Orlando Rios

ORCID: 0000-0002-1814-7815
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About
Contact & Profiles
Research Areas
  • Additive Manufacturing and 3D Printing Technologies
  • Aluminum Alloy Microstructure Properties
  • Aluminum Alloys Composites Properties
  • Magnetic Properties of Alloys
  • Additive Manufacturing Materials and Processes
  • Intermetallics and Advanced Alloy Properties
  • Material Properties and Applications
  • Advanced Materials and Mechanics
  • Polymer composites and self-healing
  • Literature, Culture, and Criticism
  • Cultural, Media, and Literary Studies
  • Supercapacitor Materials and Fabrication
  • Advanced Battery Materials and Technologies
  • Phase Change Materials Research
  • Bauxite Residue and Utilization
  • Advanced Sensor and Energy Harvesting Materials
  • Lignin and Wood Chemistry
  • Advancements in Battery Materials
  • Metallic Glasses and Amorphous Alloys
  • Semiconductor materials and interfaces
  • Liquid Crystal Research Advancements
  • Electric Motor Design and Analysis
  • Metal and Thin Film Mechanics
  • Magnetic and transport properties of perovskites and related materials
  • Manufacturing Process and Optimization

University of Tennessee at Knoxville
2012-2024

Oak Ridge National Laboratory
2013-2023

Knoxville College
2020-2023

Critical Technologies (United States)
2023

Georgia Institute of Technology
2021

Physical Sciences (United States)
2020

National Technical Information Service
2013-2019

Oak Ridge Associated Universities
2016-2019

Office of Scientific and Technical Information
2019

Universidade Federal do Rio de Janeiro
2008-2016

The synthesis, processing, and performance of a low‐cost monolithic battery electrode, produced entirely natural renewable resources, are reported. This anode material exhibits tunable electrochemical suitable for both high power energy applications. A synthesis method that directly results in electrically interconnected three‐dimensional architectures is presented, where the carbon framework functions as current collector lithium insertion material, eliminating extra mass expense inactive...

10.1002/adfm.201301420 article EN Advanced Functional Materials 2013-08-09

A new class of castable cerium strengthened aluminum alloys has phenomenal high temperature properties without the need for heat treatment.

10.1039/c7mh00391a article EN Materials Horizons 2017-01-01

Abstract Additive manufacturing allows for the production of complex parts with minimum material waste, offering an effective technique fabricating permanent magnets which frequently involve critical rare earth elements. In this report, we demonstrate a novel method - Big Area Manufacturing (BAAM) to fabricate isotropic near-net-shape NdFeB bonded magnetic and mechanical properties comparable or better than those traditional injection molded magnets. The starting polymer magnet composite...

10.1038/srep36212 article EN cc-by Scientific Reports 2016-10-31

Functional polymers are intelligent materials that can respond to a variety of external stimuli. However, these have not yet found widespread real world applications because the difficulties in fabrication and limited number functional building blocks be incorporated into material. Here, we demonstrate simple route incorporate three (azobenzene chromophores, liquid crystals, dynamic covalent bonds) an epoxy-based crystalline network (LCN), which azobenzene-based epoxy monomer is polymerized...

10.1021/acsami.6b04374 article EN publisher-specific-oa ACS Applied Materials & Interfaces 2016-06-01

We report a method to fabricate Nd–Fe–B (NdFeB) bonded magnets of complex shape via extrusion-based additive manufacturing (AM), also known as 3D-printing. have successfully formulated 3D-printable epoxy-based ink for direct-write AM with anisotropic MQA NdFeB magnet particles that can be deposited at room temperature. The new feedstocks contain up 40 vol.% particles, and they are shown remain uniformly dispersed in the thermoset matrix throughout deposition process. Ring, bar,...

10.1080/10426914.2016.1221097 article EN Materials and Manufacturing Processes 2016-08-17

Lignin-based carbons can be used as a low-cost alternative to graphite and petroleum-based enabling the production of sustainable, functional carbon materials for various applications. The microstructure development these controlled through chemical modification lignin precursor choice carbonization parameters. In this work, microstructured are synthesized from using combination fiber processing techniques. Lignin is modified by incorporating different ester groups which results in highly...

