallene (Cr-Pdene) with few atomic layers is shown as an advanced catalyst ultrasensitive selective sensing via highly efficient...
Abstract Electrocatalytic C−N bond coupling to convert CO 2 and N molecules into urea under ambient conditions is a promising alternative harsh industrial processes. However, the adsorption activation of inert gas then driving C–N reaction energetically challenging. Herein, novel Mott–Schottky Bi‐BiVO 4 heterostructures are described that realize remarkable yield rate 5.91 mmol h −1 g Faradaic efficiency 12.55 % at −0.4 V vs. RHE. Comprehensive analysis confirms emerging space–charge region...
Polyoxometalate (POM) based binary and ternary hybrids, including the combination of POMs, semiconductors, nanostructured carbon (carbon nanotube (CNT), graphene, dots et al.) metal nanoparticles (MNPs), are key materials in photoelectrocatalysis. POM play a role constructing nanohybrids contributing to their photoelectrochemical catalytic properties. These composites combine properties from two or three functional nanoscale materials, resulting wider range applications, catalysis, energy...
WO3 and TiO2 colloids were synthesized by the forced hydrolysis technique, different amounts of added to under sonication get stable combined (WO3/TiO2). The experimental results indicate that UV-light coloration can be improved greatly after combination. When molar ratio is about 1:40, ΔOD at 900 nm for WO3/TiO2 12.7 times colloids. improvement effect increases with increased concentration in composite colloids, maximum enhancement increase more than 50-fold. It shown combination,...
The molecular recognition of polyoxometalates by human serum albumin is studied using two different (POMs) at pH 7.5. results are compared with those obtained 3.5 and 9.0. At 7.5, both POMs strongly interact the protein binding behaviors. Keggin shaped POM, [H2W12O40]6- (H2W12), specifically binds protein, forming a complex 1:1 stoichiometry Ka = 2.9 × 106 M-1. constant decreased dramatically increase ionic strength, thus indicating mostly electrostatic process. Isothermal titration...
Binding human serum albumin (HSA) of three polyoxometalates (POMs) with the Wells−Dawson structure, α2-[P2W17O61]10− (abbreviated as α2-P2W17) and two its metal-substituted derivatives, α2-[NiP2W17O61]8− α2-[CuP2W17O61]8− (α2-P2W17Ni α2-P2W17Cu, respectively) was studied in an aqueous medium at pH 7.5. Fluorescence quenching, circular dichroism (CD), thermal denaturation, isothermal titration calorimetry (ITC) were used for this purpose. The results compared those obtained previously Keggin...