10.1039/c3ra46928j article EN RSC Advances 2013-12-03

Lignin is one of the most abundant and inexpensive natural biopolymers. It can be efficiently converted to low cost carbon fiber, monolithic structures, or powders that could used directly in production anodes for lithium-ion batteries. In this work, we report thermomechanical processing methods relevant conversion lignin precursors into fiber-based anode materials, impact precursor modification on melt processing, microstructure final material. Modification softwood produced functionalities...

10.1021/sc500189p article EN ACS Sustainable Chemistry & Engineering 2014-06-24

We explore the long-term demand and supply potentials of rare earth elements in alternative energy vehicles (AEVs) United States until 2050. Using a stock-flow model, we compare baseline scenario with scenarios that incorporate an exemplary technological innovation: novel aluminum–cerium–magnesium alloy. find introduction alloy demonstrates even low penetration rates can exceed domestic cerium production capacity, illustrating possible consequences innovations to material demand. End-of-life...

10.3390/resources7010009 article EN cc-by Resources 2018-01-25

Reprocessable shape memory liquid crystalline epoxy networks were synthesized.

10.1039/c7sm00934h article EN Soft Matter 2017-01-01

Decreasing microstructural length scales to the nanoscale is a proven way of increasing strength, but intrinsic metastability such structures typically makes them susceptible thermally activated coarsening. Recent advances in additive manufacturing permit bulk-nanostructured materials be produced through rapid solidification, like other metastable as-built coarsen rapidly with even modest thermal exposure. Here, selective laser melting employed produce an Al-Ce-based alloy high mechanical...

10.1016/j.matdes.2021.109988 article EN cc-by-nc-nd Materials & Design 2021-07-15

Liquid crystalline elastomers (LCEs) have emerged as an important class of functional materials that are suitable for a wide range applications, such sensors, actuators, and soft robotics. The unique properties LCEs originate from the combination between liquid crystal elastomeric network. control macroscopic orientation network structure is crucial to realizing useful functionalities LCEs. A variety chemistries been developed fabricate LCEs, including hydrosilylation, free radical...

10.1021/acsami.1c21096 article EN ACS Applied Materials & Interfaces 2022-03-23

Liquid-crystal elastomers (LCEs) capable of performing large and reversible deformation in response to an external stimulus are important class soft actuators. However, their manufacturing process typically involves a multistep approach that requires harsh conditions. For the very first time, LCEs with customized geometries can be manufactured by rapid one-step at room temperature developed. The hydrogen bond (H-bond) crosslinked main chain polymers comprising flexible short side chains....

10.1002/anie.202308793 article EN Angewandte Chemie International Edition 2023-07-27

Disulfide exchange and thiol–disulfide interchange reactions allow for reprocessing recycling of azobenzene-based liquid crystalline networks.

10.1039/c7ra06343a article EN cc-by-nc RSC Advances 2017-01-01

A smectic main-chain liquid crystalline elastomer (LCE), with controlled shape memory behavior, is synthesized by polymerizing a biphenyl-based epoxy monomer an aliphatic carboxylic acid curing agent. Microstructures of the LCEs, including their crystallinity and cross-linking density, are modified adjusting stoichiometric ratio reactants to tailor thermomechanical properties behavior material. Thermal characterized using differential scanning calorimetry dynamic mechanical analysis,...

10.1021/acs.macromol.5b00519 article EN Macromolecules 2015-04-10

Sodium sulfate decahydrate (Na2SO4.10H2O, SSD), a low-cost phase change material (PCM), can store thermal energy. However, separation and unstable energy storage capacity (ESC) limit its use. To address these concerns, eight polymer additives-sodium polyacrylate (SPA), carboxymethyl cellulose (CMC), Fumed silica (SiO2), potassium (PPA), nanofiber (CNF), hydroxyethyl (HEC), dextran sodium (DSS), poly(sodium 4-styrenesulfonate) (PSS)-were used to explore several stabilization mechanisms. The...

10.1016/j.isci.2023.107175 article EN cc-by iScience 2023-06-20
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